Structure-dissolution Relationships of Phosphate and Bioactive Glasses by Liquid, Solid-state and Paramagnetic NMR PDF Download
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Author: Dahiana Andrea Avila Salazar
Publisher:
ISBN:
Category :
Languages : de
Pages : 0
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Book Description
The doctoral thesis comprises a study of the relationships between structure and dissolution behaviour of phosphate and bioactive glasses by employing analytical techniques such as electron paramagnetic resonance (EPR), liquid NMR, solid-state MAS NMR and paramagnetic NMR spectroscopy, among others. The understanding of the corrosion processes of phosphate glasses is important for their technological applications, e.g. drug delivery, antibacterials and tissue engineering. In the present work, the NMR findings provided insights about the role of cations on the mechanism of hydrolysis of phosphate glasses. The incorporation of cobalt into glasses is a new approach to overcome the vascularization limitation in tissue engineering by stimulating the production of blood vessels. These glasses are also interesting as semiconductors, optical devices and solid-state lasers, among others. This work shows that structural (i.e. thermal) properties of cobalt phosphate glasses with constant basicity are dictated by the coordination number of Co2+ sites. The second part of the study on cobalt phosphate glasses is in publication process under the title: "Co2+ as an internal paramagnetic 31P NMR probe for structural analysis of cobalt-phosphate glasses in the solid-state and leachate solutions". This work presents a new approach to investigate the mechanism of dissolution of phosphate glasses based on the paramagnetic effects. Accordingly, features such as the spin-orbit (SO) coupling, zero-field splitting (ZFS) and symmetry of Co2+ sites are correlated to the paramagnetic shift, paramagnetic relaxation enhancement (PRE) and broadening effects on the spectra. That allows the assessment of the distribution of Co2+ ions in the glass network. Additionally, it enables monitoring structural dynamics of phosphate complexes in solution, including conformational changes, upon ligand binding recognition under different conditions, i.e. buffer aqueous solutions (Tris, EDTA).
Author: Dahiana Andrea Avila Salazar
Publisher:
ISBN:
Category :
Languages : de
Pages : 0
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Book Description
The doctoral thesis comprises a study of the relationships between structure and dissolution behaviour of phosphate and bioactive glasses by employing analytical techniques such as electron paramagnetic resonance (EPR), liquid NMR, solid-state MAS NMR and paramagnetic NMR spectroscopy, among others. The understanding of the corrosion processes of phosphate glasses is important for their technological applications, e.g. drug delivery, antibacterials and tissue engineering. In the present work, the NMR findings provided insights about the role of cations on the mechanism of hydrolysis of phosphate glasses. The incorporation of cobalt into glasses is a new approach to overcome the vascularization limitation in tissue engineering by stimulating the production of blood vessels. These glasses are also interesting as semiconductors, optical devices and solid-state lasers, among others. This work shows that structural (i.e. thermal) properties of cobalt phosphate glasses with constant basicity are dictated by the coordination number of Co2+ sites. The second part of the study on cobalt phosphate glasses is in publication process under the title: "Co2+ as an internal paramagnetic 31P NMR probe for structural analysis of cobalt-phosphate glasses in the solid-state and leachate solutions". This work presents a new approach to investigate the mechanism of dissolution of phosphate glasses based on the paramagnetic effects. Accordingly, features such as the spin-orbit (SO) coupling, zero-field splitting (ZFS) and symmetry of Co2+ sites are correlated to the paramagnetic shift, paramagnetic relaxation enhancement (PRE) and broadening effects on the spectra. That allows the assessment of the distribution of Co2+ ions in the glass network. Additionally, it enables monitoring structural dynamics of phosphate complexes in solution, including conformational changes, upon ligand binding recognition under different conditions, i.e. buffer aqueous solutions (Tris, EDTA).
