Author: Xile Hu
Publisher:
ISBN:
Category :
Languages : en
Pages : 496
Book Description
Metal Complexes of Tripodal N-heterocyclic Carbene Ligands
High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes
Author: Carola S. Vogel
Publisher: Springer Science & Business Media
ISBN: 3642272533
Category : Science
Languages : en
Pages : 145
Book Description
Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.
Publisher: Springer Science & Business Media
ISBN: 3642272533
Category : Science
Languages : en
Pages : 145
Book Description
Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.
Novel N-Heterocyclic Carbene Ligands and Their Metal Complexes
Author: Tongxun Guo
Publisher:
ISBN: 9783954049998
Category :
Languages : en
Pages : 185
Book Description
Publisher:
ISBN: 9783954049998
Category :
Languages : en
Pages : 185
Book Description
Transition Metal Complexes of Neutral Eta1-Carbon Ligands
Author: Remi Chauvin
Publisher: Springer Science & Business Media
ISBN: 3642047211
Category : Science
Languages : en
Pages : 260
Book Description
This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.
Publisher: Springer Science & Business Media
ISBN: 3642047211
Category : Science
Languages : en
Pages : 260
Book Description
This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.
Metal Complexes of Di(N-heterocyclic Carbene) Ligands
Author: Kim S. Flaig
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Novel Di(N-heterocyclic Carbene) Ligands and Related Transition Metal Complexes
Author: Marco Monticelli
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
The PhD, a collaboration between the University of Padova and the University of Strasbourg, is focused on the chemistry of di(N-heterocyclic carbene) ligands and can be divided in four families of ligands that constitute the four chapters: i) metal complexes (Cu(I), Ag(I), Au(I), Ir(III), Ru(II)) with di(N-heterocyclic carbene) ligands bearing a rigid phenylene bridge between the carbene units; ii) metal complexes (Cu(I), Ag(I), Au(I), Ru(II)) combining an imidazole-based NHC ligand functionalized with a triazole in the 5 position of the backbone; iii) metal complexes (Ag(I), Au(I), Pd(II)) with heteroditopic ligands based on imidazol-2-ylidene and 1,2,3-triazol-5-ylidene moieties connected with a propylene bridge; iv) bis(benzoxazolium) proligands and attempted synthesis of related transition metal complex.
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
The PhD, a collaboration between the University of Padova and the University of Strasbourg, is focused on the chemistry of di(N-heterocyclic carbene) ligands and can be divided in four families of ligands that constitute the four chapters: i) metal complexes (Cu(I), Ag(I), Au(I), Ir(III), Ru(II)) with di(N-heterocyclic carbene) ligands bearing a rigid phenylene bridge between the carbene units; ii) metal complexes (Cu(I), Ag(I), Au(I), Ru(II)) combining an imidazole-based NHC ligand functionalized with a triazole in the 5 position of the backbone; iii) metal complexes (Ag(I), Au(I), Pd(II)) with heteroditopic ligands based on imidazol-2-ylidene and 1,2,3-triazol-5-ylidene moieties connected with a propylene bridge; iv) bis(benzoxazolium) proligands and attempted synthesis of related transition metal complex.
Late Transition Metal Complexes Incorporating Hemilabile Mixed-donor N-heterocyclic Carbene Ligands
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The discovery of N-heterocyclic carbenes (NHC) has dramatically affected the world of catalysis. Their inherent properties that make them excellent auxiliary ligands for catalytic processes have countless laboratories worldwide probing and exploiting every notable feature they possess. However, while there is no shortage of attention in this field of research, there has been considerably less interest in NHCs with an ability chelate to metals via a mixed-donor ligand architecture. Thus, this thesis describes the synthesis and application of a ligand set comprised of bidentate mixed-donor NHC ligands. The ligands prepared all contain a mesitylimidazol-2-ylidene core unit, but incorporate different donor-functionalized tethers. These mixed-donor NHC ligands are synthesized by using a strong base, such as KN(SiMe3)2, to deprotonate the imidazolium salt precursors. This strategy was used to effectively prepare 1-mesityl-3-(2-(mesitylamino)ethyl)imidazol-2-ylidene, Mes[CNH] and 1-mesityl-3-(2-aminoethyl)imidazol-2-ylidene, Mes[CNH2]. Mes[CNH] was found to be a convenient proligand for the synthesis of various M-NHC (M = Rh, Ir, Ru, Pd, Ni, Fe, Ag, Li) compounds. These Mes[CNH]-M complexes demonstrated the hemilabile character of the Mes[CNH] ligand forming complexes that incorporated either a coordinated or uncoordinated amino tether. Mes[CNH]M(diene)Cl, Mes[CN]M(diene) and [Mes[CNH]M(diene)]BF4(M = Rh, Ir; diene = 1,5-cyclooctadiene, 2,5-norbornadiene) were synthesized and investigated for their ability to perform hydrogenation and hydrosilylation reactions with various substrates. Mes[CNH]Ru(=CHPh)(PCy3)Cl2, Mes[CNH]Ru(=CHPh)(py)Cl2 (py = pyridine) and Mes[CNH]Ru(=CHPh)(PMe3)Cl2 were also synthesized and fully characterized. The activity of the former two Ru complexes was studied for their ability to catalyze ring-closing metathesis (RCM) and ring-opening metathesis polymerization (ROMP) reactions. In addition, the phosphine dissociation rate of Mes[CNH]Ru(=CHPh)(PCy3).
