Physical and Chemical Speciation of Trace Metals in Estuarine and Shelf Water Systems PDF Download
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Author: Matthew Paul Hurst
Publisher:
ISBN:
Category :
Languages : en
Pages : 414
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Author: Matthew Paul Hurst
Publisher:
ISBN:
Category :
Languages : en
Pages : 414
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Author: André Tessier
Publisher: John Wiley & Sons
ISBN:
Category : Nature
Languages : en
Pages : 704
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Book Description
This publication deals with fundamental concepts and models, speciation measurements and field applications in metal speciation and bioavailability in aquatic environments. This volume provides a thorough review of current developments concerning the interactions between trace metals and aquatic organisms.
Author: Robert P. Mason
Publisher: John Wiley & Sons
ISBN: 111827458X
Category : Science
Languages : en
Pages : 450
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Book Description
This book provides a detailed examination of the concentration, form and cycling of trace metals and metalloids through the aquatic biosphere, and has sections dealing with the atmosphere, the ocean, lakes and rivers. It discusses exchanges at the water interface (air/water and sediment/water) and the major drivers of the cycling, concentration and form of trace metals in aquatic systems. The initial chapters focus on the fundamental principles and modelling approaches needed to understand metal concentration, speciation and fate in the aquatic environment, while the later chapters focus on specific environments, with case studies and research highlights. Specific examples deal with metals that are of particular scientific interest, such as mercury, iron, arsenic and zinc, and the book deals with both pollutant and required (nutrient) metals and metalloids. The underlying chemical principles controlling toxicity and bioavailability of these elements to microorganisms and to the aquatic food chain are also discussed. Readership: Graduate students studying environmental chemistry and related topics, as well as scientists and managers interested in the cycling of trace substances in aqueous systems Additional resources for this book can be found at: www.wiley.com/go/mason/tracemetals.
Author: C. Wong
Publisher: Springer Science & Business Media
ISBN: 1475768648
Category : Science
Languages : en
Pages : 913
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Book Description
In recent years, rapid scientific advances have been shattering classical concepts of oceanic trace metals concentrations. Most of the data gathered before the mid-1970s have had to be discarded. Possible associations of organic and inorganic ligands with the metals were throwing views of metal speciation into great uncertainty. Biological effects of metals need to be re-examined after recent revelations of unsuspected metal contaminations in methodology. The investigations appear chaotic, yet exciting. It implies that a new order is going to replace the past. Now, an opportunity opens its door to a brave new world for the young generation of scientists to put metal chemistries in the oceans into perspectiveo This N. AoToO. International Conference on "Trace Metals in Sea Water" hoped to catalyze this exciting process of unifying various aspects of trace metals in sea water in future years o The Conference, in the form of an Advanced Research Institute supported by the Scientific Affairs Division of NoAoT. O. supple mented by further assistance of the UoS. Office of Naval "Research, was held at the "Ettore Majorana" Center for Scientific Culture in the medieval town of Erice on the island of Sicily, Italy from March 30 to April 3, 1981. It was the first organized gathering of international scientists in this specialized field. Seventy scientists with various expertise in different aspects of the subject were present: including those from NoAoT. Oo countries (Canada, France, F. R. Germany, Greece, Iceland, Italy, U. K.
Author: Lars Landner
Publisher: Springer
ISBN: 3540477330
Category : Science
Languages : en
Pages : 229
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Book Description
The particular behavior of trace metals in the environment is determined by their specific physico-chemical form rather than by their total concentration. The introduction of atomic absorption spectrometry has lead to a plethora of scientific papers and reports in which metal concentrations in the environment are only reported as total concentrations. Only recently has the need for improved knowledge on the various forms and bioavailability of metals been realised. Considerable research effort is now devoted to measuring the concentrations of trace metals in surface waters. Efforts are made to couple chemical analytical techniques to process-related biological problems. The proceedings of the workshop on The Speciation of Metals in Water, Sediment and Soil Systems held in Sunne, Sweden, comprise these efforts and show aspects for further cooperation between analytical chemists and biologists.
Author: Camille Gaulier
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
Estuarine and coastal ecosystems provide multiple ecological, social and economic services. They are a source of food, income and are at the heart of marine trade, merchant shipping and sea transport. They therefore play a key role in our modern world and their conservation from an environmental point of view is today critical. Despite all the efforts done in environmental management, pollution associated with the rapid coastal development and intensive industrialization was inevitable and still remains one of the main threats towards marine ecosystems today. Specifically, trace metal contamination is of specific concern as coastal areas are generally prone to accumulate them. Most trace metals exhibit a dual role in marine waters: they act as nutrients in low concentrations, yet rapidly have toxic effects in higher concentration ranges. Continuous monitoring of their concentrations in estuarine and coastal ecosystems is therefore needed to better understand their biogeochemical behavior in such marine environments. However, limited knowledge exists on their bioavailability towards marine organisms: especially as the toxicity of these metals is not only related to their concentration but also strongly linked with their speciation which shows both seasonal and spatial variations. Thus, the main objective of this PhD research was to investigate the biogeochemical cycles of various trace metals and unravel their speciation and bioavailability in various aquatic systems: from very dynamic mixing zones of the Scheldt estuary to coastal harbors and shallow seawaters of the North Sea, and even to deeper and anoxic regions of the Baltic Sea. Trace metal concentrations and speciation were explored seasonally and spatially along horizontal and vertical gradients, and a comparison of classic active samplings of dissolved trace metals with a passive sampling technique (Diffusive Gradients in Thin-films; DGT) was carried out. The DGT technique was successfully used for the in-situ measurement of labile metals and eventually constitutes a good surrogate to the biomonitoring of trace elements (e.g. use of mussels, algae, etc.). This method offsets the lack of knowledge in terms of water quality monitoring and the results challenge the classic criteria which are used by international regulatory requirements (e.g. WFD, MSFD) and local commitments (e.g. OSPAR, HELCOM). Indeed, new criteria based on labile metal species instead of total dissolved species should be considered in the future. Such approach of trace metal speciation and assessment in aquatic systems could surely lead to a more integrated environmental management and improve our knowledge on anthropogenic impacts and pollutant fluxes. Moreover, it is eventually the main key to explain and predict bioavailability and potential toxicity of trace metals to the marine fauna and flora. This work therefore invites you to dive into a journey along our coasts, from urbanized areas to wild open seas, from their surface to their deepest waters.
