Lead: R2PbR2', R2PbR'R", RPbR'R"R'", and R4-nPbHn (n PDF Download
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Author: Friedo Huber
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 214
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Author: Friedo Huber
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 214
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Book Description
Author: Richard W. Weiss
Publisher: Springer Science & Business Media
ISBN: 3642502903
Category : Science
Languages : en
Pages : 1139
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Author: Michael Dub
Publisher: Springer
ISBN: 3662430746
Category : Science
Languages : en
Pages : 382
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Author: M. F. Ansell
Publisher: Elsevier
ISBN: 9780080880723
Category : Science
Languages : en
Pages : 477
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Aliphatic Compounds
Author: Alan G. MacDiarmid
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 288
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Author: B. J. Aylett
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
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A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Author: Alan G. MacDiarmid
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages : 288
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Author:
Publisher: Academic Press
ISBN: 9780080580050
Category : Science
Languages : en
Pages : 421
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Advances in Organometallic Chemistry
Author: Michael Dub
Publisher:
ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 726
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Author: L. C. Willemsens
Publisher:
ISBN:
Category : Organolead compounds
Languages : en
Pages : 164
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