Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties PDF full book. Access full book title Stereoselective Synthesis of Cyclometalated Iridium(III) Complexes: Characterization and Photophysical Properties by . Download full books in PDF and EPUB format.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 208
Get Book Here
Book Description
Author: Ahmed M. Soliman
Publisher:
ISBN:
Category :
Languages : en
Pages : 330
Get Book Here
Book Description
Author: Liana Ghizdavu
Publisher:
ISBN:
Category :
Languages : en
Pages : 134
Get Book Here
Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Get Book Here
Book Description
Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl2)3]6 unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.
Author: Brian Thomas Lottig
Publisher:
ISBN:
Category : Iridium
Languages : en
Pages : 178
Get Book Here
Book Description
Author: Travis Wayne Hesterberg
Publisher:
ISBN:
Category :
Languages : en
Pages : 312
Get Book Here
Book Description
Conducting metallopolymers have been investigated for a variety of applications due to their ability to take advantage of both the mechanical processability of the polymer material, as well as the optical and electronic properties of the metal. Our project goal is to design, synthesize and characterize novel iridium(III)-containing conducting metallopolymers for use as the active layer in polymer light-emitting diodes. We have utilized thiophene functionalized ligands that can be readily electropolymerized into conducting polymer thin films and can be easily incorporated into a device structure. Iridium(III) was chosen as the metal center due to its promising photophysical properties, as similar complexes have demonstrated high luminescent quantum yields and short phosphorescent lifetimes. The coordination environment around the metal can be altered synthetically to tune the emission wavelength across the visible spectrum. The synthetic control over the polymer backbone, as well as the iridium(III) ligand environment, allowed us to independently vary each component, which has provided a variety of materials. The materials are characterized through 1H and 13C NMR, mass spectrometry, elemental analysis, electrochemistry, X-Ray diffraction and X-Ray Photoelectron Spectroscopy. The photophysical properties of the materials are studied through UV-Visible absorption spectroscopy, UV-Vis-NIR spectroelectrochemistry and steady-state/ time-resolved emission spectroscopy.
Author: Dana Carabillo
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 48
Get Book Here
Book Description
Author: American Chemical Society
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 1042
Get Book Here
Book Description
Author: Iwao Omae
Publisher: Springer Science & Business Media
ISBN: 4431546049
Category : Science
Languages : en
Pages : 214
Get Book Here
Book Description
This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