Author: Santosh Kumar Sarkar
Publisher: Springer
ISBN: 9811027935
Category : Science
Languages : en
Pages : 261
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Book Description
This book offers a comprehensive and accessible guide covering various aspects of trace metal contamination in abiotic and biotic matrices of an iconic Indian tropical mangrove wetland – Sundarban. Divided into nine chapters, the book begins by discussing the fundamental concepts of sources, accumulation rate and significance of trace metal speciation, along with the impact of multiple stressors on trace metal accumulation, taking into account both tourist activities and the exacerbating role of climate change. The second chapter presents a detailed account of the sampling strategy and preservation of research samples, followed by exhaustive information on sediment quality assessment and ecological risk, instrumental techniques in environmental chemical analyses, quality assurance and quality control, along with the Sediment Quality Guidelines (SQGs). Using raw data, the sediment quality assessment indices (e.g., pollution load index, index of geoaccumulation, Nemerow Pollution Load Index etc.) and conventional statistical analyses are worked out and interpreted precisely, allowing students to readily evaluate and interpret them. This is followed by chapters devoted to trace metal accumulation in sediments and benthic organisms, as well as acid-leachable and geochemical fractionation of trace metals in sediments. The book then focuses on chemical speciation of butylin and arsenic in sediments as well as macrozoobenthos (polychaetous annelids). Finally, potential positive role of the dominant mangrove Avicennia in sequestering trace metals from rhizosediments of Sundarban Wetland is elaborately discussed. This timely reference book provides a versatile and in-depth account for understanding the emerging problems of trace metal contamination – issues that are relevant for many countries around the globe.
Author: C.J. Kramer
Publisher: Springer Science & Business Media
ISBN: 9400961677
Category : Science
Languages : en
Pages : 453
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Book Description
It is presently well recognized that total concentrations of trace elements in any environmental compartment supply insufficient information to understand important phenomena. The distinction and separate analysis of specific chemical species are essential for understanding cycles in the aquatic environment, involving identification and quantification of sources, transport pathways, distributions and sinks, or, in the area of interactions between trace elements and organisms to understand uptake, distribution, excretion mechanisms and effects. In the past, various ways have been developed to determine the nature and extent of complexation of trace elements in natural systems. Approaches have been followed along very different lines. These have not always been fully appreciated by specialists working in even related fields of complexation research. The first International Symposium on the Complexation of Trace metals in Natural Waters was held at the Netherlands Institute for Sea Research (NIOZ, Texel, the Netherlands from 2-6 May 1983. The scientific programme was planned by the chief organizers Drs. C.J.M. Kramer and J.C. Duinker (NIOZ) together with Prof. Dr. H.W. Nurnberg (Kernforschungsanlage, Julich, Federal Republic of Germany) and Dr. M. Branica (Rudjer Boskovic Institute, Zagreb, Yugoslavia).
Author: Ronald Eisler
Publisher: Elsevier
ISBN: 0080963536
Category : Science
Languages : en
Pages : 524
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Book Description
Each book has two main goals1. Determine baseline concentrations of metals and metalloids in tissues of representative field populations of estuarine coastal, and open ocean organisms (Book 1:algae and macrophytes, protists, sponges, coelenterates, molluscs, crustaceans, insects, chaetognaths, annelids, echinoderms, and tunicates) (Book 2: elasmobranchs, fishes, reptiles, birds, mammals) and their significance to organism health and to the health of their consumers.2. Synthesize existing information on biological, chemical, and physical factors known to modify uptake, retention, and translocation of each element under field and laboratory conditions. Recognition of the importance of these modifiers and their accompanying interactions is essential to the understanding of metals kinetics in marine systems and to the interpretation of baseline residue data. Synthesizes existing information on biological, chemical, and physical factors known to modify uptake, retention, and translocation of each element Aids understanding of metals kinetics in marine systems Allows the interpretation of baseline residue data
Author: Gary C. Leppard
Publisher: Springer Science & Business Media
ISBN: 1468482343
Category : Science
Languages : en
Pages : 323
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Book Description
