The Structure of Ionic Liquids PDF Download
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Author: Ruggero Caminiti
Publisher: Springer Science & Business Media
ISBN: 3319016989
Category : Science
Languages : en
Pages : 202
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Book Description
This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.
Author: Ruggero Caminiti
Publisher: Springer Science & Business Media
ISBN: 3319016989
Category : Science
Languages : en
Pages : 202
Get Book Here
Book Description
This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.
Author: H. S. Green
Publisher: Springer Science & Business Media
ISBN: 3642459471
Category : Science
Languages : en
Pages : 326
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Book Description
135 We first describe the thermodynamic theory of surface tension and adsorption, by the method of the dividing surface of GIBBS. The use of a dividing surface or its equivalent is indispensable for the treatment of a curved interface, as otherwise the concepts of the area and curvature of the interface, cannot be pre cisely defined. In the case of a plane interface, however, the concept of the dividing surface is not necessary and a valid alternative exposition has been proposed by GUGGEN HEIM [3J, [4J in treating the interface zone as a separate entity of some definite thickness bounded by two mathematical planes. We make, however, little mention of this method, since it seems to be of only minor importance in connec tion with the statistical treatment of an interface. To avoid any ambiguity, the treatment of a spherical interface given in this article is based not on the original method of GIBBS but on the method modified by HILL [8J and KONDO [9]. This method, however, is not applicable to non spherical interfaces, which will not be dealt with in this article. Although all the relations for a plane interface can be deduced from the cor responding ones for a spherical interface by putting the curvature equal to zero, the planar and the spherical cases are considered separately because of the prac tical importance and easy physical visualization of a plane interface.
Author: Kendall N. Houk
Publisher: Springer
ISBN: 9783540074847
Category : Science
Languages : en
Pages : 208
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Book Description
Author: Sigmund Flügge
Publisher:
ISBN:
Category : Physics
Languages : en
Pages :
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Book Description
Author: Thomas J. Hughel
Publisher:
ISBN:
Category : Liquids
Languages : en
Pages : 404
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Book Description
Introductory remarks / R.L. Smith -- Free volume model of the liquid state / David Turnbull -- The geometry of the structure of liquids / J.D. Bernal -- A brief review of some aspects of the molecular theory of liquids / Stuart A. Rice -- Transport processes, correlation functions, and reciprocity relations in dense media / I. Prigogine -- An outline of the theory of transport properties / N.F. Mott -- X-ray and neutron diffraction studies of liquid structure / Newell S. Gingrich -- Inelastic neutron scattering by liquids / H. Palevsky -- Proton magnetic resonance studies of compounds with the structure (CH3)4X / George W. Smith -- Viscosity anomalies and other pre-freezing pheonomena / A.R. Ubbelohde -- Surface tension of liquid metals and oxide melts / Paul Kozakevitch -- Importance of the surface tension of metals in some engineering problems / D.J. Harvey -- Dynamic nucleation / Bruce Chalmers -- Eutectic solidification / G.A. Chadwick -- Deviation from the normal fusion curve / Donald L. Ball.
Author: D Eisenberg
Publisher: Oxford University Press, USA
ISBN: 0198570260
Category : Science
Languages : en
Pages : 315
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Book Description
The authors have correlated many experimental observations and theoretical discussions from the scientific literature on water. Topics covered include the water molecule and forces between water molecules; the thermodynamic properties of steam; the structures of the ices; the thermodynamic, electrical, spectroscopic, and transport properties of the ices and of liquid water; hydrogen bonding in ice and water; and models for liquid water. The main emphasis of the book is on relatingthe properties of ice and water to their structures. Some background material in physical chemistry has been included in order to ensure that the material is accessible to readers in fields such as biology, biochemistry, and geology, as well as to chemists and physicists.
Author: S. Flügge
Publisher: Springer Verlag
ISBN: 9780387025490
Category : Science
Languages : en
Pages : 320
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Book Description
Author: Paola Gallo
Publisher: Springer Nature
ISBN: 3030683494
Category : Science
Languages : en
Pages : 329
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Book Description
This book offers a didactic and a self-contained treatment of the physics of liquid and flowing matter with a statistical mechanics approach. Experimental and theoretical methods that were developed to study fluids are now frequently applied to a number of more complex systems generically referred to as soft matter. As for simple liquids, also for complex fluids it is important to understand how their macroscopic behavior is determined by the interactions between the component units. Moreover, in recent years new and relevant insights have emerged from the study of anomalous phases and metastable states of matter. In addition to the traditional topics concerning fluids in normal conditions, the authors of this book discuss recent developments in the field of disordered systems in condensed and soft matter. In particular they emphasize computer simulation techniques that are used in the study of soft matter and the theories and study of slow glassy dynamics. For these reasons the book includes a specific chapter about metastability, supercooled liquids and glass transition. The book is written for graduate students and active researchers in the field.
Author: Roland Kjellander
Publisher: CRC Press
ISBN: 1482244047
Category : Science
Languages : en
Pages : 557
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Book Description
The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications for many industrial applications. This book shows how you can start from basic laws for the interactions and motions of microscopic particles and calculate how macroscopic systems of these particles behave, thereby explaining properties of matter at the scale that we perceive. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author’s treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book also provides an expanded, in-depth treatment of polar liquids and electrolytes.
Author: Jannis Samios
Publisher: Springer Science & Business Media
ISBN: 1402023847
Category : Science
Languages : en
Pages : 548
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Book Description
The unique behavior of the "liquid state", together with the richness of phenomena that are observed, render liquids particularly interesting for the scientific community. Note that the most important reactions in chemical and biological systems take place in solutions and liquid-like environments. Additionally, liquids are utilized for numerous industrial applications. It is for these reasons that the understanding of their properties at the molecular level is of foremost interest in many fields of science and engineering. What can be said with certainty is that both the experimental and theoretical studies of the liquid state have a long and rich history, so that one might suppose this to be essentially a solved problem. It should be emphasized, however, that although, for more than a century, the overall scientific effort has led to a considerable progress, our understanding of the properties of the liquid systems is still incomplete and there is still more to be explored. Basic reason for this is the "many body" character of the particle interactions in liquids and the lack of long-range order, which introduce in liquid state theory and existing simulation techniques a number of conceptual and technical problems that require specific approaches. Also, many of the elementary processes that take place in liquids, including molecular translational, rotational and vibrational motions (Trans. -Rot. -Vib. coupling), structural relaxation, energy dissipation and especially chemical changes in reactive systems occur at different and/or extremely short timescales.
