Author: Sister Julie Kramer
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
Book Description
Synthesis and Magnetic Properties of Some Copper(II) and Nickel(II) Triketonate Complexes
Author: Sister Julie Kramer
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
Book Description
Synthesis and Magnetic Properties of Transition Metal (II) 1,3,5-triketonate Complexes
Author: Daniel Patrick Murtha
Publisher:
ISBN:
Category : Ketones
Languages : en
Pages : 198
Book Description
Publisher:
ISBN:
Category : Ketones
Languages : en
Pages : 198
Book Description
Synthesis and Magnetic Properties of Some Binuclear Divalent Transition Metal Di and Triketonates
Author: Londa L. Borer
Publisher:
ISBN:
Category : Ketones
Languages : en
Pages : 266
Book Description
Publisher:
ISBN:
Category : Ketones
Languages : en
Pages : 266
Book Description
A Study of the Copper (II) and Nickel (II) Complexes of Some 5-substituted Tetrazoles
Author: Ned Arthur Daugherty
Publisher:
ISBN:
Category : Copper compounds
Languages : en
Pages : 252
Book Description
Publisher:
ISBN:
Category : Copper compounds
Languages : en
Pages : 252
Book Description
1. Synthesis, Structure and Properties of an Imidazolate Bridged CU(II)-Co(III) Complex ; 2. Synthesis, Structures and Properties of Nickel (II) and Copper (II) Tropocoronand Complexes
Author: William Michael Davis
Publisher:
ISBN:
Category : Heterobimetallic complexes
Languages : en
Pages : 440
Book Description
Publisher:
ISBN:
Category : Heterobimetallic complexes
Languages : en
Pages : 440
Book Description
Master's Theses and Doctoral Dissertations in the Pure and Applied Sciences
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 194
Book Description
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 194
Book Description
Synthesis and Magnetic Properties of Some Mononuclear, Binuclear, and Mixed-metal Binuclear Transition Metal (II) Complexes
Author: Raymond L. Hough
Publisher:
ISBN:
Category :
Languages : en
Pages : 150
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 150
Book Description
Synthesis and Characterisation of Nickel (II) and Copper (II) Complexes of Some Macrocyclic Schiff-base Ligands
Author: Hassan Keypour
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Synthesis, Structure, and Magnetic Characterization of Some Copper(II) Halide Complexes
Author: Wayne Edward Marsh
Publisher:
ISBN:
Category : Copper compounds
Languages : en
Pages : 488
Book Description
Publisher:
ISBN:
Category : Copper compounds
Languages : en
Pages : 488
Book Description
Novel Iron(II) Triazole-pyridine Based Dinuclear Complexes
Author: Huan Guo
Publisher:
ISBN:
Category :
Languages : en
Pages : 204
Book Description
The major focus of this thesis involves a new approach to spin-crossover (SCO) in iron(II) dinuclear complexes. In order to acquire SCO properties, a series of novel ligands (L1M, L2M, L3M, L4M), together with the corresponding iron(II) and/or nickel(II) complexes were synthesized and characterized. Beyond the successful synthesis and characterization of these ligands, some interesting aspects of their synthesis are discussed. The reported ligands are methyl-derivatives from ligands previously studied in the group. The methyl group in the position 6 of the pyridine group is introduced to induce steric hindrance in the complexes and decrease the ligand field strength. As a result, the influence of the methyl group may induce SCO in low spin (LS) complexes, or tune the SCO properties (such as transition hysteresis or transition temperature) in complexes with SCO. Ligands were divided into three different types according to their spacers: a ligand with an aromatic spacer (L1M), ligands with aliphatic spacer (L2M, L3M) and a ligand with no spacer (L4M). The difference between their structures helped us to better understand the coordination chemistry of the corresponding complexes. The nickel(II) complexes formed provided useful background information on the coordination chemistry of iron(II), such as the crystal field stabilization energy (10Dq) value. An approximation of 10Dq value of iron(II) was calculated based on the 10Dq value of analogous nickel(II) complexes using an empirical rule, to provide a prediction of SCO property.
Publisher:
ISBN:
Category :
Languages : en
Pages : 204
Book Description
The major focus of this thesis involves a new approach to spin-crossover (SCO) in iron(II) dinuclear complexes. In order to acquire SCO properties, a series of novel ligands (L1M, L2M, L3M, L4M), together with the corresponding iron(II) and/or nickel(II) complexes were synthesized and characterized. Beyond the successful synthesis and characterization of these ligands, some interesting aspects of their synthesis are discussed. The reported ligands are methyl-derivatives from ligands previously studied in the group. The methyl group in the position 6 of the pyridine group is introduced to induce steric hindrance in the complexes and decrease the ligand field strength. As a result, the influence of the methyl group may induce SCO in low spin (LS) complexes, or tune the SCO properties (such as transition hysteresis or transition temperature) in complexes with SCO. Ligands were divided into three different types according to their spacers: a ligand with an aromatic spacer (L1M), ligands with aliphatic spacer (L2M, L3M) and a ligand with no spacer (L4M). The difference between their structures helped us to better understand the coordination chemistry of the corresponding complexes. The nickel(II) complexes formed provided useful background information on the coordination chemistry of iron(II), such as the crystal field stabilization energy (10Dq) value. An approximation of 10Dq value of iron(II) was calculated based on the 10Dq value of analogous nickel(II) complexes using an empirical rule, to provide a prediction of SCO property.