Author: Leopold Gmelin
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 414
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Book Description
The volume gives a highly topical review of all binuclear organorhenium compounds with organic ligands bonded to rhenium through more than one C atom (2L to 12L ligands such as C2R4 , Â-C5R5 , ÂC6H6, or bridging C5H4-X-C5H4). It includes, for example, the most recent results on the compounds ÄReÜ-(ChC)n -ÄReÜ where ÄReÜ stands for (C5(CH3)5)Re(P(C6H5)3)(NO) and the polyacetylene bridge has up to 20 carbon atoms. These species have stable mono- or dications with fully delocalized charges. The present volume, volume 5, and the forthcoming volume 6 give a comprehensive and up-to-date overview of all binuclear organorhenium compounds.
Author: Reinhard Albrecht
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 316
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Book Description
The volume presents all chemical and physical data on mononuclear organorhenium compounds with C5H5Re(CO)2 or 3 and (C5H5)2Re fragments and, in the main part, gives all information on the large variety of mononuclear organorhenium compounds with substituted cyclopentadienyl ligands. Moreover, all compounds are described that have (5-coordinated six-membered or larger organic rings as well as ligands bonded through six carbon atoms (6L ligands such as benzene, substituted benzenes, and condensed aromatic ring systems). Volumes 1 to 4 of this series give a comprehensive overview of mononuclear organorhenium compounds.
Author: Manfred Winter
Publisher: Springer Science & Business Media
ISBN: 3662088444
Category : Science
Languages : en
Pages : 627
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Book Description
The present volume is the first of a series of volumes dealing with organorhenium com pounds. lt covers the Literature completely up to the end of 1987. An empirical formula index and a Ligand formula index provide ready access to the compounds covered. ln accordance with the previous arrangement adopted for organemetallic compounds (cf. volumes covering organocobalt, organonickel, or organotitanium compounds), this volume starts with the mononuclear organorhenium compounds. lt contains compounds in which the organic Ligand is bonded to the Re atom by one C atom CL Ligand) and up to four CO groups. Other mononuclear compounds will be covered in the next volume of this series. 2 1 A formula like (C0) Re( D)s L belongs to a type of mononuclear rhenium compounds 2 containing three monodentate ligands eo two-electron donor) such as P(CH )s and one Ligand 3 bonded by one C atom CL) such as C H (trans-pentadienyl) or C(O)R with R = CH . 5 7 3 Much of the data, particularly in tables, is given in abbreviated form without dimensions; for explanation see p. X. Additional remarks, if necessary, are given in the headings of tl'le tables. Frankfurt am Main Adolf Slawisch November 1988 X Remarks on Abbreviation& and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarification.
Author: Reinhard Albrecht
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 188
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Book Description
Author: Reinhard Albrecht
Publisher: Springer Science & Business Media
ISBN: 3662060523
Category : Science
Languages : en
Pages : 555
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Book Description
The present volume belongs to a series of handbooks dealing with organorhenium com pounds. 1t covers the Literature up to the end of 1993, but some more recent data published in 1994 have also been considered. Patents, conference reports, and dissertations generally were not reviewed. An empirical formula index, a Ligand formula index, and a transition metals cross reference table provide ready access to all compounds covered. The following comments may be helpful for rapidly finding the compound(s) you wish to get information of. ln the Gmelin series "Organometallic Compounds" the term "organometallic" is re served for all compounds containing at Least one carbon-to-metal bond. For all volumes published in this series, see p. VI. The series on organorhenium compounds started with the description of mononuclear compounds in Volumes 1 to 4 (Volume 4 is still to be published) and continues with the present Volume 5 describing all binuclear organorhenium compounds having 0 to 10 CO groups as Ligands, except (C0) Re which will be included in the next volume together 10 2 with all other binuclear compounds having carbenes, isonitriles, and "L Ligands (n > 1) bonded to rhenium as weiL as all other polynuclear organorhenium compounds.
Author: Leopold Gmelin
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 280
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Book Description
This volume is the first of two volumes describing mononuclear cyclopentadienyl rhenium compounds. All chemical, physical, and catalytic properties are given. The major part is devoted to the class of (C5H5)Re compounds without CO groups. The most important species within this class are the NO and PR3 derivatives. Another section describes compounds containing one CO group and closes with 5LRe(CO)2 compounds without additional organic mL ligands (ligands bonded by m C atoms to rhenium). An important starting material for the preparation of other organorhenium compounds is ÄC5H5Re(CO)2NOÜ+. This compound, as well as many others, is of interest in comparison with the analogous organometallic compounds of Cr, Mo, W, and especially Mn. The empirical and ligand formula indices provide ready access to the desired compounds.
Author: Herbert Schumann
Publisher: Springer
ISBN: 9783540937388
Category : Science
Languages : en
Pages : 314
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Book Description
Volume 24 begins with the description of compounds containing more than one organotin unit. It deals with a portion of R3Sn-G-SnR3 compounds with six identical R groups and a large variety of organic G units bonded to both tin atoms exclusively via carbon atoms. Many of these compounds have been used as a synthesis aid for particular organic systems, organic derivatives of other main group elements or transition metals, and some types of polymers.
Author:
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 496
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Book Description
Author: Karin Greiner
Publisher: Springer Science & Business Media
ISBN: 3662075393
Category : Science
Languages : en
Pages : 190
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Book Description
Author: Marlies Mirbach
Publisher: Springer Science & Business Media
ISBN: 3662063123
Category : Science
Languages : en
Pages : 421
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Book Description
This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX, RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by an atom other than carbon. R, X, and/or Y can also be chelating ligands. The remaining part of the volume completeLy covers all pentavalent antimony compounds containing two Sb-C bonds (RSbX, RSb(X)Y, RR'SbX, RR'Sb(X)Y, bi- and tetranucLear 2 3 2 2 3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C bond (RSbX, RSb(X)Y, 4 3 RSb(X)Y, bi- and trinucLear compounds, Chapter 2.7, p. 237). These compounds form ad 2 2 ducts with Lewis bases (symbol D) and form many ionic compLexes by the addition of saLts such as amine hydrochLorides (symbol MZ). The adducts and ionic compLexes are described immediately after the parent substances. The volume concludes with an Empirical Formula Index (p. 318) and a Ligand Formula Index (p. 357).
