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Languages : en
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TDA Research, Inc. has developed a novel sorbent based post-combustion CO2 removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO2 capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO2 produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO2 produced with the lowest possible increase in the cost of energy.
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Languages : en
Pages :
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Book Description
TDA Research, Inc. has developed a novel sorbent based post-combustion CO2 removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO2 capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO2 produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO2 produced with the lowest possible increase in the cost of energy.
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Category :
Languages : en
Pages : 114
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In this project TDA Research, Inc (TDA) has developed a new post combustion carbon capture technology based on a vacuum swing adsorption system that uses a steam purge and demonstrated its technical feasibility and economic viability in laboratory-scale tests and tests in actual coal derived flue gas. TDA uses an advanced physical adsorbent to selectively remove CO2 from the flue gas. The sorbent exhibits a much higher affinity for CO2 than N2, H2O or O2, enabling effective CO2 separation from the flue gas. We also carried out a detailed process design and analysis of the new system as part of both sub-critical and super-critical pulverized coal fired power plants. The new technology uses a low cost, high capacity adsorbent that selectively removes CO2 in the presence of moisture at the flue gas temperature without a need for significant cooling of the flue gas or moisture removal. The sorbent is based on a TDA proprietary mesoporous carbon that consists of surface functionalized groups that remove CO2 via physical adsorption. The high surface area and favorable porosity of the sorbent also provides a unique platform to introduce additional functionality, such as active groups to remove trace metals (e.g., Hg, As). In collaboration with the Advanced Power and Energy Program of the University of California, Irvine (UCI), TDA developed system simulation models using Aspen PlusTM simulation software to assess the economic viability of TDA's VSA-based post-combustion carbon capture technology. The levelized cost of electricity including the TS & M costs for CO2 is calculated as $116.71/MWh and $113.76/MWh for TDA system integrated with sub-critical and super-critical pulverized coal fired power plants; much lower than the $153.03/MWhand $147.44/MWh calculated for the corresponding amine based systems. The cost of CO2 captured for TDA's VSA based system is $38.90 and $39.71 per tonne compared to $65.46 and $66.56 per tonne for amine based system on 2011 $ basis, providing 40% lower cost of CO2 captured. In this analysis we have used a sorbent life of 4 years. If a longer sorbent life can be maintained (which is not unreasonable for fixed bed commercial PSA systems), this would lower the cost of CO2 captured by $0.05 per tonne (e.g., to $38.85 and $39.66 per tonne at 5 years sorbent replacement). These system analysis results suggest that TDA's VSA-based post-combustion capture technology can substantially improve the power plant's thermal performance while achieving near zero emissions, including greater than 90% carbon capture. The higher net plant efficiency and lower capital and operating costs results in a substantial reduction in the cost of carbon capture and cost of electricity for the power plant equipped with TDA's technology.
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ISBN:
Category :
Languages : en
Pages : 183
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Author: National Academies of Sciences, Engineering, and Medicine
Publisher: National Academies Press
ISBN: 0309484529
Category : Science
Languages : en
Pages : 511
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Book Description
To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.
Author: Paul Feron
Publisher: Woodhead Publishing
ISBN: 0081005156
Category : Technology & Engineering
Languages : en
Pages : 816
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Book Description
Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon dioxide. As fossil fuel-based power generation technologies are likely to remain key in the future, at least in the short- and medium-term, carbon capture and storage will be a critical greenhouse gas reduction technique. Post-combustion capture involves the removal of carbon dioxide from flue gases after fuel combustion, meaning that carbon dioxide can then be compressed and cooled to form a safely transportable liquid that can be stored underground. - Provides researchers in academia and industry with an authoritative overview of the amine-based methods for carbon dioxide capture from flue gases and related processes - Editors and contributors are well known experts in the field - Presents the first book on this specific topic
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309305322
Category : Science
Languages : en
Pages : 235
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Book Description
The signals are everywhere that our planet is experiencing significant climate change. It is clear that we need to reduce the emissions of carbon dioxide and other greenhouse gases from our atmosphere if we want to avoid greatly increased risk of damage from climate change. Aggressively pursuing a program of emissions abatement or mitigation will show results over a timescale of many decades. How do we actively remove carbon dioxide from the atmosphere to make a bigger difference more quickly? As one of a two-book report, this volume of Climate Intervention discusses CDR, the carbon dioxide removal of greenhouse gas emissions from the atmosphere and sequestration of it in perpetuity. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration introduces possible CDR approaches and then discusses them in depth. Land management practices, such as low-till agriculture, reforestation and afforestation, ocean iron fertilization, and land-and-ocean-based accelerated weathering, could amplify the rates of processes that are already occurring as part of the natural carbon cycle. Other CDR approaches, such as bioenergy with carbon capture and sequestration, direct air capture and sequestration, and traditional carbon capture and sequestration, seek to capture CO2 from the atmosphere and dispose of it by pumping it underground at high pressure. This book looks at the pros and cons of these options and estimates possible rates of removal and total amounts that might be removed via these methods. With whatever portfolio of technologies the transition is achieved, eliminating the carbon dioxide emissions from the global energy and transportation systems will pose an enormous technical, economic, and social challenge that will likely take decades of concerted effort to achieve. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration will help to better understand the potential cost and performance of CDR strategies to inform debate and decision making as we work to stabilize and reduce atmospheric concentrations of carbon dioxide.
