Statistical Mechanics of Assemblies of Charged Particles PDF Download
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Author: Barry William Ninham
Publisher:
ISBN:
Category : Particles
Languages : en
Pages : 366
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Book Description
Author: Barry William Ninham
Publisher:
ISBN:
Category : Particles
Languages : en
Pages : 366
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Book Description
Author: Douglas John Mitchell
Publisher:
ISBN:
Category : Many-body problem
Languages : en
Pages :
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Book Description
Author: Radu Balescu
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 510
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Book Description
Author: B. W. Ninham
Publisher:
ISBN:
Category : Particles
Languages : en
Pages : 366
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Book Description
Author: Herbert Spohn
Publisher: Cambridge University Press
ISBN: 1009402277
Category : Science
Languages : en
Pages : 379
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Author: Nikolay Vladimirovic Shestopalov
Publisher:
ISBN:
Category :
Languages : en
Pages : 180
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Book Description
Self-assembly is a process of non-intrusive transformation of a system from a disordered to an ordered state. For engineering purposes, self-assembly of microscopic objects can benefit significantly from macroscopic guidance and control. This dissertation is concerned with controlling self-assembly in binary monolayers of electrically charged particles that follow basic laws of statistical mechanics. First, a simple macroscopic model is used to determine an optimal thermal control for self-assembly. The model assumes that a single rate-controlling mechanism is responsible for the formation of spatially ordered structures and that its rate follows an Arrhenius form. The model parameters are obtained using molecular dynamics simulations. The optimal control is derived in an analytical form using classical optimization methods. Two major lessons were learned from that work: (i) isothermal control was almost as effective as optimal time-dependent thermal control, and (ii) neither electrostatic interactions nor thermal control were particularly effective in eliminating voids formed during self-assembly. Accordingly, at the next stage, the focus is on temperature-pressure control under isothermal-isobaric conditions. In identifying optimal temperature and pressure conditions, several assumptions, that allow one to relate the optimal conditions to the phase diagram, are proposed. Instead of verifying the individual assumptions, the entire approach is verified using molecular dynamics simulations. It is estimated that under optimal isothermal-isobaric conditions the rate of self-assembly is about five time faster than that under optimal temperature control conditions. It is argued that the proposed approach of relating optimal conditions to the phase diagram is applicable to other systems. Further, the work reveals numerous and useful parallels between self-assembly and crystal physics, which are important to exploit for developing robust engineering self-assembly processes.
Author: F. Rohrlich
Publisher: World Scientific
ISBN: 9812700048
Category : Science
Languages : en
Pages : 323
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Book Description
Originally written in 1964, this famous text is a study of the classical theory of charged particles. Many applications treat electrons as point particles. At the same time, there is a widespread belief that the theory of point particles is beset with various difficulties such as an infinite electrostatic self-energy, a rather doubtful equation of motion which admits physically meaningless solutions, violation of causality and others. The classical theory of charged particles has been largely ignored and has been left in an incomplete state since the discovery of quantum mechanics. Despite the great efforts of men such as Lorentz, Abraham, Poincar, and Dirac, it is usually regarded as a ?lost cause?. But thanks to progress made just a few years ago, the author is able to resolve the various problems and to complete this unfinished theory successfully.
Author: Bruce Berne
Publisher: Springer Science & Business Media
ISBN: 1468425536
Category : Science
Languages : en
Pages : 253
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Book Description
The last decade has been marked by a rapid growth in statistical mechanics, especially in connection with the physics and chemistry of the fluid state. Our understanding in these areas has been considerably advanced and enriched by the discovery of new techniques and the sharpening of old techniques, ranging all the way from computer simulation to mode-mode coupling theories. Statistical mechanics brings together under one roof a broad spectrum of mathematical techniques. The aim of these volumes is to provide a didactic treatment of those techniques that are most useful for the study of problems of current interest to theoretical chemists. The emphasis throughout is on the techniques themselves and not on reviewing the enormous literature in statistical mechanics. Each author was charged with the following task. Given N pages, (a) pose the problem, (b) present those aspects of the particular technique that clearly illustrate its internal workings, (c) apply the technique to the solution of several illustrative examples, and (d) write the chapter so that it will enable the reader to approach key citations to the literature intelligently. These volumes are designed for graduate students and research workers in statistical mechanics. Nevertheless, because of the range of techniques and their general utility, they should be useful in other areas as well.
Author: R. Balescu
Publisher:
ISBN:
Category :
Languages : en
Pages : 477
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Book Description
Author: Avijit Lahiri
Publisher: Avijit Lahiri
ISBN:
Category : Science
Languages : en
Pages : 1623
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Book Description
Equilibrium and Non-equilibrium Statistical Mechanics is a source-book of great value to college and university students embarking upon a serious reading of Statistical Mechanics, and is likely to be of interest to teachers of the subject as well. Written in a lucid style, the book builds up the subject from basics, and goes on to quite advanced and modern developments, giving an overview of the entire framework of statistical mechanics. The equilibrium ensembles of quantum and classical statistical mechanics are introduced at length, indicating their relation to equilibrium states of thermodynamic systems, and the applications of these ensembles in the case of the ideal gas are worked out, pointing out the relevance of the ideal gas in respect of a number of real-life systems. The application to interacting systems is then taken up by way of explaining the virial expansion of a dilute gas. The book then deals with a number of foundational questions relating to the existence of the thermodynamic limit and to the equivalence of the various equilibrium ensembles. The relevance of the thermodynamic limit in explaining phase transitions is indicated with reference to the Yang-Lee theory and the Kirkwood-Salsburg equations for correlation functions. The statistical mechanics of interacting systems is then taken up again, with reference to the 1D and 2D Ising model and to the spin glass model of disordered systems. Applications of the Mean field theory are worked out, explaining the Landau-Ginzburg theory, which is then followed by the renormalization group approach to phase transitions. Interacting systems in the quantum context are referred to, addressing separately the cases of interacting bosons and fermions. The case of the weakly interacting bosons is explained in details, while the Landau theory for fermi liquids is also explained in outline. The book then goes on to a modern but readable account of non-equilibrium statistical mechanics, explaining the link with irreversible thermodynamcs. After an exposition of the Boltzmann equations and the linear response theory illustrated with reference to the hydrodynamic model, it explains the statistical mechanics of reduced systems, in the context of a number of reduction schemes. This is followed by an account of the relevance of dynamical chaos in laying down the foundations of classical statistical mechanics, where the SRB distributon is introduced in the context of non-equilibrium steady states, with reference to which the principle of minimum entropy production is explaned. A number of basic fluctuation relations are then worked out, pointing out their relation to irreversible thermodynamics. Finally, the book explains the relevance of quantum chaos in addressing foundational issues in quantum statistical mechanics, beginning with Berry’s conjecture and then going on to an exposition of the eigenstate thermalization (ETH) hypothesis, indicating how the latter is relevant in explaining the processes of equilibriation and thermalization in thermodynamic systems and their sub-systems.
