Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes

Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes PDF Author: Bin Md Yamin Bohari
Publisher:
ISBN:
Category : Alkenes
Languages : en
Pages : 434

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Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes

Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes PDF Author: Bin Md Yamin Bohari
Publisher:
ISBN:
Category : Alkenes
Languages : en
Pages : 434

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Mechanistic Studies on Some Oxidation Reactions of Palladium(II) Complexes

Mechanistic Studies on Some Oxidation Reactions of Palladium(II) Complexes PDF Author: Paul Lawrence Rispoli
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 466

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Palladium Catalyzed Oxidation of Hydrocarbons

Palladium Catalyzed Oxidation of Hydrocarbons PDF Author: P. Henry
Publisher: Springer Science & Business Media
ISBN: 940099446X
Category : Science
Languages : en
Pages : 449

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Book Description
The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.

Mechanistic Studies on the Reactions of Dienes and Palladium(II) Complexes

Mechanistic Studies on the Reactions of Dienes and Palladium(II) Complexes PDF Author: H. M. Asfour
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Catalytic Reactions

Catalytic Reactions PDF Author: Peter Maitlis
Publisher: Elsevier
ISBN: 0323159613
Category : Science
Languages : en
Pages : 233

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Book Description
The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.

Synthetic and Mechanistic Studies of Some Olefin Reactions with Palladium(II)

Synthetic and Mechanistic Studies of Some Olefin Reactions with Palladium(II) PDF Author: Norman Thomas Byrom
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Handbook of Palladium-Catalysed Organic Reactions

Handbook of Palladium-Catalysed Organic Reactions PDF Author: J. C. Fiaud
Publisher: Elsevier
ISBN: 0080533140
Category : Science
Languages : en
Pages : 319

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Book Description
This comprehensive handbook will be an indispensable research tool for chemists. Handbook of Palladium Catalysed Organic Reactions provides a synoptic description of the main types of reactions which are catalyzed by Palladium and the mechanism which causes these reactions. Each reaction is presented in graphical form and classified according to the type of transformation involved. Other books covering the use of Palladium complexes as catalysts have been written, but the Handbook is the only to offer a synoptic view, showing the catalytic cycle of each reaction. This complete coverage provides the reader with a good understanding of the parameters involved. The tables included can be viewed from the point of view of the reagents, the product of the reaction, or the mechanism involved. The Handbook is a companion to the Database of Palladium Chemistry: Reactions andCatalytic Cycles, published on CD-ROM. Begins with explicit instructions from the authors, facilitating use of the Handbook Details the associated catalytic cycle for each class of reactions Offers a choice of references, allowing the reader to find the closest example for solving a given problem 84 types of mechanism covered, plus over 2500 references Presents graphical abstracts for all reactions described, making it easy to search a type of reaction Comb-bound for easy reference Free demo disk included for the Database of Palladium Chemistry A versatile tool for chemists in the academic community, this handbook will be an invaluable tool in the laboratory

Understanding Organometallic Reaction Mechanisms and Catalysis

Understanding Organometallic Reaction Mechanisms and Catalysis PDF Author: Valentin P. Ananikov
Publisher: John Wiley & Sons
ISBN: 3527678220
Category : Science
Languages : en
Pages : 483

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Book Description
Exploring and highlighting the new horizons in the studies of reaction mechanisms that open joint application of experimental studies and theoretical calculations is the goal of this book. The latest insights and developments in the mechanistic studies of organometallic reactions and catalytic processes are presented and reviewed. The book adopts a unique approach, exemplifying how to use experiments, spectroscopy measurements, and computational methods to reveal reaction pathways and molecular structures of catalysts, rather than concentrating solely on one discipline. The result is a deeper understanding of the underlying reaction mechanism and correlation between molecular structure and reactivity. The contributions represent a wealth of first-hand information from renowned experts working in these disciplines, covering such topics as activation of small molecules, C-C and C-Heteroatom bonds formation, cross-coupling reactions, carbon dioxide converison, homogeneous and heterogeneous transition metal catalysis and metal-graphene systems. With the knowledge gained, the reader will be able to improve existing reaction protocols and rationally design more efficient catalysts or selective reactions. An indispensable source of information for synthetic, analytical, and theoretical chemists in academia and industry.

Kinetic Effects of Anionic Ligands in Some Reactions of Palladium (II) Complexes

Kinetic Effects of Anionic Ligands in Some Reactions of Palladium (II) Complexes PDF Author: L. Cattalini
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 3

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Handbook of Organopalladium Chemistry for Organic Synthesis

Handbook of Organopalladium Chemistry for Organic Synthesis PDF Author: Ei-ichi Negishi
Publisher: John Wiley & Sons
ISBN: 0471461555
Category : Science
Languages : en
Pages : 1697

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Book Description
Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.