Metallurgical Studies of Niobium-uranium Alloys

Metallurgical Studies of Niobium-uranium Alloys PDF Author: John A. DeMastry
Publisher:
ISBN:
Category : Niobium alloys
Languages : en
Pages : 50

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In a continuing program, fabrication characteristics, physical and mechanical properties, and corrosion behavior in air, CO2, NaK, water, and steam were studied for . binary niobium fuel alloys containing 10, 20, 30, 40, 50, and 60 wt.% uranium To evaluate the effects of two major impurities of niobium, oxygen, and zirconium, three niobium base stocks, differing according to the level of these impurities, were used for each alloy. The impurity combinations employed were 600 ppm oxygen and 0.74 wt.% zirconium, 700 ppm oxygen, and 0.17 wt.% zirconium, and 300 ppm oxygen and 0.02 wt.% zirconium, Representative specimens of these alloys retained their hardness up to 900 deg C The 10 and 20 wt.% uraniuin alloys were successfully rorged at 2500 deg F and rolled at 1800 deg F to sheet. Fabrication characteristics of the remaining alloys are under investigation. The 0.2% offset yield strength of the 10 wt.% uranium alloy was 57,200 psi at room temperature and 36,900 psi at 1600 deg F. For the 20 wt.% uranium alloy it was 93,200 psi at room temperature and 71.000 psi at 1600 deg F. The corrosion life of all of the alloys in air at 572 deg F and in CO2 at 600 deg F was superior to that of unalloyed niobium. In 1000- hr exposures to 600 deg F water most of the alloys exhibited corrosion rates only two or three times greater than that of Zircaloy-2. All oi the alloys appear compatible with NaK at 1600 deg F. The impurity combinations employed in the base niobium appeared to have no effect on the corrosion behavior and mechanical properties of the alloys. (auth).

Physical Metallurgy of Uranium Alloys

Physical Metallurgy of Uranium Alloys PDF Author: John J. Burke
Publisher:
ISBN:
Category : Materials
Languages : en
Pages : 1036

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Physical Metallurgy of Uranium

Physical Metallurgy of Uranium PDF Author: Abe Noel Holden
Publisher:
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 282

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The Metallurgy of Nuclear Fuel

The Metallurgy of Nuclear Fuel PDF Author: V. S. Yemel'Yanov
Publisher: Elsevier
ISBN: 1483186024
Category : Technology & Engineering
Languages : en
Pages : 600

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Book Description
The Metallurgy of Nuclear Fuel: Properties and Principles of the Technology of Uranium, Thorium and Plutonium is a systematic analysis of the metallurgy of nuclear fuel, with emphasis on the physical, mechanical, and chemical properties as well as the technology of uranium, thorium, and plutonium, together with their alloys and compounds. The minerals and raw material sources of nuclear fuel are discussed, along with the principles of the technology of the raw material processing and the production of the principal compounds, and of the pure metals and alloys. Comprised of three parts, this volume begins with an introduction to the history of the discovery of uranium and its position in the periodic system; its use as a nuclear fuel; radioactivity and isotopic composition; alloys and compounds; and physical, mechanical, and chemical properties. The effect of mechanical and thermal treatment, thermal cycling and irradiation on the physicochemical properties of uranium is also examined. The next two sections are devoted to thorium and plutonium and includes chapters dealing with their uses, alloys and compounds, and methods of recovery and purification. This book is written for university students, but should also prove useful to young production engineers and scientific workers who are concerned with problems in the metallurgy of nuclear fuel.

Fundamental and Applied Research and Development in Metallurgy

Fundamental and Applied Research and Development in Metallurgy PDF Author: A. R. Kaufmann
Publisher:
ISBN:
Category : Uranium alloys
Languages : en
Pages : 88

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Metallurgical Technology of Uranium and Uranium Alloys: Physical metallurgy of uranium and uranium alloys

Metallurgical Technology of Uranium and Uranium Alloys: Physical metallurgy of uranium and uranium alloys PDF Author:
Publisher:
ISBN:
Category : Uranium
Languages : en
Pages : 362

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Development of Niobium Diffusion Barriers for Aluminum-clad Uranium Alloy Fuel Elements

Development of Niobium Diffusion Barriers for Aluminum-clad Uranium Alloy Fuel Elements PDF Author: B. N. Briggs
Publisher:
ISBN:
Category : Niobium
Languages : en
Pages : 56

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Diffusion Studies in the Uranium - Niobium System

Diffusion Studies in the Uranium - Niobium System PDF Author: Norman L. Peterson
Publisher:
ISBN:
Category :
Languages : en
Pages : 116

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Development of Niobium-uranium Alloys for Elevated-temperature Fuel Applications

Development of Niobium-uranium Alloys for Elevated-temperature Fuel Applications PDF Author: John A. DeMastry
Publisher:
ISBN:
Category : Niobium alloys
Languages : en
Pages : 72

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Book Description
As a continuation of studies reported in BMI-1400, fabrication characteristics, physical and mechanical properties, and corrosion behavior in NaK, sodium, and water of niobium--uranium binary alloys containing up to 60 wt.% uranium were investigated. Alloys were cast by a skull melting and consumable and nonconsumable arc-melting methods. Fabrication difficulties with alloys containing greater than 25 wt.% uranium were related to coring-type microsegregation during casting. Tensile tests indicated 0.2% offset yield strengths of 16,880, 22,370 and 28,600 psi for niobium2000 deg F. Additional tensile data were obtained for alloys from 1600 to 2400 deg F. Stresses to produce minimum creep rates of 0.001, 0.01, and 0.1%/hr at 1600, 1800, and 2000 deg F were also determined. Both tensile and creep strengths were found to be sensitive to oxygen content. All alloys appeared compatible with NaK at 1600 deg F and with sodium at 1500 deg F. In 600 deg F water, most of the alloys tested exhibited negligible weight changes after 336 days' exposure. Weight changes were greater after 140 days' exposure to 680 deg F water, but corrosion rates were considered satisfactory for a clad fuel. The thermal and electrical conductivities of niobium are lowered by the addition of uranium, while the thermal-expansion characteristics are essentially unaffected. Recrystallization temperatures for 90% cold-reduced niobium-4.38, -14.3, -20, -25.0, and -30 wt.% uranium alloys are 2300, 2300, 2400, 2300, and 2200 deg F, respectively. No appreciable effect of oxygen contents ranging from 100 to 1000 ppm was observed on the composition limits of the gamma immiscibility gap in the niobium-- uranium system. (auth).

Bibliography on Uranium Alloys

Bibliography on Uranium Alloys PDF Author: Helen C. Friedemann
Publisher:
ISBN:
Category : Uranium
Languages : en
Pages : 76

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