Metallocenes and Asymmetry

Metallocenes and Asymmetry PDF Author: Héctor González
Publisher:
ISBN:
Category :
Languages : en
Pages : 278

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Book Description

Metallocenes and Asymmetry

Metallocenes and Asymmetry PDF Author: Héctor González
Publisher:
ISBN:
Category :
Languages : en
Pages : 278

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Book Description


Asymmetric Synthesis of Helical Metallocenes

Asymmetric Synthesis of Helical Metallocenes PDF Author: Anantha R. Sudhakar
Publisher:
ISBN:
Category : Metallocenes
Languages : en
Pages : 868

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Metallocenes in Regio- and Stereoselective Synthesis

Metallocenes in Regio- and Stereoselective Synthesis PDF Author: Tamotsu Takahashi
Publisher: Springer Science & Business Media
ISBN: 9783540016069
Category : Science
Languages : en
Pages : 260

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Book Description
Metallocene is a well known sandwich complex with two cyclopentadienyl ligands such as ferrocene. Recently, such metallocene compounds have been found to be very characteristic and they have become very important, not only in the area of organic synthesis, but also in polymerization in industry. Metal complexes with one cyclopentadienyl ligand have also become popular as half sandwich complexes. The number of researchers in the field of metallocenes has increased rapidly. However, the origin of the characteristic reactivity of metallocenes is not fully understood. In this volume, the chemistry of metal complexes with at least one cyclopentadienyl ligand is comprehensively covered by leading experts. Reactions discussed here are (i) natural product synthesis, (ii) catalytic asymmetric synthesis, (iii) cyclization reactions, (iv)catalytic reactions, (iv) polymerization reactions and (v) carbon-carbon bond cleavage reactions. The reader will have access to useful information about the current state of metallocene chemistry.

Fundamentals of Asymmetric Catalysis

Fundamentals of Asymmetric Catalysis PDF Author: Patrick J. Walsh
Publisher: University Science Books
ISBN: 9781891389542
Category : Science
Languages : en
Pages : 692

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Book Description
This work describes the essential aspects of enantioselective catalysis, with chapters organised by concept rather than by reaction type. Each concept is supported by examples to give the reader broad exposure to a wide range of catalysts, reactions and reaction mechanisms.

Topics in Stereochemistry

Topics in Stereochemistry PDF Author: Norman L. Allinger
Publisher: John Wiley & Sons
ISBN: 0470147326
Category : Science
Languages : en
Pages : 268

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Book Description
This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.

The Synthesis and Application of Bulky Metallocenes to Asymmetric Catalysis

The Synthesis and Application of Bulky Metallocenes to Asymmetric Catalysis PDF Author: Geraint Jones
Publisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 370

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Synthesis and Asymmetric Reactivity of Electronically and Sterically Differentiating Chiral Cyclopentadienyl Metal Complexes

Synthesis and Asymmetric Reactivity of Electronically and Sterically Differentiating Chiral Cyclopentadienyl Metal Complexes PDF Author: Ronald Lee Halterman
Publisher:
ISBN:
Category :
Languages : en
Pages : 486

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New Chiral C1-symmetric Metallocenes Designed for Asymmetric Catalysis

New Chiral C1-symmetric Metallocenes Designed for Asymmetric Catalysis PDF Author: Michael Albert Giardello
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Metallocenes in Regio- and Stereoselective Synthesis

Metallocenes in Regio- and Stereoselective Synthesis PDF Author: Marko Hapke
Publisher: Springer Nature
ISBN: 3031573811
Category :
Languages : en
Pages : 208

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Book Description


Metallocenes

Metallocenes PDF Author: Antonio Togni
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 576

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Book Description
That terms like sandwich complexes or the concept of compounds without direct chemical bonds between the central metal atom and the ligating atoms are nowadays common knowledge can be attributed to the sensational discovery of ferrocene in the early 1950s. Although ferrocene is still at the forefront of research, this two-volume book highlights the development of metallocene chemistry, and emphasizes the similarities and differences between ferrocene and other metallocenes. Do you require a transition metal to build metallocenes? Must the planes of the cyclopentadienyl ligands be parallel to allow the compound to behave like a typical metallocene? Do zirconocenes react by the same mechanism as molybdenocenes? What are the (potential) applications of these substances? Let yourself be guided by the leading experts in this field, and learn all about the synthesis, reactivity, and unique properties of these sandwich complexes. If you are more interested in applications, there is a wealth of polymeric and dendritic materials with metallocene building blocks described herein. This book also focusses on metallocenes as catalysts in polymerization or asymmetric reactions. If you are graduate student or researcher in organic, inorganic, organometallic, polymer chemistry, and materials science you will find this book an inspiring source of ideas for your own research.