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Languages : en
Pages :
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Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO2 capture. The project objective was to address the viability and accelerate development of a solid-based CO2 capture technology. To meet this objective, initial evaluations of sorbents and the process/equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO2 capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines; 31 carbon based materials; 6 zeolites; 7 supported carbonates (evaluated under separate funding); and 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant's Martin Lake Steam Electric Station and Xcel Energy's Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO2 removal with the sorbents evaluated under this program, it was useful to compare the CO2 removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the cocurrent adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO2 for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO2 removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO2 capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO2 uptake rate. Three additional supported amine materials, sorbents AX, F, and BN, were selected for evaluation using the 1 kW pilot at Sherco. Sorbent AX was operated in batch mode and performed similarly to sorbent R (i.e. could achieve up to 90% removal when given adequate regeneration time). Sorbent BN was not expected to be subject to the same mass diffusion limitations as experienced with sorbent R. When sorbent BN was used in continuous mode the steady state CO2 removal was approximately double that of sorbent R, which highlighted the importance of sorbents without kinetic limitations.
Author: Kaspars Krutkramelis
Publisher:
ISBN: 9781124555058
Category : Carbon sequestration
Languages : en
Pages : 105
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Book Description
Solid state carbonaceous sorbents are tested and evaluated as potential materials for CO2 capture from coal-fired power plant flue gas. In order to establish economic viability for CO2 capture of carbon materials, elementary adsorption and regeneration experiments have been performed. It has been known that carbon materials have fairly low heat of sorption towards CO2, approximately 20 [kJ/mol CO2] for AC-1. This is advantageous, if one considers and anticipates approximately similar regeneration energy for CO2 release and capture. However, further research in desorption methods demonstrates significantly larger regeneration energy requirements than previously thought. An original direct steam regeneration approach requires theoretical regeneration energy at approximately 311 [kJ/mol CO2] and experimental measurements suggest values closer to 443 [kJ/mol CO2]. Vacuum regeneration is explored next as a potential method for lower desorption energy. It is found that the vacuum desorption process is a considerably better selection with approximately 28 [kJ/mol CO2] theoretical energy requirement for ambient pressure sorption, and 56 and, 85 [kJ/mol CO2] for 3.92 [bar] and 9.72 [bar] PSA respectively. Nevertheless, due to efficiency limitations of physical vacuum systems, CO2 capture by vacuum desorption surges to approximately 101 [kJ/mol CO2] for ambient pressure sorption, and the best case scenario CO2 nominal capture cost is calculated at $40.49/tCO2.
Author: Deepak Pant
Publisher: Springer Nature
ISBN: 9811606382
Category : Science
Languages : en
Pages : 331
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Book Description
This book focuses on the recent trends in carbon management and up-to-date information on different carbon management strategies that lead to manage increasing concentration of atmospheric carbon dioxide. The growing evidence of climate change resulting from the continued increase of atmospheric carbon dioxide concentration has made it a high profile political–social and trade issue. The mean global average earth temperature rose by 0.6± 2°C during the second half of the century with the rate of 0.17°C/decade. As per GISS data in the year of 2017, it rose 0.9°C (1.62 °F) above the 1951-1980 mean global temperature. Recently World Meteorological Organization analyzes the past record temperature and found the past 10 years were the warmest years about 1.1°C above preindustrial level. Over the past decade, carbon management by various techniques has to come to fore as a way to manage carbon dioxide emissions contributing to climate change. The proposed book addresses the need for an understanding of sustainable carbon dioxide management technologies mainly focused on (a) minimizing carbon dioxide emission from sources; (b) maximizing environmentally sound recuse, reduce and recycling; (c)emerging technology toward carbon dioxide mitigation and d) converting carbon dioxide into valuable products form sustainable use. Other books related to carbon management attempt to cover the carbon capture and sequestration, carbon mineralization, utilization and storage but the topic of CO2 management strategies is not discussed in detail for sustainable development. Furthermore, this book also covers all physical, chemical and biological process for long-term capture, removal and sequestration of carbon dioxide from the atmosphere for sustainable management which is not described in other carbon management books. In order to meet CO2 emissions reduction target, a range of technological approaches, including development of clean fuels and clean coal technologies, adopting cleaner and more energy efficiency and conservation, developing renewable energy and implementing CCS technologies, will also be considered for sustainable future.
Author: Mohammad Reza Rahimpour
Publisher: Woodhead Publishing
ISBN: 0128227583
Category : Science
Languages : en
Pages : 574
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Book Description
Advances in Carbon Capture reviews major implementations of CO2 capture, including absorption, adsorption, permeation and biological techniques. For each approach, key benefits and drawbacks of separation methods and technologies, perspectives on CO2 reuse and conversion, and pathways for future CO2 capture research are explored in depth. The work presents a comprehensive comparison of capture technologies. In addition, the alternatives for CO2 separation from various feeds are investigated based on process economics, flexibility, industrial aspects, purification level and environmental viewpoints. - Explores key CO2 separation and compare technologies in terms of provable advantages and limitations - Analyzes all critical CO2 capture methods in tandem with related technologies - Introduces a panorama of various applications of CO2 capture
