Some Studies on Complexes Formed Between Transition Metals and Tertiary Phosphines PDF Download
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Author: John Michael Jenkins
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: John Michael Jenkins
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Louis M. Pignolet
Publisher: Springer Science & Business Media
ISBN: 1461336236
Category : Science
Languages : en
Pages : 494
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Book Description
The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 480
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An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: Najeeb Abdul Munem Al-Salem
Publisher:
ISBN:
Category :
Languages : en
Pages : 444
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Author: Edward Joseph Lukosius
Publisher:
ISBN:
Category : Transition metal compounds
Languages : en
Pages : 268
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Author: Ezra Eddy Isaacs
Publisher:
ISBN:
Category : Organometallic chemistry
Languages : en
Pages : 0
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The reaction of cycloheptatrienyltricarbonyl molybdenum cation with various main group V donor ligands (L) yielded, in general, mono-substituted complexes, [C[subscript 7]H[subscript 7]Mo(CO)[subscript 2]L][superscript +]. [superscript 31]P nmr studies on some related di-tertiary phosphine complexes provided a convenient and unequivocal determination of the stereochemistry. The reduction of the cationic cycloheptatrienyl complexes with sodium borohydride provided a suitable synthetic route to the group V derivatives of cyclo- heptatrienetricarbonylmolybdenum. The infrared, [superscript l]H and [superscript 13]C nmr, and mass spectral properties of these complexes were studied. Some main group IV ligands bonded to cycloheptatrienyldicarbonylmolybdenum were also prepared and studied by spectral means. A number of main group IV - group VI metal penta- carbonyl anionic derivatives have been prepared by the reaction of the chloropentacarbonyl anions with the organolithium compounds of the group IV elements. These compounds have the general formula, [R[subscript 3]M' -M(CO)[subscript 5]][superscript -] (where R = Me, Ph or halogen; M' = Si, Ge, Sn or Pb; M = Cr, Mo or W). Approximate carbonyl force constants were calculated from the infrared carbonyl stretching vibrations and these provided some insight into the nature of the metal-metal bonds. Transition metal nitrosyl derivatives have also been prepared by the reaction of some anionic complexes with nitrosonium hexafluorophosphate. These compounds have the general formula LM(CO)[subscript 4]NO (where L is a main group IV ligand or a halogen group and M is Mo or W). The carbonyl and nitrosyl force constants were calculated and are discussed in terms of the relative bonding properties of CO and NO ligands. Finally, the oxidation reaction of some dinuclear metal carbonyls with AgNO[subscript 2] led to the formation of metal carbonyls containing nitro ligands. Linkage isomerism involving nitro and nitrito species was encountered in solution. The [(CH[subscript 3]CN)[subscript 3]Re(CO)[subscript 3]] + cation was formed 2 - from the oxidation reaction of [Re[subscript 4](CO)[subscript 16]][superscript 2-] in acetonitrile.
Author: Anthony Robert Galbraith
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: John Richard Moss
Publisher:
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Category :
Languages : en
Pages :
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Author: Charles Andrew McAuliffe
Publisher: Elsevier Science & Technology
ISBN:
Category : Complex compounds
Languages : en
Pages : 568
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Author: Maravanji S. Balakrishna
Publisher: Elsevier
ISBN: 0128156945
Category : Science
Languages : en
Pages : 445
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Book Description
Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects. Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties
