Investigating Mass Transport Limitations on Xylan Hydrolysis During Dilute Acid Pretreatment of Poplar PDF Download
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Languages : en
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Mass transport limitations could be an impediment to achieving high sugar yields during biomass pretreatment and thus be a critical factor in the economics of biofuels production. The objective of this work was to study the mass transfer restrictions imposed by the structure of biomass on the hydrolysis of xylan during dilute acid pretreatment of biomass. Mass transfer effects were studied by pretreating poplar wood at particle sizes ranging from 10 micrometers to 10 mm. This work showed a significant reduction in the rate of xylan hydrolysis in poplar when compared to the intrinsic rate of hydrolysis for isolated xylan that is possible in the absence of mass transfer. In poplar samples we observed no significant difference in the rates of xylan hydrolysis over more than two orders of magnitude in particle size. It appears that no additional mass transport restrictions are introduced by increasing particle size from 10 micrometers to 10 mm. This work suggests that the rates of xylan hydrolysis in biomass particles are limited primarily by the diffusion of hydrolysis products out of plant cell walls. A mathematical description is presented to describe the kinetics of xylan hydrolysis that includes transport of the hydrolysis products through biomass into the bulk solution. The modeling results show that the effective diffusion coefficient of the hydrolysis products in the cell wall is several orders of magnitude smaller than typical values in other applications signifying the role of plant cell walls in offering resistance to diffusion of the hydrolysis products.
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Languages : en
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Book Description
Mass transport limitations could be an impediment to achieving high sugar yields during biomass pretreatment and thus be a critical factor in the economics of biofuels production. The objective of this work was to study the mass transfer restrictions imposed by the structure of biomass on the hydrolysis of xylan during dilute acid pretreatment of biomass. Mass transfer effects were studied by pretreating poplar wood at particle sizes ranging from 10 micrometers to 10 mm. This work showed a significant reduction in the rate of xylan hydrolysis in poplar when compared to the intrinsic rate of hydrolysis for isolated xylan that is possible in the absence of mass transfer. In poplar samples we observed no significant difference in the rates of xylan hydrolysis over more than two orders of magnitude in particle size. It appears that no additional mass transport restrictions are introduced by increasing particle size from 10 micrometers to 10 mm. This work suggests that the rates of xylan hydrolysis in biomass particles are limited primarily by the diffusion of hydrolysis products out of plant cell walls. A mathematical description is presented to describe the kinetics of xylan hydrolysis that includes transport of the hydrolysis products through biomass into the bulk solution. The modeling results show that the effective diffusion coefficient of the hydrolysis products in the cell wall is several orders of magnitude smaller than typical values in other applications signifying the role of plant cell walls in offering resistance to diffusion of the hydrolysis products.
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Languages : en
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Book Description
Mass transport limitations could be an impediment to achieving high sugar yields during biomass pretreatment and thus be a critical factor in the economics of biofuels production. The objective of this work was to study the mass transfer restrictions imposed by the structure of biomass on the hydrolysis of xylan during dilute acid pretreatment of biomass. Mass transfer effects were studied by pretreating poplar wood at particle sizes ranging from 10 micrometers to 10 mm. This work showed a significant reduction in the rate of xylan hydrolysis in poplar when compared to the intrinsic rate of hydrolysis for isolated xylan that is possible in the absence of mass transfer. In poplar samples we observed no significant difference in the rates of xylan hydrolysis over more than two orders of magnitude in particle size. It appears that no additional mass transport restrictions are introduced by increasing particle size from 10 micrometers to 10 mm. This work suggests that the rates of xylan hydrolysis in biomass particles are limited primarily by the diffusion of hydrolysis products out of plant cell walls. A mathematical description is presented to describe the kinetics of xylan hydrolysis that includes transport of the hydrolysis products through biomass into the bulk solution. The modeling results show that the effective diffusion coefficient of the hydrolysis products in the cell wall is several orders of magnitude smaller than typical values in other applications signifying the role of plant cell walls in offering resistance to diffusion of the hydrolysis products.
Author: Michael Himmel
Publisher: Wiley-Blackwell
ISBN:
Category : Science
Languages : en
Pages : 552
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Book Description
This book examines the connection between biomass structure, ultrastructure, and composition, to resistance to enzymatic deconstruction, with the aim of discovering new cost-effective technologies for biorefineries. It contains chapters on topics extending from the highest levels of biorefinery design and biomass life-cycle analysis, to detailed aspects of plant cell wall structure, chemical treatments, enzymatic hydrolysis, and product fermentation options."--Pub. desc.
