Laser Spectroscopy and Dynamics of Transient Species. Final Progress Report, June 1, 1986 - May 31, 1996 PDF Download
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Languages : en
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Languages : en
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Languages : en
Pages : 4
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Work on sub-Doppler spectroscopy of thioformaldehyde is nearing completion; the sub-Doppler structure in the H[sub 2]CS spectrum correlates with previous observations of anomalously long fluorescence lifetimes and reduced quantum yields of fluorescence under collision-free conditions. Singlet-triplet perturbations are large and occur haphazardly when levels in the two states are near- coincidence. High-resolution FTIR spectra of many bands of HCOCl and DCOCl have been recorded. Laser fluorescence on formic acid is being studied. Reactive jet spectroscopy is being used to produce new reactive intermediates in F[sub 2]/Ar gas streams. Preliminary experiments are underway in S[sub 3] and S[sub 4] systems.
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Languages : en
Pages : 15
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This research concerns the study of the spectroscopy and excited state dynamics of a number of transient molecules containing either sulfur or oxygen. The identification and study of sulfur species which are analogs of important oxygen-containing combustion intermediates is important to our understanding of reactive intermediates. The oxygen-containing species chosen for study are new systems whose electronic spectra have not previously been identified. The major experimental technique used in this work was pyrolysis jet spectroscopy. Since many of the species have not been previously studied by laser techniques, much effort was devoted to determining methods for producing and observing them. We have been very successful in a number of cases and have developed some further experimental techniques.
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Languages : en
Pages : 4
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Work on sub-Doppler spectroscopy of thioformaldehyde is nearing completion; the sub-Doppler structure in the H2CS spectrum correlates with previous observations of anomalously long fluorescence lifetimes and reduced quantum yields of fluorescence under collision-free conditions. Singlet-triplet perturbations are large and occur haphazardly when levels in the two states are near- coincidence. High-resolution FTIR spectra of many bands of HCOCl and DCOCl have been recorded. Laser fluorescence on formic acid is being studied. Reactive jet spectroscopy is being used to produce new reactive intermediates in F2/Ar gas streams. Preliminary experiments are underway in S3 and S4 systems.
Author:
Publisher:
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Category :
Languages : en
Pages : 15
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Book Description
This research concerns the study of the spectroscopy and excited state dynamics of a number of transient molecules containing either sulfur or oxygen. The identification and study of sulfur species which are analogs of important oxygen-containing combustion intermediates is important to our understanding of reactive intermediates. The oxygen-containing species chosen for study are new systems whose electronic spectra have not previously been identified. The major experimental technique used in this work was pyrolysis jet spectroscopy. Since many of the species have not been previously studied by laser techniques, much effort was devoted to determining methods for producing and observing them. We have been very successful in a number of cases and have developed some further experimental techniques.
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Category :
Languages : en
Pages : 5
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Work was done on sub-Doppler spectroscopy of thioformaldehyde, electronic spectrum of FS2 radical, FTIR spectra of the transient molecule formyl chloride (HCOCl and DCOCl), and high-resolution FTIR spectra of the?9 (CH2 wag) and?5 (CSO symm. stretch) bands of sulfine (H2CSO), a transient species formed in pyrolysis of dimethyl sulfoxide and oxidation of thioformaldehyde.
Author: Laszlo Nemes
Publisher: World Scientific
ISBN: 9812837647
Category : Science
Languages : en
Pages : 536
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This book is a stop-gap contribution to the science and technology of carbon plasmas and carbon vapors. It strives to cover two strongly related fields: the molecular quantum theory of carbon plasmas and carbon nanostructures; and the molecular and atomic spectroscopy of such plasmas and vapors. These two fields of research are strongly intertwined and thus reinforce one another.Even though the use of carbon nanostructures is increasing by the day and their practical uses are emerging, there is no modern review on carbon plasmas, especially from molecular theoretical and spectroscopic viewpoints. The importance of the present book is therefore great from both educational and practical aspects. This review might be the first step towards bringing such textbooks into existence for university education. Similarly, for applied and engineering works in carbon nanostructures, the book provides a theoretical salient point for technologists in the field.
Author: Robert Sethfield Smith
Publisher:
ISBN:
Category : Laser spectroscopy
Languages : en
Pages : 140
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Abstract.
Author: N. T. Hunt
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Category :
Languages : en
Pages :
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Category : Aeronautics
Languages : en
Pages : 836
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