Author: Richard W. Weiss
Publisher: Springer Science & Business Media
ISBN: 3642518893
Category : Science
Languages : en
Pages : 714
Book Description
The aim of this compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limi~ed to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions, and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in ''Die Chemie der metall-organischen Verbindungen," Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin, and lead. Volume III contains derivatives of arsenic, antimony, and bismuth. The compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the .. coverage of the literature complete in order that the compilation may have best ~i1ity to the chemist, chemical engineer, patent attorney, and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.
Lead: R3PbR' compounds
Author: Friedo Huber
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 432
Book Description
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 432
Book Description
Compounds of Germanium, Tin, and Lead, including Biological Activity and Commercial Application
Author: Richard W. Weiss
Publisher: Springer Science & Business Media
ISBN: 3642518893
Category : Science
Languages : en
Pages : 714
Book Description
The aim of this compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limi~ed to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions, and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in ''Die Chemie der metall-organischen Verbindungen," Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin, and lead. Volume III contains derivatives of arsenic, antimony, and bismuth. The compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the .. coverage of the literature complete in order that the compilation may have best ~i1ity to the chemist, chemical engineer, patent attorney, and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.
Publisher: Springer Science & Business Media
ISBN: 3642518893
Category : Science
Languages : en
Pages : 714
Book Description
The aim of this compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limi~ed to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions, and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in ''Die Chemie der metall-organischen Verbindungen," Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin, and lead. Volume III contains derivatives of arsenic, antimony, and bismuth. The compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the .. coverage of the literature complete in order that the compilation may have best ~i1ity to the chemist, chemical engineer, patent attorney, and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.
Lead: R2PbR2', R2PbR'R", RPbR'R"R'", and R4-nPbHn (n
Author: Friedo Huber
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 214
Book Description
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 214
Book Description
Aliphatic Compounds
Author: M. F. Ansell
Publisher: Elsevier
ISBN: 008088072X
Category : Technology & Engineering
Languages : en
Pages : 285
Book Description
Aliphatic Compounds
Publisher: Elsevier
ISBN: 008088072X
Category : Technology & Engineering
Languages : en
Pages : 285
Book Description
Aliphatic Compounds
Organometallic Compounds Literature Survey 1937–1958
Author: Michael Dub
Publisher: Springer
ISBN: 3662430746
Category : Science
Languages : en
Pages : 382
Book Description
Publisher: Springer
ISBN: 3662430746
Category : Science
Languages : en
Pages : 382
Book Description
Organometallic Compounds
Author: B. J. Aylett
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
Book Description
A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
Book Description
A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
The Organic Compounds of Lead
Author: Hymin Shapiro
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 522
Book Description
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 522
Book Description
Organometallic Compounds of the Grooup IV Elements: The bond to halogens and hologenoids. (2v)
Author: Alan G. MacDiarmid
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 256
Book Description
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 256
Book Description
A Text-book of Inorganic Chemistry
Author: John Newton Friend
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 456
Book Description
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 456
Book Description
Organometallic Compounds of the Group IV Elements: Synthesis and properties of the silicon-halogen and silicon-halogenoid bond
Author: Alan G. MacDiarmid
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 290
Book Description
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 290
Book Description