Synthesis and Characterization of (o-Amidobenzenethiolato)indium Complexes as Green Redox Active Catalysts PDF Download
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Author: Michael Mosher
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 0
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Book Description
Author: Michael Mosher
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 0
Get Book Here
Book Description
Author: Michael Mosher
Publisher:
ISBN:
Category : Green chemistry
Languages : en
Pages : 0
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Book Description
Author: Rachel Vanderkloet
Publisher:
ISBN:
Category : Green chemistry
Languages : en
Pages : 80
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Book Description
Author: Lauren Wentzell
Publisher:
ISBN:
Category : Bismuth compounds
Languages : en
Pages : 96
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Book Description
Author: Padmapriya Srinivasan
Publisher:
ISBN:
Category : Green chemistry
Languages : en
Pages : 0
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Book Description
Green Chemistry initiatives have recently been at the forefront of both industrial and academic communities in order to address fundamental scientific challenges of protecting human health and the environment. The Twelve Principles of Green Chemistry, of which catalysis is a primary tenet and the main motivation for this project, has led the path to reduce waste production in the chemical industry. The principle of catalysis states that catalytic reactions necessarily produce less waste than stoichiometric reactions. Traditionally, precious and toxic heavy transition metals such as platinum and palladium have been used as metal centres in catalysts because of their stability, favourable redox properties, and ease of characterization. These concerns prompted this research in finding more environmentally friendly alternatives as metal centres in catalysis, such as main group complexes. Indium is a heavy main group metal that is environmentally benign. It is most stable in the +3 oxidation state and, notably, does not possess other readily accessible oxidation states. To make indium complexes redox-active, so-called "non-innocent" redox-active ligands are being explored. The current work seeks to synthesize a series of redox-active indium catalysts with varied steric bulk about the indium centre and different redox-active ligands. The goals of this study are to first synthesize and structurally characterize organometallic indium compounds with the redox-active ligand 2-amninobenzenethiol, and then test the reactivity of indium complexes with dithiolate ligands using mild oxidizing agents. A third goal is to use DFT methods to rationalize the synthesized complexes in terms of structure, reactivity, bonding motifs, and in interpreting the experimental spectroscopic data.
