Author: Jarosław Koperski
Publisher:
ISBN:
Category : Laser spectroscopy
Languages : en
Pages : 224

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Author: Jaroslaw Koperski
Publisher: Wiley-VCH
ISBN: 9783527403844
Category : Science
Languages : en
Pages : 237

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Author: Gary William Leach
Publisher:
ISBN:
Category :
Languages : en
Pages : 252

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Author: Jaroslaw Koperski
Publisher:
ISBN:
Category :
Languages : en
Pages : 150

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Author: Jaroslaw Koperski
Publisher:
ISBN:
Category :
Languages : en
Pages : 149

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 317

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The gas phase high resolution spectroscopic study of weakly bound clusters can provide the information necessary to develop an intermolecular potential energy surface. This surface can then be used to better understand condensed phases. In this work, a tunable far infrared laser spectrometer is used to study weakly bound dimers produced in the newly developed continuous planar supersonic jet expansion apparatus. The water dimer is an extensively studied hydrogen bonded dimer. It undergoes several tunneling motions which result in splittings and perturbations of the rovibrational energy levels. A review is presented of much of the experimental and theoretical work done on water dimer, including a description of the combined fit of all the high resolution spectroscopic results by Coudert and Hougen. Also included is a discussion of the measurement of the K = 1 lower --> K = 2 lower band performed using the tunable far infrared laser/planar jet apparatus. The preliminary results from the study of CH4{center dot}H2O will also be presented. CH4{center dot}H2O is unique in that unlike a strongly anisotropic complex, such as the water dimer, the monomer subunits are nearly free internal rotors. Seven bands are observed which have very similar band origins and rotational constants. Two energy level diagrams are proposed which are strongly influenced by earlier ArH2O studies. A brief qualitative discussion of the CH4{center dot}H2O binding energy compared to that of ArH2O is also included. 152 refs., 54 figs., 20 tabs.

Author:
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 558

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Author: Barry A. Swartz
Publisher:
ISBN:
Category :
Languages : en
Pages : 218

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Author: Martin Quack
Publisher: John Wiley & Sons
ISBN: 0470066539
Category : Science
Languages : en
Pages : 2236

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The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications

Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 1246

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