Studies on the Anodic Polarization of Zirconium and Zirconium Alloys

Studies on the Anodic Polarization of Zirconium and Zirconium Alloys PDF Author: Mario Maraghini
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Category : Oxidation
Languages : en
Pages : 64

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Studies on the Anodic Polarization of Zirconium

Studies on the Anodic Polarization of Zirconium PDF Author: Geroge B. Jr Adams
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Category : Chemical reactions
Languages : en
Pages : 40

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STUDIES ON THE ANODIC POLARIZATION OF ZIRCONIUM--GROWTH RATES AND THICKNESSES OF THE VERY THIN ANODIC OXIDE FILMS.

STUDIES ON THE ANODIC POLARIZATION OF ZIRCONIUM--GROWTH RATES AND THICKNESSES OF THE VERY THIN ANODIC OXIDE FILMS. PDF Author:
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Category :
Languages : en
Pages :

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Formation Fields and Current Efficiencies in the Anodic Oxidation of Zirconium

Formation Fields and Current Efficiencies in the Anodic Oxidation of Zirconium PDF Author: George Baker Adams
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Category : Electrolytic oxidation
Languages : en
Pages : 38

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Zirconium

Zirconium PDF Author: Hugh Ellison Voress
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Category : Zirconium
Languages : en
Pages : 46

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Electrochemical and Polarographic Studies on the Corrosion of Zirconium in Presence of Various Aqueous Media

Electrochemical and Polarographic Studies on the Corrosion of Zirconium in Presence of Various Aqueous Media PDF Author: George B. Adams (Jr.)
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Category : Mineralogy
Languages : en
Pages : 14

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Catalog of Technical Reports

Catalog of Technical Reports PDF Author: United States. Dept. of Commerce. Office of Technical Services
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Category :
Languages : en
Pages : 742

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Study of the Characteristics of the Corrosion Film on Zirconium Using Polarized Light

Study of the Characteristics of the Corrosion Film on Zirconium Using Polarized Light PDF Author: Nels Roland Nelson
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Category : Zirconium
Languages : en
Pages : 224

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THE ELECTROCHEMICAL POLARIZATION OF ZIRCONIUM IN NACL SOLUTIONS.

THE ELECTROCHEMICAL POLARIZATION OF ZIRCONIUM IN NACL SOLUTIONS. PDF Author:
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Category :
Languages : en
Pages : 54

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Cathodic and anodic polarization curves of Zr in neutral NaCl solution were determined at constant current densities in the range of 3.5 x 10 to the power of -8 to 3.5 x 10 to the power of -3 amp/sq cm. All potentials were steady state. In aerated 0.5 M NaCl, the cathode reaction occurring below the O limiting diffusion current of 2 x 10 to the power of -4 amp/sq cm was the reduction of O to OH. At current densities above the diffusion wave, H was evolved. A change in salt concentration resulted in a slight shift of the diffusion current due to different O solubilities in the different salt concentrations. In deaerated 0.5 M chloride solution, the O diffusion current decreased with a decrease in O concentration. The value for the slope of the Tafel line was 0.12, and the H overvoltage was 0.83 v at 1 ma/sq cm. Another wave occurred at 2 x 10 to the power of -6 amp/sq cm and can best be explained as the reduction of a surface oxide layer on the metal. Anodically, Zr dissolved in 0.5 M NaCl. The dissolution potential, 0.15 v, was constant with a change in current density. Commercial Zr and pure Hf also dissolved under similar conditions. In neutral sulfate solutions, Zr was passive under anodic treatment. At the higher current densities, above 1 x 10 to the power of -3 amp/sq cm, the potential apparently reached a constant value in about 10 min, followed by a sudden increase in potential to 28.5 v. This high potential was a result of an IR drop across a surface of oxide present on the Zr coupon.

TID.

TID. PDF Author:
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ISBN:
Category : Energy development
Languages : en
Pages : 146

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