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Author: Ralph E. White
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 568
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Book Description
Volume 30 of this authoritative series provides detailed information about current advances in both fundamental and applied electrochemical research.
Author: Ralph E. White
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 568
Get Book Here
Book Description
Volume 30 of this authoritative series provides detailed information about current advances in both fundamental and applied electrochemical research.
Author: Ralph E. White
Publisher: Springer Science & Business Media
ISBN: 1441990275
Category : Science
Languages : en
Pages : 380
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Book Description
This volume of Modern Aspects contains seven chapters. The major topics covered in the first six chapters of this volume include fundamentals of solid state electrochemistry; kinetics of electrochemical hydrogen entry into metals and alloys; oxidation of organics; fuel cells; electrode kinetics of trace-anion catalysis; nano structural analysis. The last chapter is a corrected version of chapter four from Volume 35. Faisal M. AI-faqeer and Howard W. Pickering begin the first chapter by going back to 1864 and Cailletet who found that some hydrogen evolved and was absorbed by iron when it was immersed in dilute sulfuric acid. The absorption of hydrogen into metals and alloys can lead to catastrophic failures of structures. They discuss the kinetics of electrochemical hydrogen entry into metals and alloys. In chapter three, Clyde L. Briant reviews the electrochemistry, corrosion and hydrogen embrittlement of unalloyed titanium. He begins by reviewing the basic electrochemistry and general corrosion of titanium. He also discusses pitting and galvanostatic corrosion followed by a review of hydrogen embrittlement emphasizing the formation of hydrides and the effect of these on titanium's mechanical properties. Christos Comninellis and Gy6rgy F6ti discuss the oxidative electrochemical processes of organics in chapter three. They begin by defining direct and indirect electrochemical oxidation of organics. They introduce a model that allows them to distinguish between active (strong) and non-active (weak) anodes. Different classes of organic compounds are used for kinetic models of organic oxidation at active and non-active type anodes.
Author: J. O’M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1461574463
Category : Science
Languages : en
Pages : 461
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Book Description
The present collection of articles follows the arrangement used in previous volumes. Solutions are discussed first, surfaces and double layers second, electrode kinetics third, and then the applied subjects. The introduction of spectroscopic methods to electrochemistry is well exemplified by NMR studies of ionic solutions, as represented here in the detailed article by E. von Goldammer. Correspondingly, the spectroscopic approach can be applied to surfaces, and B. G. Baker has written an introduction to this topic for electrochemists from the point of view of gas phase measurements. One of the topics which begins to reach a degree of sophistica tion in electrode process chemistry is the adsorption of organic species on electrodes, and this topic is described in our volume by the well-known electrochemist M. W. Breiter. The work has much rele vance to the corresponding electrode kinetics and oxidation of organic materials. Much less sophisticated is the position in the electrochemistry of sulfide minerals, but it has seemed worthwhile to have the present record described by D. F. A. Koch; his chapter demonstrates the value of qualitative electrochemical studies in this field. The Hydrogen Economy is perhaps an example of straw fire in electrochemistry, for its great popularity beginning in 1973 reflects an interest which can hardly grow larger. However, much discussion of the Hydrogen Economy is concerned with its nonelectrochemical v vi Preface aspects and D. P. Gregory gives here the latest from the hydrogen front, with emphasis on the electrochemistry.
Author: John Bockris
Publisher: Springer Science & Business Media
ISBN: 1461574587
Category : Science
Languages : en
Pages : 674
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Book Description
This volume contains eight chapters covering a wide range of topics: ultrasonic vibration potentials, impedance measurements, photo electrochemical kinetics, chlorine production, electrochemical behavior of titanium, structural properties of membranes, bioelec troche mistry, and small-particle effects for electrocatalysis. Chapter 1, contributed by Zana and Yeager, discusses the little used but potentially important area of ultrasonic vibration potentials. The authors review the historical literature and the associated theoretical equations. They continue by discussing various aspects of the experimental technique and close with a review of the existing studies. They conclude by noting that vibra tion potentials may be useful for determining the effects of various agents on colloidal suspensions found in such important industries as paper production. Chapter 2 is a review of impedance techniques, written by Macdonald and McKubre. The authors include not only derivations of various impedance functions for electrochemical systems but also particularly useful discussions of instrumental methods. The authors close with an interesting claim: "the distribution of current and potential within a porous battery or fuel-cell electrode and within 'flow-through' electrodes is best analyzed in terms of the frequency dispersion of the impedance." Chapter 3, by Khan and Bockris, is a timely review of photo electrochemical kinetics and related devices. Their work begins by reviewing critically important papers on photoelectrochemical kinetics. They continue by presenting detailed discussions concern ing the conceptual ideas of the semiconductor-solution interface.
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 0306461676
Category : Science
Languages : en
Pages : 820
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Book Description
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.
