Measurement and Prediction of Phase Equilibria for the Ternary System Methane + Ethane + Carbon Dioxide and Its Constitutent Binaries at Temperatures from 203.50K to 270.00K PDF Download
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Author: Michael Sheng-Wei Wei
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 212
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Author: Michael Sheng-Wei Wei
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 212
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Book Description
Author: Robert E. Phelps
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 278
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Author: Vijay Ssingh Gupta
Publisher:
ISBN:
Category :
Languages : en
Pages : 236
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Author: Robert E. Phelps
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 64
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Author: Y. S. Kim
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
A theoretical approach, the SAFT (Statistical Associating Fluid Theory) equation of state, is adapted and extended to understand the thermodynamics and phase equilibria of systems containing carbon dioxide (CO2), CO2-philic and CO2-phobic compounds, including both small molecules (such as n-alkanes and n-perfluoroalkanes) and macromolecules (homopolymers, polymer blends and copolymers), to provide rapid reliable predictions for a wide range of systems of interest. Most prior research has concentrated on developing SAFT equations suitable for phase equilibrium calculations (vapor-liquid and liquid-liquid). In the present work we demonstrate that the SAFT equations are particularly useful not only in pressure-temperature-volume-composition phase equilibrium problems but, also for more difficult aspects of the behavior of mixtures such as derivative properties (e.g., Joule-Thomson inversion curves) and formation of aggregates. To accomplish this goal, we studied the strengths and limitations that different thermodynamic models present not only for pure CO2, but also for its mixtures with small molecules and macromolecules. The research is divided in three major areas: a) a fundamental investigation of the thermophysical properties of pure carbon dioxide, using predictions from both molecular simulations and equations of state; b) a detailed study of the phase equilibria of binary and ternary mixtures of CO2, n-perfluoroalkanes and n-alkanes as a representation of small CO2-philic and partially CO2-phobic compounds; and c) a study of phase equilibria in binary and ternary mixtures of CO2, CO2-philic and CO2-phobic polymers. The ability of the SAFT approach to perform such predictions relies on its more rigorous foundation, since it is practically the only approach that has been able to describe both small molecules and macromolecules.
Author: HAROLD GEORGE DONNELLY
Publisher:
ISBN:
Category :
Languages : en
Pages : 540
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Author: Andre Muhlbauer
Publisher: CRC Press
ISBN: 9781560325505
Category : Science
Languages : en
Pages : 490
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Book Description
This new book provides, for the first time, a thorough survey of the techniques and equipment for both high- and low-pressure phase equilibrium measurement and addresses the equally challenging task of accurately modeling or predicting the equilibria. The book is unique because it combines in depth and authoritative coverage of both experimental and theoretical procedures in a single volume. Written as a reference for practicing engineers and scientists in the chemical engineering field, this book will also be useful as an advanced graduate-level text.
Author: Ajit A. Kulkarni
Publisher:
ISBN:
Category :
Languages : en
Pages : 248
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Author: Ivan Wichterle
Publisher:
ISBN:
Category :
Languages : en
Pages :
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