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Author: Scott E. Denmark
Publisher: John Wiley & Sons
ISBN: 0470638435
Category : Science
Languages : en
Pages : 580
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Book Description
Volume 76 in the venerable Organic Reactions series comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds. This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity. As with all Organic Reactions chapters, these reviews emphasize the preparative aspects of the featured transformation and contain comprehensive compilations of all known examples in the tables.
Author: Scott E. Denmark
Publisher: John Wiley & Sons
ISBN: 0470638435
Category : Science
Languages : en
Pages : 580
Get Book Here
Book Description
Volume 76 in the venerable Organic Reactions series comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds. This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity. As with all Organic Reactions chapters, these reviews emphasize the preparative aspects of the featured transformation and contain comprehensive compilations of all known examples in the tables.
Author:
Publisher: John Wiley & Sons
ISBN: 1119570409
Category : Science
Languages : en
Pages : 1133
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Book Description
Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.
Author:
Publisher: John Wiley & Sons
ISBN: 1119266513
Category : Science
Languages : en
Pages : 1358
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Book Description
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
Author:
Publisher: John Wiley & Sons
ISBN: 111816380X
Category : Science
Languages : en
Pages : 642
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Book Description
This new volume in the venerable Organic Reactions series comprises two chapters written in part by the inventors of the unique and important name reactions discussed in these chapters. The first chapter describes a truly remarkable transformation of carboxylic acid derivatives into heteroatom-substituted cyclopropanes, now known as Kulinkovich Cyclopropanation. The second chapter represents an homage to one of the giants of organic chemistry, Sir Derek H. R. Barton. This chapter covers the radical deoxygenation of secondary alcohols that has become known as the Barton-McCombie Reaction.
Author:
Publisher: John Wiley & Sons
ISBN: 1119644747
Category : Science
Languages : en
Pages : 993
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Book Description
The 101st volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
Author: P. Andrew Evans
Publisher: John Wiley & Sons
ISBN: 1119982294
Category : Science
Languages : en
Pages : 868
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Book Description
A carefully curated review of the scientific literature, Volume 113 of Organic Reactions presents critical discussions of widely used organic reactions or particular steps of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method. Launched in 1942, the Organic Reactions series today is a leading secondary- and tertiary-level source for organic chemists across the world.
Author:
Publisher: John Wiley & Sons
ISBN: 111901400X
Category : Science
Languages : en
Pages : 814
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Book Description
The first chapter describes the manifold ways in which the latent functionality embedded in the humble heterocycle furan can be revealed by various oxidative processes.The second chapter details the fascinating cycloaddition and electrocyclization chemistry of unsaturated ketenes. The third chapter chronicles the development of a remarkable organometallic reaction of unactivated alkenes and alkynes, namely carbozincation.
Author:
Publisher: John Wiley & Sons
ISBN: 1119832071
Category : Science
Languages : en
Pages : 1026
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Book Description
The 108th volume in this series for organic chemists in academia and industry presents critical discussions of the following widely used organic reactions: CYCLIZATION REACTIONS OF NITROGEN-CENTERED RADICALS Stuart W. McCombie, Béatrice Quiclet-Sire, and Samir Z. Zard TRANSITION-METAL-CATALYZED AMINOOXYGENATION OF ALKENES Sherry R. Chemler, Dake Chen, Shuklendu D. Karyakarte, Jonathan M. Shikora, and Tomasz Wdowik
Author: P. Andrew Evans
Publisher: John Wiley & Sons
ISBN: 1119982219
Category : Science
Languages : en
Pages : 837
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Book Description
The 111th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular steps of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method. Volume contents: RING-OPENING REACTIONS OF EPOXIDES WITH TITANIUM(III) REAGENTS T. V. (Babu) RajanBabu, William A. Nugent, and Sandipan Halder REDUCTIVE CYCLIZATION OF 2-NITRO- AND β-NITROSTYRENES, 2-NITROBIPHENYLS, AND 1-NITRO-1,3-DIENES TO INDOLES, CARBAZOLES, AND PYRROLES Björn C. G. Söderberg and William F. Berkowitz
Author: Scott E. Denmark
Publisher: John Wiley & Sons
ISBN: 1118841905
Category : Science
Languages : en
Pages : 464
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Book Description
The two chapters in Volume 84 describe transition metal catalyzed processes that form carbon-carbon bonds and carbon-oxygen bonds in very interesting and practical ways. The first chapter authored by Christina Moberg describes an important subset of one of the earliest and most important enantioselective carbon-carbon bond forming reactions that employ transition metal complexes, namely molybdenum-catalyzed, asymmetric allylic alkylations. The second chapter authored by Brian W. Michel, Laura D. Steffens, and Matthew S. Sigman deals with one of the oldest examples of transition metal catalyzed oxidation, known as the Wacker process.
