Study of the Magnetic and Transport Properties of the New Ternary Rare Earth Intermetallic RCrSb3 (R PDF Download
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Author: Michael L. Leonard
Publisher:
ISBN:
Category :
Languages : en
Pages : 154
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Author: Michael L. Leonard
Publisher:
ISBN:
Category :
Languages : en
Pages : 154
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Author: W.E. Wallace
Publisher: Elsevier
ISBN: 032315803X
Category : Science
Languages : en
Pages : 279
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Book Description
Rare Earth Intermetallics provides an account of the magnetic characteristics of rare earth intermetallics. This book discusses bulk magnetic characteristics, such as temperature dependence of susceptibility, saturation magnetization, nature of the cooperative magnetic phase, low temperature specific heats, and related thermal properties. Other topics include the magnetic interactions, crystal field interaction by the operator equivalent method, and rare earth-nontransition metal systems. The miscellaneous IVA compounds, rare earth substitution, variation in the iron moment, and compounds with 4d and 5d transition metals are also elaborated in this text. This publication is recommended for students and researchers interested in rare earth intermetallics.
Author: Andrej Szytula
Publisher: CRC Press
ISBN: 0429607318
Category : Science
Languages : en
Pages : 294
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Book Description
Rare-earth intermetallics, also known as lanthanide elements, play an important role in the study of magnetic materials and the development of semi- and super-conducting materials. This handbook provides an up-to-date compilation of crystallographic, physical, and magnetic data on rare-earth intermetallic compounds. Over 20 different structure types are described in detail with an emphasis on how crystal structure can affect magnetic properties. Theoretical models for magnetic interactions are described as well as the impact of crystal electric fields on transport properties, magneto crystalline anistropy and hyperfine interactions. This book provides materials scientists, engineers and physicists with all the critical information needed to use rare-earth intermetallics effectively in the development of new materials.
Author: Edward Adam Görlich
Publisher:
ISBN: 9788323310747
Category :
Languages : en
Pages : 192
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Book Description
Author: Emil Burzo
Publisher: Springer Nature
ISBN: 3030992454
Category : Science
Languages : en
Pages : 544
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Book Description
This book presents advances in the field of rare-earth (R) – transition metal (M) – boron compounds with extensive references. Since titanium and scandium do not form compounds with rare-earths, the Sc/Ti-M-B series are additionally presented. In each chapter the crystal structures, the complex physical properties as determined from neutron diffraction, magnetic measurements, resonance studies, transport properties and band structure calculations are critical analyzed. The models used in describing the experimental evidence are also presented. Tables with the main properties of the R-M-B compounds are given and representative data are illustrated in figures. In this way, the book provides state-of-the art knowledge and a valuable analysis of up-to-date results in the field. The technical applications, as permanent magnets, thermoelectric and magnetocaloric devices, hydrogen storage are also highlighted along with the authors insights into future directions in the field. The book is of interest for scientists involved in the development of the field as well as those working in the technical uses of rare-earth compounds.
Author: Heike Pfau
Publisher: Springer
ISBN: 3319395432
Category : Technology & Engineering
Languages : en
Pages : 133
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Book Description
This thesis explores thermal transport in selected rare-earth-based intermetallic compounds to answer questions of great current interest. It also sheds light on the interplay of Kondo physics and Fermi surface changes. By performing thermal conductivity and electrical resistivity measurements at temperatures as low as 25mK, the author demonstrates that the Wiedemann–Franz law, a cornerstone of metal physics, is violated at precisely the magnetic-field-induced quantum critical point of the heavy-fermion metal YbRh2Si2. This first-ever observation of a violation has dramatic consequences, as it implies a breakdown of the quasiparticle picture. Utilizing an innovative technique to measure low-temperature thermal transport isothermally as a function of the magnetic field, the thesis interprets specific, partly newly discovered, high-field transitions in CeRu2Si2 and YbRh2Si2 as Lifshitz transitions related to a change in the Fermi surface. Lastly, by applying this new technique to thermal conductivity measurements of the skutterudite superconductor LaPt4Ge12, the thesis proves that the system is a conventional superconductor with a single energy gap. Thus, it refutes the widespread speculations about unconventional Cooper pairing in this material.
Author: Venkateshwarlu Goruganti
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Physical properties of RTX compounds (R = Rare earth, T = Transition metal and X = main group element from B, C or N group) compounds have been studied by means of electrical resistivity, heat capacity, dc magnetization and NMR. Searching for new magnetic materials is always an interesting topic from both a technological and basic research prospective; it is even more interesting when unusual magnetic phases are observed. Ternary intermetallic plumbides are interesting because of their unconventional magnetic ordering and variety of multiple magnetic transitions. Crystalline electric fields (CEF) also strongly effect the magnetic properties of these intermetallics. To understand the phase transitions, CEF effects, and magnetic interactions, a systematic study of the RNiPb, R2Ni2Pb, R5NiPb3 and RCuGe systems were conducted. Among the results for NdNiPb a single antiferromagnetic transition was found at 3.5K, while the superconductivity found in some ingots of this material was shown not to correspond to a bulk behavior for this phase. Nd2Ni2Pb was shown to have a canted zero field magnetic structure with a low temperature metamagnetic transition 3 T. In NdCuGe, a 3K AF transition was found along with a corresponding magnon contribution to the specific heat and magnetic and thermodynamic behavior from which the detailed CEF configuration was obtained. In a series of measurements on recently-synthesized R5NiPb3 (R=Ce, Nd, Gd), for Ce5NiPb3 a transition at 48 K was found, which was confirmed to be ferromagnetic character from field dependent heat capacity and Curie-Weiss susceptibility. Nd5NiPb3 exhibits two transitions, an antiferromagnetic transition at 42 K and an apparently weak ferromagnetic canting transition at 8 K. For Gd5NiPb3, a ferro- or ferrimagnetic transition was found at 68 K. For the Ce and Nd materials metamagnetism was also observed at low temperatures. In addition, very large metallic type [gamma] terms were found in the specific heat, as well as a reduced value of the magnetic entropy, for all three systems. These results imply a lack of ordering for one of the two in-equivalent chains in these materials. This is discussed in terms of possible geometrical frustration on one of the spin chains.
