Author: H. L. PETERSEN
Publisher:
ISBN:
Category :
Languages : en
Pages : 1
Book Description
OXYGEN WAS PARTLY DISSOCIATED BY A MICROWAVE DISCHARGE IN STATIC EXPERIMENTS, AND THE ABSOLUTE CONCENTRATION OF ATOMS WAS DETERMINED WITH A Wrede gage. The rate of recombination was measured by observing the radiation emitted as a result of the reaction of O atoms with a trace of NO2. An upper limit of 2.5 x 10 to the 14th power cc sq./mole sq. sec was established for the rate constant at 350 K of the reaction O + O + O2 yields O2 + O2. Since this upper limit is 1/3 to 1/2 times the value found in shocktube experiments for the same rate constant at 3500 K, it is concluded that the rate constant increases slowly with temperature instead of varying as an inverse power of absolute temperature, as has conventionally been assumed. In the same experiments, the rate constant for the reaction O + O2 + O2 yields O3 + O2 was found to be 1.1 x 10 to the 14th power cc sq./mole sq. sec at 350 K, in excellent agreement with other recent determinations. Recombination was strongly catalyzed by OH radicals in accordance with the mechanism O + OH + O2 yields HO2 + O2 and O + HO2 yields OH + O2. The rates of these reactions are reported. (Author).
Kinetics of Recombination of Atomic Oxygen at Room Temperature
Author: H. L. PETERSEN
Publisher:
ISBN:
Category :
Languages : en
Pages : 1
Book Description
OXYGEN WAS PARTLY DISSOCIATED BY A MICROWAVE DISCHARGE IN STATIC EXPERIMENTS, AND THE ABSOLUTE CONCENTRATION OF ATOMS WAS DETERMINED WITH A Wrede gage. The rate of recombination was measured by observing the radiation emitted as a result of the reaction of O atoms with a trace of NO2. An upper limit of 2.5 x 10 to the 14th power cc sq./mole sq. sec was established for the rate constant at 350 K of the reaction O + O + O2 yields O2 + O2. Since this upper limit is 1/3 to 1/2 times the value found in shocktube experiments for the same rate constant at 3500 K, it is concluded that the rate constant increases slowly with temperature instead of varying as an inverse power of absolute temperature, as has conventionally been assumed. In the same experiments, the rate constant for the reaction O + O2 + O2 yields O3 + O2 was found to be 1.1 x 10 to the 14th power cc sq./mole sq. sec at 350 K, in excellent agreement with other recent determinations. Recombination was strongly catalyzed by OH radicals in accordance with the mechanism O + OH + O2 yields HO2 + O2 and O + HO2 yields OH + O2. The rates of these reactions are reported. (Author).
Publisher:
ISBN:
Category :
Languages : en
Pages : 1
Book Description
OXYGEN WAS PARTLY DISSOCIATED BY A MICROWAVE DISCHARGE IN STATIC EXPERIMENTS, AND THE ABSOLUTE CONCENTRATION OF ATOMS WAS DETERMINED WITH A Wrede gage. The rate of recombination was measured by observing the radiation emitted as a result of the reaction of O atoms with a trace of NO2. An upper limit of 2.5 x 10 to the 14th power cc sq./mole sq. sec was established for the rate constant at 350 K of the reaction O + O + O2 yields O2 + O2. Since this upper limit is 1/3 to 1/2 times the value found in shocktube experiments for the same rate constant at 3500 K, it is concluded that the rate constant increases slowly with temperature instead of varying as an inverse power of absolute temperature, as has conventionally been assumed. In the same experiments, the rate constant for the reaction O + O2 + O2 yields O3 + O2 was found to be 1.1 x 10 to the 14th power cc sq./mole sq. sec at 350 K, in excellent agreement with other recent determinations. Recombination was strongly catalyzed by OH radicals in accordance with the mechanism O + OH + O2 yields HO2 + O2 and O + HO2 yields OH + O2. The rates of these reactions are reported. (Author).
Recombination of Carbon Monoxide and Atomic Oxygen at High Temperatures
Author: Theodore A. Brabbs
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
Book Description
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
Book Description
A Theoretical Study of the Recombination Kinetics of Atomic Oxygen
Author: Sterge T. Demetriades
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 36
Book Description
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 36
Book Description
The Kinetics of Oxygen Dissociation in a Radio-frequency Discharge
Author: Kam Hong Kwong
Publisher:
ISBN:
Category :
Languages : en
Pages : 204
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 204
Book Description
Temperature Measurement of the Free Atmosphere Taking Into Account the Recombination of Atoms
Author: A. F. Chizhov
Publisher:
ISBN:
Category : Atmosphere, Upper
Languages : en
Pages : 26
Book Description
Publisher:
ISBN:
Category : Atmosphere, Upper
Languages : en
Pages : 26
Book Description
Atom Recombination on Surface
Author: Young Chai Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 340
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 340
Book Description
NASA Technical Report
Author:
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 1126
Book Description
Publisher:
ISBN:
Category : Aerodynamics
Languages : en
Pages : 1126
Book Description
A Theoretical and Experimental Investigation of the Chemical Kinetics of an Oxygen Microwave Discharge
Author: Mary Lynn Brake
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 432
Book Description
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 432
Book Description
A Compendium of Evaluated and Estimated Rate Coefficients
Author: David Garvin
Publisher:
ISBN:
Category : Activity coefficients
Languages : en
Pages : 340
Book Description
Publisher:
ISBN:
Category : Activity coefficients
Languages : en
Pages : 340
Book Description
U.S. Government Research Reports
Author:
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 298
Book Description
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 298
Book Description