Kinetics of Fast Reactions in the Gas Phase [microform] : Shock Tube Studies of the Hydrogen-oxygen, Deuterium-oxygen and Hydrogen-nitrous Oxide Systems PDF Download
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![Kinetics of Fast Reactions in the Gas Phase [microform] : Shock Tube Studies of the Hydrogen-oxygen, Deuterium-oxygen and Hydrogen-nitrous Oxide Systems PDF](https://books.google.com/books/content/images/frontcover/94reMgEACAAJ?fife=w150-h200)
Author: Sydney Charles Barton
Publisher: National Library of Canada
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 466
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Book Description
![Kinetics of Fast Reactions in the Gas Phase [microform] : Shock Tube Studies of the Hydrogen-oxygen, Deuterium-oxygen and Hydrogen-nitrous Oxide Systems PDF](https://books.google.com/books/content/images/frontcover/94reMgEACAAJ?fife=w80-h100)
Author: Sydney Charles Barton
Publisher: National Library of Canada
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 466
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Book Description
Author: Sydney Charles Barton
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 466
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Book Description
Author: B. Levitt
Publisher: Springer Science & Business Media
ISBN: 1468426850
Category : Science
Languages : en
Pages : 342
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Book Description
The chapters in this book are devoted to the elementary reactions of small molecules in the gas phase, with some emphasis on reactions important in combustion. The first three chapters cover experimental measurements made at high temperatures, mainly using shock waves and flames; the final chapter describes discharge flow methods near room temperature. The authors-all active in the fields they describe were asked to aim at a level intermediate between a textbook and a review, designed for readers not already familiar with this branch of chemical kinetics. We hope the book will prove especially useful to research workers in related subjects, to research students, and perhaps as source material for the preparation of lectures. The examples have been chosen to illustrate the theoretical basis of the topics rather than attempt a complete coverage. Professors Wagner and Troe describe the remarkable progress made in recent years in measuring dissociation rates for small molecules. Tests ofunimolecular reaction theories are usually made in the 'fall-off' region of pressure: the kinetics change from first order to second order as the pressure is reduced. For large molecules this region lies below atmospheric pressure and is relatively easily accessible. For molecules with four or less atoms, however, the fall-off region lies well above atmospheric pressure: it has been explored using the high pressure shock tube techniques developed by the authors.
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1776
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Book Description
Author: D. L. Baulch
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 588
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Book Description
Author:
Publisher:
ISBN:
Category : Canada
Languages : en
Pages : 1218
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Book Description
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1018
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Book Description
Author: Keith J. Laidler
Publisher: Elsevier
ISBN: 1483222411
Category : Science
Languages : en
Pages : 263
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Book Description
Reactions Kinetics: Volume I: Homogeneous Gas Reactions presents a general introduction to the subject of kinetics, including the basic laws of kinetics and the theoretical treatment of reaction rates. This four-chapter book deals mainly with homogeneous reactions in the gas phase. Chapter 1 presents the kinetic laws based on experimental results in terms of their simple concepts, with a special consideration of the way in which rates depend on concentration, while Chapter 2 deals with the interpretation of rates in terms of more fundamental theories. Chapter 3 covers the overall reactions that are believed to be elementary, such as the reaction between hydrogen and iodine, the reverse decomposition of hydrogen iodide, the corresponding reactions involving deuterium instead of hydrogen, and the dimerizations of butadiene and cyclopentadiene, as well as a few elementary termolecular reactions, all involving nitric oxide. This chapter also includes a general account of some of the elementary reactions that occur as steps in more complex mechanisms. Chapter 4 examines the reaction rates of numerous complex gas reactions. Undergraduate physical chemistry and chemical kinetics students, as well as advanced students in other fields, such as biology and physics, will find this book invaluable.
Author: Frank E. Belles
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 26
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Book Description
Author: V.N. Kondratiev
Publisher: Springer Science & Business Media
ISBN: 3642676081
Category : Science
Languages : en
Pages : 254
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Book Description
The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
