Photocatalytic Degradation of Chlorinated Volatile Organic Compounds in Gaseous Phase

Photocatalytic Degradation of Chlorinated Volatile Organic Compounds in Gaseous Phase PDF Author: Nan-Min Wu
Publisher:
ISBN:
Category : Photobiochemistry
Languages : en
Pages : 198

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Photocatalytic Degradation of Chlorinated Volatile Organic Compounds in Gaseous Phase

Photocatalytic Degradation of Chlorinated Volatile Organic Compounds in Gaseous Phase PDF Author: Nan-Min Wu
Publisher:
ISBN:
Category : Photobiochemistry
Languages : en
Pages : 198

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Gaseous Phase Photocatalytic Degradation of Volatile Organic Compounds by Titanium Dioxide

Gaseous Phase Photocatalytic Degradation of Volatile Organic Compounds by Titanium Dioxide PDF Author: Yuk-Lin Chan
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 176

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Gas Phase Photocatalytic Degradation on TiO2 Pellets of Volatile Chlorinated Organic Compounds from a Soil Vapor Extraction Well

Gas Phase Photocatalytic Degradation on TiO2 Pellets of Volatile Chlorinated Organic Compounds from a Soil Vapor Extraction Well PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 18

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The mineralization of trichloroethylene (TCE) and tetrachloroethylene (PCE) in gas stream from a soil vapor extraction (SVE) well was demonstrated with an annular photocatalytic reactor packed with porous TiO2 pellets in field trials at the Savannah River Site in Aiken, SC. The TiO2 pellets were prepared using a sol-gel method. The experiments were performed at 55 to 60°C using space times of 108 to 101° g s/mol for TCE and PCE. Chloroform (CHCl3) and carbon tetrachloride (CCl4) were detected as minor products from side reactions. On a molar basis, CCl4 and CHCl3 produced were about 2% and 0.2 % of the reactants.

Gas-phase photocatalytic oxidation of volatile organic compounds

Gas-phase photocatalytic oxidation of volatile organic compounds PDF Author: Anna Kachina
Publisher:
ISBN: 9789522145499
Category : Air
Languages : en
Pages : 85

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Photocatalytic Degradation of NOX, VOCs, and Chloramines by TiO2 Impregnated Surfaces

Photocatalytic Degradation of NOX, VOCs, and Chloramines by TiO2 Impregnated Surfaces PDF Author: Eva Miriam Land
Publisher:
ISBN:
Category : Air
Languages : en
Pages :

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Experiments were conducted to determine the photocatalytic degradation of three types of gas-phase compounds, NOX, VOCs, and chloramines, by TiO2 impregnated tiles. The oxides of nitrogen NO and NO2 (NOx) have a variety of negative impacts on human and environmental health ranging from serving as key precursors for the respiratory irritant ozone, to forming nitric acid, which is a primary component of acid rain. A flow tube reactor was designed for the experiments that allowed the UV illumination of the tiles under exposure to both NO and NO2 concentrations in simulated ambient air. The reactor was also used to assess NOx degradation for sampled ambient air. The PV values for NO and NO2 were 0.016 cm s-1 and 0.0015 cm s-1, respectively. For ambient experiments a decrease in ambient NOx of ~ 40% was observed over a period of roughly 5 days. The mean PV for NOx for ambient air was 0.016 cm s-1 and the maximum PV was .038 cm s-1. Overall, the results indicate that laboratory conditions generally simulate the efficiency of removing NOx by TiO2 impregnated tiles. Volatile organic compounds (VOC's) are formed in a variety of indoor environments, and can lead to respiratory problems (US EPA, 2010). The experiments determined the photocatalytic degradation of formaldehyde and methanol, two common VOCs, by TiO2 impregnated tiles. The same flow tube reactor used for the previous NOX experiments was used to test a standardized gas-phase concentration of formaldehyde and methanol. The extended UV illumination of the tiles resulted in a 50 % reduction in formaldehyde, and a 68% reduction in methanol. The deposition velocities (or the photocatalytic velocities, PV) were estimated for both VOC's. The PV for formaldehyde was 0.021 cm s-1, and the PV for methanol was 0.026 cm s-1. These PV values are slightly higher than the mean value determined for NO from the previous experiments which was 0.016 cm s-1. The results suggest that the TiO2 tiles could effectively reduce specific VOC levels in indoor environments. Chlorination is a widespread form of water disinfection. However, chlorine can produce unwanted disinfection byproducts when chlorine reacts with nitrogen containing compounds or other organics. The reaction of chlorine with ammonia produces one of three chloramines, (mono-, di-, and tri-chloramine). The production of chloramines compounds in indoor areas increases the likelihood of asthma in pool professionals, competitive swimmers, and children that frequently bath in indoor chlorinated swimming pools (Jacobs, 2007; Nemery, 2002; Zwiener, 2007). A modified flow tube reactor in conjunction with a standardized solution of monochloramine, NH2Cl, determined the photocatalytic reactions over the TiO2 tiles and seven concrete samples. The concrete samples included five different concrete types, and contained either 5 % or 15 % TiO2 by weight. The PV for the tiles was 0.045 cm s-1 for the tiles manufactured by TOTO Inc. The highest PV from the concrete samples was 0.054 cm s-1. Overall the commercial tiles were most efficient at reducing NH2Cl, compared to NOX and VOC compounds. However, the concrete samples had an even higher PV for NH2Cl than the tiles. The reason for this is unknown; however, distinct surface characteristics and a higher concentration of TiO2 in the concrete may have contributed to these findings.