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The discovery of N-heterocyclic carbenes (NHC) has dramatically affected the world of catalysis. Their inherent properties that make them excellent auxiliary ligands for catalytic processes have countless laboratories worldwide probing and exploiting every notable feature they possess. However, while there is no shortage of attention in this field of research, there has been considerably less interest in NHCs with an ability chelate to metals via a mixed-donor ligand architecture. Thus, this thesis describes the synthesis and application of a ligand set comprised of bidentate mixed-donor NHC ligands. The ligands prepared all contain a mesitylimidazol-2-ylidene core unit, but incorporate different donor-functionalized tethers. These mixed-donor NHC ligands are synthesized by using a strong base, such as KN(SiMe3)2, to deprotonate the imidazolium salt precursors. This strategy was used to effectively prepare 1-mesityl-3-(2-(mesitylamino)ethyl)imidazol-2-ylidene, Mes[CNH] and 1-mesityl-3-(2-aminoethyl)imidazol-2-ylidene, Mes[CNH2]. Mes[CNH] was found to be a convenient proligand for the synthesis of various M-NHC (M = Rh, Ir, Ru, Pd, Ni, Fe, Ag, Li) compounds. These Mes[CNH]-M complexes demonstrated the hemilabile character of the Mes[CNH] ligand forming complexes that incorporated either a coordinated or uncoordinated amino tether. Mes[CNH]M(diene)Cl, Mes[CN]M(diene) and [Mes[CNH]M(diene)]BF4(M = Rh, Ir; diene = 1,5-cyclooctadiene, 2,5-norbornadiene) were synthesized and investigated for their ability to perform hydrogenation and hydrosilylation reactions with various substrates. Mes[CNH]Ru(=CHPh)(PCy3)Cl2, Mes[CNH]Ru(=CHPh)(py)Cl2 (py = pyridine) and Mes[CNH]Ru(=CHPh)(PMe3)Cl2 were also synthesized and fully characterized. The activity of the former two Ru complexes was studied for their ability to catalyze ring-closing metathesis (RCM) and ring-opening metathesis polymerization (ROMP) reactions. In addition, the phosphine dissociation rate of Mes[CNH]Ru(=CHPh)(PCy3).
Organic Synthesis
Author: Belakatte Parameshwarappa Nandeshwarappa
Publisher: BoD – Books on Demand
ISBN: 1789859433
Category : Science
Languages : en
Pages : 250
Book Description
The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.
Publisher: BoD – Books on Demand
ISBN: 1789859433
Category : Science
Languages : en
Pages : 250
Book Description
The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.
N-Heterocyclic Carbenes in Transition Metal Catalysis
Author: Frank Glorius
Publisher: Springer
ISBN: 9783642071973
Category : Science
Languages : en
Pages : 0
Book Description
In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.
Publisher: Springer
ISBN: 9783642071973
Category : Science
Languages : en
Pages : 0
Book Description
In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.
Carbene Chemistry
Author: Guy Bertrand
Publisher: CRC Press
ISBN: 0824743210
Category : Science
Languages : en
Pages : 278
Book Description
Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.
Publisher: CRC Press
ISBN: 0824743210
Category : Science
Languages : en
Pages : 278
Book Description
Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.