Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations PDF Download
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Author: Kelly A. Davis
Publisher: Springer Science & Business Media
ISBN: 3540458069
Category : Technology & Engineering
Languages : en
Pages : 202
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Book Description
The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.
Author: Kelly A. Davis
Publisher: Springer Science & Business Media
ISBN: 3540458069
Category : Technology & Engineering
Languages : en
Pages : 202
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Book Description
The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.
Author: Hisashi Yamamoto
Publisher: John Wiley & Sons
ISBN: 3527345884
Category : Science
Languages : en
Pages : 428
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Book Description
Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemistry. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more.
Author: Jorge Coelho
Publisher: Springer Science & Business Media
ISBN: 9400760108
Category : Medical
Languages : en
Pages : 433
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Book Description
This book is part of a series dedicated to recent advances on preventive, predictive and personalised medicine (PPPM). It focuses on the theme of “Drug delivery systems: advanced technologies potentially applicable in personalised treatments”. The critical topics involving the development and preparation of effective drug delivery systems, such as: polymers available, self-assembly, nanotechnology, pharmaceutical formulations, three dimensional structures, molecular modeling, tailor-made solutions and technological tendencies, are carefully discussed. The understanding of these areas constitutes a paramount route to establish personalised and effective solutions for specific diseases and individuals.
Author: Munmaya Mishra
Publisher: CRC Press
ISBN: 135165120X
Category : Medical
Languages : en
Pages : 2856
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Book Description
The Concise Encyclopedia of Biomedical Polymers and Polymeric Biomaterials presents new and selected content from the 11-volume Biomedical Polymers and Polymeric Biomaterials Encyclopedia. The carefully culled content includes groundbreaking work from the earlier published work as well as exclusive online material added since its publication in print. A diverse and global team of renowned scientists provide cutting edge information concerning polymers and polymeric biomaterials. Acknowledging the evolving nature of the field, the encyclopedia also features newly added content in areas such as tissue engineering, tissue repair and reconstruction, and biomimetic materials.
Author: Nicolay V Tsarevsky
Publisher: Royal Society of Chemistry
ISBN: 1849737428
Category : Science
Languages : en
Pages : 364
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Book Description
Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.
Author: Jean-François Lutz
Publisher: John Wiley & Sons
ISBN: 3527342370
Category : Technology & Engineering
Languages : en
Pages : 532
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Book Description
Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.
Author: Bruno Ameduri
Publisher: Elsevier
ISBN: 0080474829
Category : Technology & Engineering
Languages : en
Pages : 508
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Book Description
Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today’s engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells For immediate use by today's engineers, industrial and academic scientists, and researchers Written to enable self-managed reading and learning, being both a source of data and a reference
Author: James E. Mark
Publisher: Academic Press
ISBN: 0123948320
Category : Technology & Engineering
Languages : en
Pages : 801
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Book Description
The 4e of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in previous editions, the emphasis remains on a unified treatment of the material, exploring chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Updated material stresses the continuous relationship between ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. Exciting new developments in green tire manufacturing and tire recycling are covered. Provides a complete survey of elastomers for engineers and researchers in a unified treatment: from chemical aspects like elastomer synthesis and curing to the final applications of rubber, including tire engineering and manufacturing Contains important updates to several chapters, including elastomer synthesis, characterization, viscoelastic behavior, rheology, reinforcement, tire engineering, and recycling Includes a new chapter on the burgeoning field of bioelastomers
Author: Krzysztof Matyjaszewski
Publisher:
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 444
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Book Description
Recent progress in the field of controlled/living radical polymerization.
Author: Peidong Yang
Publisher: World Scientific
ISBN: 9814485713
Category : Science
Languages : en
Pages : 386
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Book Description
This important book reviews extensively the preparative chemistry of various nanostructured materials, as well as structural-property correlations for these new materials. Materials of current interest, such as nanocrystals, nanowires, nanotubes, porous materials, and composites, are comprehensively covered.