Waste Gas Treatment for Resource Recovery

Waste Gas Treatment for Resource Recovery PDF Author: Piet Lens
Publisher: IWA Publishing
ISBN: 1843391279
Category : Science
Languages : en
Pages : 512

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Book Description
The prevention of over-exploitation and the efficient use of natural resources are key goals of environmental managment in Industry. Waste Gas Treatment for Resource Recovery presents the reader with technical, ecological and economical aspects of gaseous effluent treatment and resource recovery. Practical experience from industry and agriculture is presented, the role of newly developed advanced technology in future recycling of gas streams discussed and attention given to criteria for sustainability in gas treatment. Detailed analysis of material flows, novel process applications and bioreactor designs, odour quantification and removal process techniques and European legislations for waste gas discharge and recovery are highlights of the extensive and comprehensive coverage of this book. Waste Gas Treatment for Resource Recovery will enable production, process and environmental engineers and managers to evaluate internal recycling possibilities, which contribute to an economically and environmentally friendly manufacturing processes with reduced pollution loads and waste gas volumes. Analysis of material flows, e.g. the development of methodologies and techniques to monitor the use and flow of materials on a life cycle basis Novel process applications and bioreactor designs for resource recovery from waste gases Odour quantification techniques and novel odour removal processes European dimension of polluted gas streams and the European legislation for waste gas discharges and recovery

Current Developments in Photocatalysis and Photocatalytic Materials

Current Developments in Photocatalysis and Photocatalytic Materials PDF Author: Xinchen Wang
Publisher: Elsevier
ISBN: 0128190035
Category : Science
Languages : en
Pages : 568

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Book Description
Photocatalytic materials can improve the efficiency and sustainability of processes and offer novel ways to address issues across a wide range of fields—from sustainable chemistry and energy production to environmental remediation. Current Developments in Photocatalysis and Photocatalytic Materials provides an overview of the latest advances in this field, offering insight into the chemistry and activity of the latest generation of photocatalytic materials.After an introduction to photocatalysis and photocatalytic materials, this book goes on to outline a wide selection of photocatalytic materials, not only covering typical metal oxide photocatalysts such as TiO2 but also exploring newly developed organic semiconducting photocatalysts, such as g-C3N4.Drawing on the experience of an expert team of contributors, Current Developments in Photocatalysis and Photocatalytic Materials highlights the new horizons of photocatalysis, in which photocatalytic materials will come to play an important role in our day-to-day lives. - Reviews developments in both organic- and inorganic-based materials for use in photocatalysis - Presents the fundamental chemistry and activity of a broad range of key photocatalytic materials, including both typical and novel materials - Highlights the role photocatalytic materials can play in sustainable applications

Proceedings of the 50th Industrial Waste Conference May 8, 9, 10, 1995

Proceedings of the 50th Industrial Waste Conference May 8, 9, 10, 1995 PDF Author: Purdue Research Foun
Publisher: CRC Press
ISBN: 9781575040226
Category : Technology & Engineering
Languages : en
Pages : 872

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Book Description
Proceedings of the 50th Industrial Waste Conference is the only comprehensive documentation of the entire seminar. It is an overview of the current state of hazardous waste identification, management and disposal.

Advanced Aspects of Spectroscopy

Advanced Aspects of Spectroscopy PDF Author: Muhammad Akhyar Farrukh
Publisher: BoD – Books on Demand
ISBN: 9535107151
Category : Technology & Engineering
Languages : en
Pages : 551

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Book Description
Spectroscopy is the study of absorption and emission of electromagnetic radiation due to the interaction between matter and energy that energy depends on the specific wavelength of electromagnetic radiation. This field has proven invaluable research tool in a number of areas including chemistry, physics, biology, medicine and ecology. The spectroscopic field of research is growing day-by-day and scientists are exploring new areas in this field by introducing new techniques. The main purpose of this book is to highlight these new spectroscopic techniques like Magnetic Induction Spectroscopy, Laser-Induced Breakdown Spectroscopy, X-ray Photoelectron Spectroscopy, Low Energy Electron Loss Spectroscopy, Micro- to Macro-Raman Spectroscopy, Liquid-Immersion Raman Spectroscopy, High-Resolution Magic Angle Spinning (HR-MAS) Nuclear Magnetic Resonance (NMR) Spectroscopy, Injection and Optical Spectroscopy, and Nano Spectroscopy. This book is divided into five sections including General Spectroscopy, Advanced Spectroscopy, Nano Spectroscopy, Organic Spectroscopy, and Physical Spectroscopy which cover topics from basic to advanced levels which will provide a good source of learning for teaching and research purposes.

Photocatalytic Degradation of Chlorinated Hydrocarbons

Photocatalytic Degradation of Chlorinated Hydrocarbons PDF Author: Daniel Clark Gapen
Publisher:
ISBN:
Category :
Languages : en
Pages : 430

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