Radical Ionic Systems PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Radical Ionic Systems PDF full book. Access full book title Radical Ionic Systems by Anders Lund. Download full books in PDF and EPUB format.
Author: Anders Lund
Publisher: Springer Science & Business Media
ISBN: 9401137501
Category : Science
Languages : en
Pages : 498
Get Book Here
Book Description
It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.
Author: Zory Vlad Todres
Publisher: CRC Press
ISBN: 0824743717
Category : Science
Languages : en
Pages : 537
Get Book Here
Book Description
Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relating to ecology and biology, and inorganic participants in ion radical organic reactions. Applications discussed include the roles of ion radicals in biological systems and their uses in optoelectronics, organic metals, and the manufacture of paper.
Author: Anders Lund
Publisher: Springer Science & Business Media
ISBN: 9401137501
Category : Science
Languages : en
Pages : 498
Get Book Here
Book Description
It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.
Author: David Crich
Publisher: John Wiley & Sons
ISBN: 1118634896
Category : Science
Languages : en
Pages : 1874
Get Book Here
Book Description
Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.
Author: Robert A. Moss
Publisher: John Wiley & Sons
ISBN: 9780471233244
Category : Science
Languages : en
Pages : 1088
Get Book Here
Book Description
Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
Author: Malcolm D. Forbes
Publisher: John Wiley & Sons
ISBN: 9780470584101
Category : Science
Languages : en
Pages : 300
Get Book Here
Book Description
Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Author: H. J. Keller
Publisher: Springer
ISBN: 1489970312
Category : Technology & Engineering
Languages : en
Pages : 353
Get Book Here
Book Description
Theoretical and experimental work on solids with low-dimensi℗Ư onal cooperative phenomena has been rather explosively expanded in the last few years, and it seems to be quite fashionable to con℗Ư tribute to this field, especially to the problem of one-dimensional metals. On the whole, one could divide the huge amount of recent investigations into two parts although there is much overlap bet℗Ư ween these regimes, namely investigations on magnetic exchange interactions constrained to mainly one or two dimensions and, secondly, work done on Id metallic solids or linear chain compounds with Id delocalized electrons. There is, of course, overlap from one extreme case to the other with these solids and in some rare cases both phenomena are studied on one and the same crystal. In fact, however, most of the scientific groups in this area could be associated roughly with one of these categories and, in addition, a separation between theoreticians and experimentalists in each of these groups leads to a further splitting of interests although many theories about these solids have been tested by experimenta℗Ư lists. Nevertheless, more cooperation and understanding between scientists working on low-dimensional cooperative phenomena should appreciably stimulate further development. With a better inderdis℗Ư ciplinary understanding, new ideas could possibly help chemists in synthesizing tailor-cut solids. This would in return give experi℗Ư mentalists new phenomena to examine and finally would stimulate new theoretical work.
Author: D. Bryce-Smith
Publisher: Royal Society of Chemistry
ISBN: 0851860354
Category : Photochemistry
Languages : en
Pages : 995
Get Book Here
Book Description
The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to.
Author: Leroy G. Augenstein
Publisher: Academic Press
ISBN: 1483282406
Category : Science
Languages : en
Pages : 382
Get Book Here
Book Description
Advances in Radiation Biology, Volume 2, reflects a continuing effort to provide wide-ranging analyses of progress in various phases of radiation research. The articles cover a spectrum of topics varying from the initial physical events which allow us to discriminate color, to the chemical and biological processes which determine the extent and permanence of radiation damage, and finally to the role of genetic control and damage in determining the fate of irradiated cells. The basic emphasis of the articles also varies. In some, the main attempt is to review extensively the available data so as to evaluate the possible contributions of various mechanisms to a given phenomenon. One article is devoted an evaluation of one physical approach which appears to be a promising way of understanding color perception. These different treatments should be of value not only to the researcher but also to the student, inasmuch as each approach is invariably dictated by the state of the art in the area being covered.
Author:
Publisher: Academic Press
ISBN: 0080581587
Category : Science
Languages : en
Pages : 466
Get Book Here
Book Description
Advances in Physical Organic Chemistry
Author: A Gilbert
Publisher: Royal Society of Chemistry
ISBN: 1847554792
Category : Science
Languages : en
Pages : 452
Get Book Here
Book Description
The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.
