Reactions of Nitrogen Dioxide with Chloride and Bromide Salts PDF Download
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Author: Thomas D. Allston
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 178
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Book Description
"Infrared absorption spectroscopy was used to study the reaction of nitrogen dioxide with a number of halide salts: MX (s) + 2N02 (g), XNO (g) + MN03 (s), where M = metal and X = halogen (CI, Br). This reaction was observed for the chloride and bromide salts of sodium, potassium, calcium and magnesium. These reactions do not reach thermodynamic equilibrium, and evidence is presented that they are surface controlled. These reactions are very fast and evidence is reported for the relative rates of the chloride and bromide salts. The following mechanism may explain the observed experimental results: (M+X- )(s) + N02(g) (M+X-N02)(s) (M+x-N02)(s) (M+XN02- )(s) (M+XN02-N02)(s) + N02(g) (M+XN02-N02)(s) (M+XN02-N02)(s) (M+XNON03- )(s) (M+XNON03- )(s) (M+N03- )(s) + XNO(g), where (M X- ) (s), XNO (g), and the subscript "(s)" refer to the halide salt, nitrosyl halide, and the solid state respectively."--Abstract.
Author: Thomas D. Allston
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 178
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Book Description
"Infrared absorption spectroscopy was used to study the reaction of nitrogen dioxide with a number of halide salts: MX (s) + 2N02 (g), XNO (g) + MN03 (s), where M = metal and X = halogen (CI, Br). This reaction was observed for the chloride and bromide salts of sodium, potassium, calcium and magnesium. These reactions do not reach thermodynamic equilibrium, and evidence is presented that they are surface controlled. These reactions are very fast and evidence is reported for the relative rates of the chloride and bromide salts. The following mechanism may explain the observed experimental results: (M+X- )(s) + N02(g) (M+X-N02)(s) (M+x-N02)(s) (M+XN02- )(s) (M+XN02-N02)(s) + N02(g) (M+XN02-N02)(s) (M+XN02-N02)(s) (M+XNON03- )(s) (M+XNON03- )(s) (M+N03- )(s) + XNO(g), where (M X- ) (s), XNO (g), and the subscript "(s)" refer to the halide salt, nitrosyl halide, and the solid state respectively."--Abstract.
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Author: Mark J. McClements
Publisher:
ISBN:
Category : Organic compounds
Languages : en
Pages : 194
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Author: Bernard Moody
Publisher: Elsevier
ISBN: 148328008X
Category : Science
Languages : en
Pages : 577
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Book Description
Comparative Inorganic Chemistry, Third Edition focuses on the developments in comparative inorganic chemistry, including properties of elements and the structure of their atoms, electronic configuration of atoms of elements, and the electronic theory of valency. The manuscript first offers information on the development of fundamental ideas in 19th century chemistry, as well as purification and identification of substances in the laboratory; classical arguments for the existence of atoms and molecules; and electrolytes, ions, and electrons. The book also takes a look at the properties of elements and the structure of their atoms. The classification of elements in the 19th century, atomic nucleus, divisible atoms, nuclear reactions and fusions, and artificial radioactivity and nuclear transmutations are discussed. The book examines the electronic theory of valency and periodic classification, including basic assumptions of the electronic theory, hydration of ions, ionic bond and the formation of ions, and the development of the concept of valency. The manuscript also ponders on bonding and the structures displayed by elements and their compounds; oxidation, reduction, and electrochemical processes; and the principles on the extraction of elements. The publication is a dependable source of information for chemists and readers interested in inorganic chemistry.
Author: Barbara J. Finlayson-Pitts
Publisher: Elsevier
ISBN: 0080529070
Category : Science
Languages : en
Pages : 993
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Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. - Serves as a graduate textbook and "must have" reference for all atmospheric scientists - Provides more than 5000 references to the literature through the end of 1998 - Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) - Summarizes kinetic and photochemical date for the troposphere and stratosphere - Features problems at the end of most chapters to enhance the book's use in teaching - Includes applications of the OZIPR box model with comprehensive chemistry for student use
Author: Viraf J. Dalal
Publisher: Allied Publishers
ISBN: 9788184245479
Category :
Languages : en
Pages : 126
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Author: Jiping Liu
Publisher: Springer
ISBN: 9811366470
Category : Science
Languages : en
Pages : 694
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The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.
Author:
Publisher: PHI Learning Pvt. Ltd.
ISBN: 8120343085
Category : Chemistry, Inorganic
Languages : en
Pages : 1069
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Author: K. Jones
Publisher: Elsevier
ISBN: 148313962X
Category : Science
Languages : en
Pages : 259
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The Chemistry of Nitrogen
Author: Raphael Meldola
Publisher:
ISBN:
Category :
Languages : en
Pages : 200
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Author:
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 1220
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