Reconstructive Phase Transitions

Reconstructive Phase Transitions PDF Author: Pierre Tol‚dano
Publisher: World Scientific
ISBN: 9789810223649
Category : Science
Languages : en
Pages : 424

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Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

Reconstructive Phase Transitions

Reconstructive Phase Transitions PDF Author: Pierre Tol‚dano
Publisher: World Scientific
ISBN: 9789810223649
Category : Science
Languages : en
Pages : 424

Get Book Here

Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

Reconstructive Phase Transitions: In Crystals And Quasicrystals

Reconstructive Phase Transitions: In Crystals And Quasicrystals PDF Author: Vladimir Dmitriev
Publisher: World Scientific
ISBN: 981450002X
Category : Science
Languages : en
Pages : 416

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Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

Crystal-Quasicrystal Transitions

Crystal-Quasicrystal Transitions PDF Author: M.J. Yacamán
Publisher: Elsevier
ISBN: 0444599142
Category : Science
Languages : en
Pages : 248

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Book Description
The discovery of five-fold diffraction symmetry by D. Schechtman in 1985 shocked crystallography to its roots. Incommensurable modulation of a crystal changes former identical unit cells into different ones. This radical revolution has given rise to the study of an entirely new class of matter, the quasicrystalline materials. The study of these quasi-periodic crystals brings a unique elucidation of the fundaments of crystallography and the relationship between lattice structure and macroscopic properties. This book covers the transitions between the crystalline and the quasicrystalline state. A thorough understanding of the transition from quasiperiodic to periodic lattices is essential in order to investigate the uniqueness of quasicrystals. In this well-written volume, an overview is given of the most important problems in quasicrystallography today. Leading experts provide insight into recent experimental advances achieved by studying the phase transitions between crystalline and quasicrystalline states. In the theoretical chapters one is introduced to the depth of insight into the nature of crystallography which has arisen through a rigorous understanding of the quasicrystal structure. This book is an essential source of reference for crystallographers, crystal growers and solid state physicists working in the field.

Phase Transitions and Crystal Symmetry

Phase Transitions and Crystal Symmetry PDF Author: Yurii Aleksandrovich Izyumov
Publisher: Springer Science & Business Media
ISBN: 9400919204
Category : Science
Languages : en
Pages : 462

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Book Description
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years.

Discontinuous Phase Transitions In Condensed Matter: Symmetry Breaking In Bulk Martensite, Quasiperiodic And Low-dimensional Nanostructures

Discontinuous Phase Transitions In Condensed Matter: Symmetry Breaking In Bulk Martensite, Quasiperiodic And Low-dimensional Nanostructures PDF Author: Vladimir Dmitriev
Publisher: World Scientific
ISBN: 1800612931
Category : Science
Languages : en
Pages : 469

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Book Description
Discontinuous (first-order) phase transitions constitute the most fundamental and widespread type of structural transitions existing in Nature, forming a large majority of the transitions found in elemental crystals, alloys, inorganic compounds, minerals and complex fluids. Nevertheless, only a small part of them, namely, weakly discontinuous transformations, were considered by phenomenological theories, leaving aside the most interesting from a theoretical point of view and the most important for application cases. Discontinuous Phase Transitions in Condensed Matter introduces a density-wave approach to phase transitions which results in a unified, symmetry-based, model-free theory of the weak crystallization of molecular mixtures to liquid-crystalline mesophases, strongly discontinuous crystallization from molten metals and alloys to conventional, fully segregated crystals, to aperiodic, quasi-crystalline structures. Assembly of aperiodic closed virus capsids with non-crystallographic symmetry also falls into the domain of applicability of the density-wave approach.The book also considers the applicability domains of the symmetry-based approach in physics of low-dimensional systems. It includes comparisons of stability of different surface superstructures and metal monoatomic coverage structures on the surface of single-crystalline substrates. The example of the twisted graphene bilayer demonstrates how parametrization in the spirit of an advanced phenomenological approach can establish symmetry-controlled, and therefore model-free, links between geometrical parameters of the twisted bilayer structure and reconstruction of its Brillouin zone and energy bands.