Author: Akiko Obata
Publisher: Royal Society of Chemistry
ISBN: 1839161647
Category : Technology & Engineering
Languages : en
Pages : 297
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Book Description
Inorganic glasses are successfully used in the biomedical field, in particular degradable glasses have found applications in tissue engineering, bone regeneration and tooth remineralisation. Silicate glasses are the most commonly used ones but phosphate and borate glasses are attracting more and more interest owing to their special properties, differing from those of silicate bio-glasses. Phosphate and borate glasses thus open up potential routes for new therapeutic applications. This book focuses on these emerging materials. Bridging the phosphate and borate glasses communities, this book provides a fundamental treatment of atomic structure and physicochemical properties before highlighting their current and potential future applications. Phosphate and borate glasses not only feature a broader range of glass formation than silicate glasses. Their ability to completely dissolve in water with the solubility varying over orders of magnitude with compositional changes, makes them exciting materials for delivering therapeutic agents into the human body. Biomaterials scientists working in glasses, hard tissue engineering and regenerative medicine will find this a must-have book to own, alongside their more traditional silicate glass tomes.
Author: Yaqoot Shaharyar
Publisher:
ISBN:
Category : Fluoride glasses
Languages : en
Pages : 45
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Book Description
Author: Zahid Amjad
Publisher: Springer Science & Business Media
ISBN: 1461555175
Category : Technology & Engineering
Languages : en
Pages : 509
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Book Description
Calcium Phosphates in Biological and Industrial Systems provides a comprehensive discussion on calcium phosphates in the diverse areas of their applications. The authors are all respected specialists in their particular fields, possessing wide knowledge and experience and able to analyze recent results and relate them to their respective areas of expertise. New information, as well as a review of current concepts, highlights the individual contributions. Due to the broad scope of the subject covered and the large number of contributions, this book is divided into three parts. Whilst each section contains a basic theme, there is a considerable overlapping of ideas and approaches. This reflects the excitement and interdisciplinary nature of investigations by researchers interested in dissimilar aspects of calcium phosphates. Considering the general interest in calcium phosphates, Calcium Phosphates in Biological and Industrial Systems is directed at an audience of researchers in the fields of biology, chemistry, dentistry, geology, chemical engineering, environmental engineering, and medicine. It will also be useful to technology-focused researchers in industry whose investigations might be related directly or indirectly to calcium phosphates.
Author: James E Shelby
Publisher: Royal Society of Chemistry
ISBN: 1782625119
Category : Technology & Engineering
Languages : en
Pages : 320
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Book Description
This book provides a concise and inexpensive introduction for an undergraduate course in glass science and technology. The level of the book has deliberately been maintained at the introductory level to avoid confusion of the student by inclusion of more advanced material, and is unique in that its text is limited to the amount suitable for a one term course for students in materials science, ceramics or inorganic chemistry. The contents cover the fundamental topics of importance in glass science and technology, including glass formation, crystallization, phase separation and structure of glasses. Additional chapters discuss the most important properties of glasses, including discussion of physical, optical, electrical, chemical and mechanical properties. A final chapter provides an introduction to a number of methods used to form technical glasses, including glass sheet, bottles, insulation fibre, optical fibres and other common commercial products. In addition, the book contains discussion of the effects of phase separation and crystallization on the properties of glasses, which is neglected in other texts. Although intended primarily as a textbook, Introduction to Glass Science and Technology will also be invaluable to the engineer or scientist who desires more knowledge regarding the formation, properties and production of glass.
