Preparation and Characterization of Nickel (II), Zinc (II) and Copper (II) Complexes Using Schiff Bases Containing Histidine as Ligands PDF Download
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Author: Jessy Ndongou Niameny Akerey
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Category :
Languages : en
Pages : 0
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Author: Jessy Ndongou Niameny Akerey
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Author: P.S. Braterman
Publisher: Springer Science & Business Media
ISBN: 1461307554
Category : Science
Languages : en
Pages : 419
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This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.
Author:
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Category : Analytical chemistry
Languages : en
Pages : 700
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Author: R C Sheppard
Publisher: Royal Society of Chemistry
ISBN: 1847557368
Category : Science
Languages : en
Pages : 576
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Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: Hassan Keypour
Publisher:
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Category :
Languages : en
Pages :
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Author:
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Category : Chemistry, Inorganic
Languages : en
Pages : 1044
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Author:
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ISBN:
Category : Science
Languages : en
Pages : 860
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Author: J. A. McCleverty
Publisher: Elsevier Science
ISBN: 9780080437484
Category : Science
Languages : en
Pages : 314
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Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: B. C. Whitmore
Publisher:
ISBN:
Category :
Languages : en
Pages : 13
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Binuclear complexes of Ni, Cu and Mn have been synthesized and characterized. The reaction of bis(salicylaldehyde) complexes of nickel(II) and copper(II) with m-xylylenebis-(2-(1,3-propanediamine)) (3) result in the formation of 5 and 7 respectively, while the reaction of managanese(II) acetate with salicylaldehyde and 3 results in the formation of 6a. The nickel complex, 5, undergoes a quasireversible two-electron transfer at -1.47 V vs SCE attributable to the nickel(II)-nickel(I) couple. The binuclear nickel(I) complex can be generated from 5 both electrochemically and chemically, and has been shown by infrared analysis to form adducts of CO and MeNC. Magnetic susceptibility measurements by the Faraday method show the manganese and copper complexes (6a and 7) have solid state room temperature moments of 5.47 and 1.92 B.M. per metal center, respectively, while the solution magnetic moment of the binuclear copper complex (7) is found by the Evans method to be 1.49 B.M. per copper center. This reduced magnetic moment relative to the moment for mononuclear Cusalprn(1.79 B.M) suggests a weak magnetic interaction between the two copper centers in the binuclear copper complex 7.
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Category : Amino acids
Languages : en
Pages : 586
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