Syntheses, Structures and Properties of Coordination Polymers: Structural Transformation, Heterogenous Catalysis and Luminescence PDF Download
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Author: 楊翔凱
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Languages : en
Pages :
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Author: 楊翔凱
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: 胡季弘
Publisher:
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Category :
Languages : en
Pages : 0
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Author: Ali Morsali
Publisher: John Wiley & Sons
ISBN: 1119370752
Category : Science
Languages : en
Pages : 262
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Book Description
Coordination polymer is a general term used to indicate an infinite array composed of metal ions which are bridged by certain ligands among them. This incorporates a wide range of architectures including simple one-dimensional chains with small ligands to large mesoporous frameworks. Generally, the formation process proceeds automatically and, therefore, is called a self-assembly process. In general, the type and topology of the product generated from the self-assembly of inorganic metal nodes and organic spacers depend on the functionality of the ligand and valences and the geometric needs of the metal ions used. In this book the authors explain main group metal coordination polymer in bulk and nano size with some of their application, synthesis method and etc, The properties of these efficient materials are described at length including magnetism (long-range ordering, spin crossover), porosity (gas storage, ion and guest exchange), non-linear optical activity, chiral networks, reactive networks, heterogeneous catalysis, luminescence, multifunctional materials and other properties.
Author: Mona Feizbakhsh Bazargani
Publisher:
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Languages : de
Pages : 0
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The present work deals with the preparation and characterization of ten new coordination polymers prepared from different metal ions and ligands by different synthetic methods. In addition to the structural characterization of these compounds by means of X-ray singlecrystal diffraction data, the focus is on the consideration of thermal and spectroscopic properties. The new silver coordination polymer exhibits very unique, robust and interesting polymeric structure with high thermal stability. Two new lanthanide coordination polymers (neodymium and samarium) have been synthesized with H2FDA = 2,5-furandicarboxylic acid in DMF as solvent via capped tube method. The compounds are iso-structural and exhibit threedimensional coordination polymers. The goal of using DMF as pure solvent instead of mixture of water and other solvents was to synthesize new coordination polymer which might show very intensive luminescence effect. The investigation has turned out that these compounds emerge no significant luminescence effect. As it has been reported in previous works in which the H2FDA = 2,5-furandicarboxylic acid was used for construction of lanthanide coordination polymers in water as solvent, however the compounds have exposed very interesting luminescence properties [229-230]. A new cerium coordination polymer has been produced with ligand (H2pdc = 3,5-pyrazoledicarboxylic acid) under solvothermal condition in DMF as solvent. Indeed, ligand (H2pdc = 3,5-pyrazoledicarboxylic acid) is very versatile to construct coordination network by various coordination modes. Three copper (I) coordination polymers have been successfully synthesized via solvent diffusion technique in test tube. The compounds all display 1D polymeric structure with rather similar coordination environment around metal ions. Moreover, they are very stable against temperature rising. The compounds [Pb3(CH3COO)2(N3)4]n and [Na2Pb2(CH3COO)6]n were synthesized under same synthesis conditions and starting materials but with different metal salt and ligand ratios. Interestingly, the both products show three-dimentional frameworks, however they expose different coordination structures. Actually, the investigation shows that the changing metal salt and ligand ratio can result in the formation different structures of coordination networks, although they have been produced under same reaction conditions. Compound [Pb(DHBDA)]n has been made with ligand 2,5-Dihydroxy-1,4-benzenediacetic acid which has been reported in very few works for constructing coordination compounds.
Author: 鄭永塘
Publisher:
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Category :
Languages : en
Pages :
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Author: George E. Kostakis
Publisher: MDPI
ISBN: 3038428019
Category : Science
Languages : en
Pages : 131
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This book is a printed edition of the Special Issue "Structural Design and Properties of Coordination Polymers" that was published in Crystals
Author: Rebecca Clulow
Publisher:
ISBN:
Category : Coordination polymers
Languages : en
Pages : 0
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Author: Stuart R. Batten
Publisher: Royal Society of Chemistry
ISBN: 0854048375
Category : Science
Languages : en
Pages : 440
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Book Description
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
Author: Mao-Chun Hong
Publisher: John Wiley & Sons
ISBN: 0470467320
Category : Science
Languages : en
Pages : 428
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Book Description
Design and Construction of Coordination Polymers Edited by Mao-Chun Hong Ling Chen A Unique Resource on coordination Polymers Coordination polymers are a growing, interdisciplinary field with numerous potential applications in chemistry and materials. Design and Construction of Coordination Polymers provides a comprehensive introduction to this field, focusing on synthetic strategies, structures, properties, and potential applications. Each chapter provides a unique perspective on coordination polymers, offering a dedicated approach as well as deeper insights on the most important facets of this interdisciplinary area. Combining the consistent editorial approach of a textbook with the up-to-date data and topics usually found in the latest monographs and handbooks, Design and Construction of Coordination Polymers offers an unparalleled reference to the state of the art. Among other topics, it covers: Coordination polymers with versatile structures Crystal engineering of coordination polymers Organic/inorganic hybrid complexes based on polyoxometalates Molecular-based magnetic and ferroelectric compounds Heavy main-group iodometalates Gas storage MOFs Bioinorganic coordination complexes Addressing a wide range of readers, Design and Construction of Coordination Polymers will prove an invaluable resource to everyone from senior-level undergraduate and graduate students to working scientists.
Author: Francesc X. Llabrés i Xamena
Publisher: Royal Society of Chemistry
ISBN: 1849735727
Category : Science
Languages : en
Pages : 446
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Book Description
This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.