Author: Vahak Marghussian
Publisher: William Andrew
ISBN: 0323354327
Category : Technology & Engineering
Languages : en
Pages : 293
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Book Description
Nano-Glass Ceramics: Processing, Properties and Applications provides comprehensive coverage of synthesis and processing methods, properties and applications of the most important types of nano-glass ceramics, from a unique material science perspective. Emphasis is placed on the experimental and practical aspects of the subject while covering the theoretical and practical aspects and presenting, numerous examples and details of experimental methods. In the discussing the many varied applications of nano-glass ceramics, consideration is given to both, the fields of applications in which the materials are firmly established and the fields where great promise exists for their future exploitation. The methods of investigation adopted by researchers in the various stages of synthesis, nucleation, processing and characterization of glass ceramics are discussed with a focus on the more novel methods and the state of the art in developing nanostructured glass ceramics. Comprehensive coverage of nanostructured glass ceramics with a materials science approach. The first book of this kind Applications-oriented approach, covering current and future applications in numerous fields such as Biomedicine and Electronics Explains the correlations between synthesis parameters, properties and applications guiding R&D researchers and engineers to choose the right material and increase cost-effectiveness
Author: Olga V. Frank-Kamenetskaya
Publisher: Springer Nature
ISBN: 3030216144
Category : Science
Languages : en
Pages : 900
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Book Description
The book represents a collection of papers presented at VI International Symposium "Biogenic - abiogenic interactions in natural and anthropogenic systems" that was held on 24-27 September 2018 in Saint Petersburg (Russia). Papers in this book cover a wide range of topics connecting with interactions between biogenic and abiogenic components in lithosphere, biosphere and technosphere. The main regarding topics are following: methods for studying the interactions between biogenic and abiogenic components; geochemistry of biogenic-abiogenic systems; biomineralization and nature-like materials and technologies; medical geology; biomineralogy and organic mineralogy; biomineral interactions in soil; biodeterioration of natural and artificial materials; biomineral interactions in extreme environment.
Author: Aldo R Boccaccini
Publisher: Royal Society of Chemistry
ISBN: 1782622012
Category : Science
Languages : en
Pages : 551
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Book Description
The global ageing society has significantly increased the need for implant materials, which not only replace damaged or lost tissue but are also able to regenerate it. The field of bioactive glasses has been expanding continuously over recent years as they have been shown to bond with hard and soft tissue, release therapeutically active ions, and be capable of enhancing bone formation and regeneration. In addition, they are successfully being used to re-mineralise teeth, thereby making bioactive glasses highly attractive materials in both dentistry and medicine. Understanding the multidisciplinary requirements set by the human body’s environment and the special characteristics of the different families of bioactive glasses is a key in developing new compositions to novel clinical applications. Bioactive Glasses aims to bridge the different scientific communities associated with the field of bioactive glasses with focus on the materials science point of view. Emerging applications covered include soft tissue regeneration, wound healing, vascularisation, cancer treatment and drug delivery devices. This book provides a comprehensive overview of the latest applications of bioactive glasses for material scientists.
Author: Bradley D. Fahlman
Publisher: Springer
ISBN: 9402412557
Category : Technology & Engineering
Languages : en
Pages : 817
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Book Description
The 3rd edition of this successful textbook continues to build on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field — in a concise format. The 3rd edition offers significant updates throughout, with expanded sections on sustainability, energy storage, metal-organic frameworks, solid electrolytes, solvothermal/microwave syntheses, integrated circuits, and nanotoxicity. Most appropriate for Junior/Senior undergraduate students, as well as first-year graduate students in chemistry, physics, or engineering fields, Materials Chemistry may also serve as a valuable reference to industrial researchers. Each chapter concludes with a section that describes important materials applications, and an updated list of thought-provoking questions.
Author: William Murphy
Publisher: Springer
ISBN: 1493933051
Category : Technology & Engineering
Languages : en
Pages : 676
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Book Description
This book provides tabular and text data relating to normal and diseased tissue materials and materials used in medical devices. Comprehensive and practical for students, researchers, engineers, and practicing physicians who use implants, this book considers the materials aspects of both implantable materials and natural tissues and fluids. Examples of materials and topics covered include titanium, elastomers, degradable biomaterials, composites, scaffold materials for tissue engineering, dental implants, sterilization effects on material properties, metallic alloys, and much more. Each chapter author considers the intrinsic and interactive properties of biomaterials, as well as their appropriate applications and historical contexts. Now in an updated second edition, this book also contains two new chapters on the cornea and on vocal folds, as well as updated insights, data, and citations for several chapters.