Author: Ralph E. White
Publisher: Springer Science & Business Media
ISBN: 038746106X
Category : Science
Languages : en
Pages : 367
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Book Description
This volume in the acclaimed series Modern Aspects of Electrochemistry starts with a dedication to the late Professor Brian Conway who for 50 years helped to guide this series to its current prominence. The remainder of the volume is then devoted to the following topics: PEM fuel cells; the use of graphs in electrochemical reaction newtworks; nanomaterials in Lithium-ion batteries; direct methanolf fuel cells (two chapters); fuel cell catalyst layers. The book is for electrochemists, electrochemical engineers, fuel cell workers and energy generation workers.
Author: John O M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1461574552
Category : Science
Languages : en
Pages : 440
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Book Description
The present volume contains five chapters covering areas of contemporary interest in the fields of electrolyte solutions, the state of solvent molecules at electrode surfaces, charged colloid interfaces, surface chemistry of oxide electrodes and electro chemistry, and bioelectrochemistry of charge transfer complexes. The first chapter, by Barthel, Wachter, and Gores, covers the topic of conductance of nonaqueous pro tic and aprotic electro lyte solutions. This field is not only of intrinsic interest in itself, illustrating the important departures of ion-transport behavior in organic solvents from that, more well known, in water, but the information and extensive new data presented in this chapter will be of interest to those working with nonaqueous alkali-metal batteries where the conductivity and ion-association behavior of electrolytes in various solvents other than water is of great importance. The second chapter is devoted to a very fundamental and ubiquitous aspect of electrochemistry of electrodes: the state of solvent molecules, adsorbed and oriented, at their surfaces. The role of solvent adsorption and orientation in double-layer proper ties, it will be recalled, remained poorly understood until the early 1960s. This chapter, by Trasatti, gives a thorough account of the present state of knowledge of solvent orientation at electrode interfaces and of the unsuspected (until recent years) role it plays in properties of the double layer and in determining the potential profile at charged metal surfaces in solution.
Author: Brian E. Conway
Publisher: Springer Science & Business Media
ISBN: 1461317916
Category : Science
Languages : en
Pages : 376
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Book Description
This volume of Modern Aspects of Electrochemistry contains six chapters. The first four chapters are about phenomena of interest at the microscopic level and the last two are on phenomena at the macroscopic level. In the first chapter, Uosaki and Kita review various theoretical models that have been presented to describe the phenomena that occur at an electrolyte/ semiconductor interface under illumination. In the second chapter, Orazem and Newman discuss the same phenomena from a different point of view. In Chapter 3, Bogus lavsky presents state-of-the-art considerations of transmembrane potentials and other aspects of active transport in biological systems. Next, Burke and Lyons present a survey of both the theoretical and the experimental work that has been done on hydrous oxide films on several metals. The last two chapters cover the topics of the production of chlorine and caustic and the phenomena of electrolytic gas evol ution. In Chapter 5, Hine et al. describe the engineering aspects of the three processes used in the chi or-alkali industry, and in Chapter 6, Sides reviews the macroscopic phenomena of nucleation, growth, and detachment of bubbles, and the effect of bubbles on the conduc tivity of and mass transfer in electrolytes.
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 9780306451461
Category : Comics & Graphic Novels
Languages : en
Pages : 424
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Book Description
From reviews of previous volumes: 'This volume continues the valuable service that has been rendered by the Modern Aspects series.'-Journal of Electroanalytical Chemistry 'Extremely well referenced and very readable....Maintains the overall high standards of the series.'-Journal of the American Chemical Society
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 9780306487033
Category : Science
Languages : en
Pages : 572
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Book Description
Topics in Number 38 include: -Solid State Electrochemistry encompassing modern equilibria concepts, thermodymanics and kinetics of charge carriers in solids. -Electron transfer processes, with special sections devoted to hydration of the proton and its heterogeneous transfer. -Electrosorption at electrodes and its relevance to electrocatalysis and electrodeposition of metals. -The behavior of Pt and other alloy electrocatalyst crystallites used as the electrode materials for phosphoric acid electrolyte fuel-cells. -Applications of reflexology and electron microscopy to the materials science aspect of metal electrodes. -Electroplating of metal matrix composites by codeposition of suspended particles, a process that has improved physical and electrochemical properties. From reviews of previous volumes: "This long-standing series continues its tradition of offering high quality reviews of established and emerging subject areas, together with the less common aspects of electrochemical science ... Deserves a place in electrochemistry libraries and should prove useful to electrochemists and related workers" -Chemistry and Industry "Continues the valuable service that has been rendered by the Modern Aspects series." -Journal of Electroanalytical Chemistry "Will definitely be of much use to researchers in the field of electrochemistry ... The editors of this well-produced volume deserve all appreciation for maintaining the excellent standard of the series." -Bulletin of Electrochemistry "Extremely well-referenced and very readable ... Maintains the overall high standards of the series." -Journal of the American Chemical Society
