Author: E. W. Murbach
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 24
Book Description
Oxidation of Uranium Carbide by Carbon Dioxide
Author: E. W. Murbach
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 24
Book Description
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 24
Book Description
Oxidation-reduction Reprocessing of Uranium Carbide Reactor Fuel
Author: W. G. Smiley
Publisher:
ISBN:
Category : Nuclear fuels
Languages : en
Pages : 30
Book Description
Publisher:
ISBN:
Category : Nuclear fuels
Languages : en
Pages : 30
Book Description
The Oxidation of "reactive" Uranium Carbide
Author: E. W. Murbach
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 20
Book Description
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 20
Book Description
Kinetics of the Oxidation of Uranium by Carbon Dioxide
Author: J.E. Antill
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Oxidation-Reduction Reprocessing of Uranium Carbide Reactor Fuel. I. Carbothermic Reduction of UO$sub 2$
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Gram-scale experiments on the carbothermic reduction of UO/sub 2/ were carried out as part of an investigation of oxidation-reduction reprocessing of UC. UO/sub 2/, from air oxidation of UC, was mixed with graphite powder and heated in vacuum at 1300 to 1700 deg C, both as loose powder and as pellets. The best container material was carbide-coated graphite; molybdenum was satisfactory with pellets. Information on reaction rates was obtained by measuring the evolved carbon monoxide with a gas meter. In the powder experiments, the carbon content of the products agreed with predicted values, with a standard deviation of 0.069 wt%. The carbon content of products from pellets was low by 0.25 wt%, with a standard deviation of 0.076 wt%. This is believed to be an effect of the acrylic plastic binder. Reaction rates followed a second-order rate equation, except that thc rate constant often decreased abruptly at about 90% completion. Correlation between rate and temperature was poor; for 32 values of the rate constant, K (reciprocal hours), the least squares equation was: log K = 9.8216,080/T, with a standard error of 0.20 in log K. The data also agree fairly well (standard error, 0.22) with the hypothesis that the activation energy is equal to the heat of the endothermic reaction. Because of variations in the rate, it is recommended that the reaction of each batch should be followed with a gas meter, in order to obtain a desired degree of completion. (auth).
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Gram-scale experiments on the carbothermic reduction of UO/sub 2/ were carried out as part of an investigation of oxidation-reduction reprocessing of UC. UO/sub 2/, from air oxidation of UC, was mixed with graphite powder and heated in vacuum at 1300 to 1700 deg C, both as loose powder and as pellets. The best container material was carbide-coated graphite; molybdenum was satisfactory with pellets. Information on reaction rates was obtained by measuring the evolved carbon monoxide with a gas meter. In the powder experiments, the carbon content of the products agreed with predicted values, with a standard deviation of 0.069 wt%. The carbon content of products from pellets was low by 0.25 wt%, with a standard deviation of 0.076 wt%. This is believed to be an effect of the acrylic plastic binder. Reaction rates followed a second-order rate equation, except that thc rate constant often decreased abruptly at about 90% completion. Correlation between rate and temperature was poor; for 32 values of the rate constant, K (reciprocal hours), the least squares equation was: log K = 9.8216,080/T, with a standard error of 0.20 in log K. The data also agree fairly well (standard error, 0.22) with the hypothesis that the activation energy is equal to the heat of the endothermic reaction. Because of variations in the rate, it is recommended that the reaction of each batch should be followed with a gas meter, in order to obtain a desired degree of completion. (auth).
A Review of Uranium Oxidation
Author: A. J. Scott
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 36
Book Description
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 36
Book Description
Detections of Carbon Dioxide in the Gases Evolved During the Hot Extraction Determination of Hydrogen in Uranium Ingots
Author: M. L. Jursik
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 48
Book Description
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 48
Book Description
The Carbon Reduction of Uranium Oxide
Author: Harley A. Wilhelm
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 42
Book Description
Publisher:
ISBN:
Category : Reduction (Chemistry)
Languages : en
Pages : 42
Book Description
Processing of Uranium Carbide Reactor Fuels
Author: M. J. Bradley
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 26
Book Description
Publisher:
ISBN:
Category : Carbides
Languages : en
Pages : 26
Book Description
Oxidation of Uranium Alloys in Air and Carbon Dioxide at 500-100°C
Author: J.E. Antill
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
Book Description