Author: R. Elliott
Publisher: Springer Science & Business Media
ISBN: 1475756917
Category : Technology & Engineering
Languages : en
Pages : 430
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Book Description
The rare earths have a unique place among the elements. Although very much alike chemically and in most phy~ical properties they each have very different and striking magnetic properties. The reason, of course, lies in their 4f electrons which determine the magnetic properties but have little effect on other chemical and physical behaviour. Although they are not rare, some indeed are among the more common heavy elements in the earth's crust, the difficulty of separation has meant that their intricate magnetic properties have only recently been unravelled. Now, however, the general pattern of their magnetism is well charted and the underlying theory is well understood. Both are thoroughly summarised in this book. It provides an excellent example of the kind of extensive synthesis which is possible with modem solid state physics. it represents only a high plateau in the ascent to complete understanding. But It will become clear to the reader that while the overall position is satisfactory there are many details still to be elucidated experimentally and much to be done theoretically before all the underlying forces are identified and estimated from a priori calculations. It is hoped that the book will provide a useful stimulus in this direction. It should also be of use to those who are interested in related disciplines, for example the rare earth compounds, or the transition metals. In addition rare earths promise to be important technologically as alloy constituents.
Author: Karl-Hartmut Müller
Publisher: Springer Science & Business Media
ISBN: 9401007632
Category : Science
Languages : en
Pages : 455
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Book Description
This volume contains most of the contributions presented at the NATO Advanced Research Workshop on Rare Earth Transition Metal Borocarbides (Nitrides): Superconducting, Magnetic and Normal State Properties, held in Dresden, Germany at 13 - 18 June 2000. The Workshop was chaired by K. -H. MUller and V. N. Narozhnyi. This was the first meeting specially focused on the quaternary rare-earth transition-metal borocarbides and nitrides - a new class of magnetic superconductors discovered in 1994. The motivation for organizing this workshop was to bring together scientists (both experimentalists and theoreticians), actively working in this field in different countries, using different methods, to exchange their points of view on the properties ofthese materials and to recognize the directions for future research. Totally 48 participants from 17 countries ofEurope, the United States, BraZil, India, Israel and Japan took part in this meeting. In addition about 15 observers (mainly from Germany) attended. The scientific Programme of the Workshop was composed of 7 sections. The section Introduction and Overview was followed by the Electronic Structure and Properties and Phonon Spectra; Magnetic Properties and CEF Effects; Interplay between Superconductivity and Magnetism; Vortex Lattice; Thin Films; Nature of the Superconducting State in Borocarbides sections. Totally 50 presentations were given (45 ofthem in oral form). Considerable attention was devoted to the characterization of the particular place of borocarbides amongst the other magnetic and superconducting systems and, especially, magnetic superconductors.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
The so called material science is an always growing field in modern research. For the development of new materials not only the experimental characterization but also theoretical calculation of the electronic structure plays an important role. A class of compounds that has attracted a great deal of attention in recent years is known as REME compounds. These compounds are often referred to with RE designating rare earth, actinide or an element from group 1 - 4, M representing a late transition metal from groups 8 - 12, and E belonging to groups 13 - 15. There are more than 2000 compounds with 1:1:1 stoichiometry belonging to this class of compounds and they offer a broad variety of different structure types. Although many REME compounds are know to exist, mainly only structure and magnetism has been determined for these compounds. In particular, in the field of electronic and transport properties relatively few efforts have been made. The main focus in this study is on compounds crystallizing in MgAgAs and LiGaGe structure. Both structures can only be found among 18 valence electron compounds. The f electrons are localized and therefor not count as valence electrons. A special focus here was also on the magnetoresistance effects and spintronic properties found among the REME compounds. An examination of the following compounds was made: GdAuE (E = In, Cd, Mg), GdPdSb, GdNiSb, REAuSn (RE = Gd, Er, Tm) and RENiBi (RE = Pr, Sm, Gd - Tm, Lu). The experimental results were compared with theoretic band structure calculations. The first half metallic ferromagnet with LiGaGe structure (GdPdSb) was found. All semiconducting REME compounds with MgAgAs structure show giant magnetoresistance (GMR) at low temperatures. The GMR is related to a metal-insulator transition, and the value of the GMR depends on the value of the spin-orbit coupling. Inhomogeneous DyNiBi samples show a small positive MR at low temperature that depends on the amount of metallic impurities. At higher field.