Continuum Models for Phase Transitions and Twinning in Crystals

Continuum Models for Phase Transitions and Twinning in Crystals PDF Author: Mario Pitteri
Publisher: CRC Press
ISBN: 1420036149
Category : Mathematics
Languages : en
Pages : 390

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Book Description
Continuum Models for Phase Transitions and Twinning in Crystals presents the fundamentals of a remarkably successful approach to crystal thermomechanics. Developed over the last two decades, it is based on the mathematical theory of nonlinear thermoelasticity, in which a new viewpoint on material symmetry, motivated by molecular theories, plays a c

High-Pressure Crystallography

High-Pressure Crystallography PDF Author: Elena Boldyreva
Publisher: Springer Science & Business Media
ISBN: 9048192609
Category : Science
Languages : en
Pages : 602

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Book Description
This unique book is devoted to the theme of crystallographic studies at high pressure. It places emphasis on the phenomena characteristic to the compressed state of matter, as well as experimental and theoretical techniques, used to study these phenomena.

Mechanics and Mathematics of Crystals

Mechanics and Mathematics of Crystals PDF Author: Jerald L. Ericksen
Publisher: World Scientific
ISBN: 9812562834
Category : Science
Languages : en
Pages : 655

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Book Description
This book is a unique and comprehensive collection of pioneering contributions to the mechanics of crystals by J L Ericksen, a prominent and leading contributor to the study of the mechanics and mathematics of crystalline solids over the past 35 years.It presents a splendid corpus of research papers that cover areas on crystal symmetry, constitutive equations, defects and phase transitions — all topics of current importance to a broad group of workers in the field.The volume thus provides in one place material that is frequently referenced by numerous researchers on crystals across a spectrum of activities in areas of continuum mechanics, applied mathematics, engineering and materials science.Each group of papers or chapters in the book is preceded by a summary introduction that describes how the papers on that topic fit together, and in which Ericksen sketches the context of each paper and shares with the reader his thinking and insightfulness in writing it. The volume, edited by internationally renowned scholars whose works in finite elasticity and continuum mechanics have appeared in a variety of books and prestigious journals published over the past four decades, also includes a very interesting brief autobiography by Ericksen. In it he describes his early life in Oregon, his wartime experiences, his student days and postgraduate study, his introduction to scientific work, and what motivated him in his research. An English translation and revision of the first paper in this volume, originally published in Russian, appears here for the first time.

Crystallography of Quasicrystals

Crystallography of Quasicrystals PDF Author: Steurer Walter
Publisher: Springer Science & Business Media
ISBN: 3642018998
Category : Science
Languages : en
Pages : 388

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Book Description
From tilings to quasicrystal structures and from surfaces to the n-dimensional approach, this book gives a full, self-contained in-depth description of the crystallography of quasicrystals. It aims not only at conveying the concepts and a precise picture of the structures of quasicrystals, but it also enables the interested reader to enter the field of quasicrystal structure analysis. Going beyond metallic quasicrystals, it also describes the new, dynamically growing field of photonic quasicrystals. The readership will be graduate students and researchers in crystallography, solid-state physics, materials science, solid- state chemistry and applied mathematics.

Solid-Solid Phase Transformations in Inorganic Materials

Solid-Solid Phase Transformations in Inorganic Materials PDF Author: Yves Bréchet
Publisher: Trans Tech Publications Ltd
ISBN: 3038135100
Category : Technology & Engineering
Languages : en
Pages : 1463

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Book Description
The main objective of this special collection was to present state-of-the-art advances in the field of solid-solid phase transformations. Volume is indexed by Thomson Reuters CPCI-S (WoS). The 204 peer-reviewed papers were divided into 10 chapters: 1: Displacive Transformations, 2: Diffusional Transformations, 3: Transition by Interface Migration, 4: Order-Disorder Transitions, 5: Phase Transitions and Size Effect, 6: Driven Systems and Phase Transformations, 7: Phase Transformations during Industrial Processing, 8: Amorphous Alloys, Quasicrystals and other Complex Phases, 9: Advances in the Theory and Modeling of Phase Transitions, 10: Advances in Experimental Techniques. The present work will be a useful supplement to the classic textbooks on the subject.