Organotitanium Reagents in Organic Synthesis PDF Download
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Author: Manfred T. Reetz
Publisher: Springer
ISBN:
Category : Chemical tests and reagents
Languages : en
Pages : 256
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Book Description
Author: Manfred T. Reetz
Publisher: Springer
ISBN:
Category : Chemical tests and reagents
Languages : en
Pages : 256
Get Book Here
Book Description
Author: Manfred T. Reetz
Publisher: Springer Science & Business Media
ISBN: 3642707041
Category : Science
Languages : en
Pages : 244
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Book Description
Titanium has been used to perform many kinds of reactions in organic and inorganic chemistry. The present book is concerned primarily with a new development in titanium chemistry which is useful in organic synthesis. In 1979/80 it was discovered that the titanation of classical carbanions using C1TiX leads to species with reduced basicity and reactivity. This increases 3 chemo-, regio-and stereo selectivity in reactions with organic compounds such as aldehydes, ketones and alkyl halides. Many new examples have been reported in recent times. Since the nature of the ligand X at titanium can be widely varied, the electronic and steric nature of the reagents is easily controlled. This helps in predicting the stereochemical outcome of many of the C-C bond forming reactions, but the trial and error method is still necessary in other cases. One of the ultimate objectives of chemistry is to understand correlations between structure and reactivity. Although this goal has not been reached in the area of organotitanium chemistry, appreciable progress has been made. A great deal of physical and computational data of organotitanium compounds described in the current and older literature (e. g. , Ziegler-Natta type catalysts) has been reported by polymer, inorganic and theoretical chemists. It is summarized in Chapter 2 of this book, because some aspects are useful in understanding reactivity and selectivity of organo titanium compounds in organic synthesis as described in the chapters which follow.
Author: Manfred Reetz
Publisher:
ISBN: 9783642707056
Category :
Languages : en
Pages : 252
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Book Description
Author: Mary Fieser
Publisher: John Wiley & Sons
ISBN: 0471504009
Category : Science
Languages : en
Pages : 405
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Book Description
This ongoing series, originated in 1967, has become the standard guide to the preparation, properties and uses of thousands of reagents, and additional references to reagents previously discussed. It includes data on structural formulae, molecular weight, physical constants, preferred method of preparation, and examples of important uses. It also contains data on commonly used reagents from 1966 to 1988.
Author:
Publisher: Newnes
ISBN: 008097743X
Category : Science
Languages : en
Pages : 9815
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Book Description
The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
Author: Ahmed F. Abdel-Magid
Publisher: Springer Science & Business Media
ISBN: 9783540016038
Category : Science
Languages : en
Pages : 316
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Book Description
The design of efficient syntheses of medicinal agents is one of the prime goals of the process chemist in the pharmaceutical industry. The expanding list of metal-mediated reactions has had a major impact on this endeavor over the last two decades. This volume will highlight some of the areas of organometallic chemistry that have played a particularly important role in development. The chapters are written by chemists who work in the process groups of major pharmaceutical companies and fine chemical manufacturers. Having demonstrated the power of organometallics in their processes the authors herein expand upon their experiences with examples from the literature as reported by process groups within the industry. The chapters are organized either by the application of a particular metal or reaction class. Removal of the residual metal(s) from the isolated active pharmaceutical ingredient (API) is key to the release of the material for human consumption, and hence, is reviewed here as well. This volume of Topics in Organometallic Chemistry is presented to offer a representative cross section of organometallic applications in the pharmaceutical industry as well as to give an appreciation for the creativity possible in process chemistry.
Author: Louis Frederick Fieser
Publisher:
ISBN:
Category : Chemical tests and reagents
Languages : en
Pages : 716
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Book Description
This major reference work is arranged like an encyclopedia, with each entry providing information about a reagent which has been reported as useful in organic synthesis. Most of the reagents are themselves organic, but inorganic reagents are also included. Suppliers are listed for commercially available reagents; otherwise, a brief indication of the method of preparation is given, along with a literature reference. Concise information and literature references are also provided on the application of reagents. There are author and subject indexes, and a very useful index of reagents by type, so that this reference set can serve as a very convenient point of entry into the literature dealing with a general type of reaction, whether it be a "name" reaction (e.g., Baeyer-Villiger oxidation), a method of introducing a specific functional group (e.g., amination), etc.
Author: Mary Fieser
Publisher: John Wiley & Sons
ISBN: 0471527211
Category : Science
Languages : en
Pages : 453
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Book Description
The well respected and ever popular Fieser and Fieser series on reagents for organic synthesis provides concise descriptions, good structural formulas and selected examples of applications. Provides references to new reagents as well as to reagents included in previous volumes Thousands of entries abstract the most important information on commonly used and new reagents, including preparation, uses, sources of supply, critical comments, references and more Reagents are considered in alphabetical order by common usage names.
Author: Tse-Lok Ho
Publisher: John Wiley & Sons
ISBN: 1118942809
Category : Science
Languages : en
Pages : 719
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Book Description
Fiesers' Reagents for Organic Synthesis provides an up-to-date, A-to-Z listing of reagents cited in synthetic literature. • Covers, in volume 28, chemical literature and methodologies from July 2011 - December 2012 • Features entries with concise descriptions, illustrations of chemical reactions, selected examples of applications • Includes author indexes and subject indexes • Offers practical information on making/buying reagent, its usefulness, where to find complete details
Author: George S. Zweifel
Publisher: John Wiley & Sons
ISBN: 1119086760
Category : Science
Languages : en
Pages : 416
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Book Description
This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