Author: Jonathan R. Mielenz
Publisher: Humana Press
ISBN: 9781617796470
Category : Science
Languages : en
Pages : 294
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Book Description
This editor believes the public finally understands that bioenergy should be a critical new 39 component of our world’s future energy supply. While this new enlightenment might have 40 come from bioenergy’s environmentally friendly attributes and its renewable and sustain- 41 able nature, the reality is that the primary driver has been both the high cost of energy, 42 led recently by petroleum products, and the unique climatic changes such as local weather 43 events and reports of melting of ancient glaciers. I believe that much of the public under- 44 stands the primary cause of these changes is the growing demand for fossil fuels for heat- 45 ing and transportation needs driven by both population increases and dramatic economic 46 development around the globe. This increased demand, as well as global politics, has 47 impacted the costs for these energy products. At the same time, increased use of fossil fuels 48 has been liberating unprecedented levels of CO and other greenhouse gasses (GHGs) 49 2 that must be impacting the global climate. As a result, the world is looking for alternative 50 solutions. Renewable energy is one of the leading options as long as it is pursued in a sus- 51 tainable fashion. Of course, renewable energy has numerous sources, including wind, solar, 52 geothermal, ocean currents/tides, and bio-based energy. The latter category of renewable 53 energy is centered primarily on use of green plant matter, i. e.
Author: Jong Moon Park
Publisher: Springer
ISBN: 9789400763074
Category : Technology & Engineering
Languages : en
Pages : 0
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Book Description
This handbook provides a comprehensive overview of techniques applied in biorefinery. it covers the basic principles, upfront research accomplishments as well as successful industrial applications, including all necessary steps for the provision and preparation of the biomass and all possible downstream processing steps. The book is structured in a way that is appropriate for advanced graduate students and professionals in diverse scientific and engineering communities, including biocatalysis, chemical catalysis, metabolic engineering, bioprocess engineering as well as in various engineering disciplines.
Author: Charles Wyman
Publisher: Routledge
ISBN: 1351441760
Category : Technology & Engineering
Languages : en
Pages : 289
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Book Description
Bioethanol is a versatile transportation fuel and fuel additive that offers excellent performance and reduced air pollution compared to conventional fuels. Its production and use adds little, if any, net release of carbon dioxide to the atmosphere, dramatically reducing the potential for global climate change. Through a sustained research program and an emerging economic competitiveness, the technology for bioethanol production is poised for immediate widespread commercial applications. Written by engineers and scientists providing a technical focus, this handbook provides the up-to-date information needed by managers, engineers, and scientists to evaluate the technology, market, and economics of this fuel, while examining the development of production required to support its commercial use.
Author: Anuj Chandel
Publisher: BoD – Books on Demand
ISBN: 9535111191
Category : Technology & Engineering
Languages : en
Pages : 288
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Book Description
This book provides important aspects of sustainable degradation of lignocellulosic biomass which has a pivotal role for the economic production of several value-added products and biofuels with safe environment. Different pretreatment techniques and enzymatic hydrolysis process along with the characterization of cell wall components have been discussed broadly. The following features of this book attribute its distinctiveness: This book comprehensively covers the improvement in methodologies for the biomass pretreatment, hemicellulose and cellulose breakdown into fermentable sugars, the analytical methods for biomass characterization, and bioconversion of cellulosics into biofuels. In addition, mechanistic analysis of biomass pretreatment and enzymatic hydrolysis have been discussed in details, highlighting key factors influencing these processes at industrial scale.
Author: Eero Sjostrom
Publisher: Elsevier
ISBN: 0080925898
Category : Technology & Engineering
Languages : en
Pages : 311
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Book Description
Wood Chemistry, Fundamentals and Applications, Second Edition, examines the basic principles of wood chemistry and its potential applications to pulping and papermaking, wood and wood waste utilization, pulping by-products for production of chemicals and energy, and biomass conversion.
Author: Ashok Pandey
Publisher: Academic Press
ISBN: 0128003960
Category : Technology & Engineering
Languages : en
Pages : 273
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Book Description
Pretreatment of Biomass provides general information, basic data, and knowledge on one of the most promising renewable energy sources—biomass for their pretreatment—which is one of the most essential and critical aspects of biomass-based processes development. The quest to make the environment greener, less polluted, and less hazardous has led to the concept of biorefineries for developing bio-based processes and products using biomass as a feedstock. Each kind of biomass requires some kind of pretreatment to make it suitable for bioprocess. This book provides state-of-art information on the methods currently available for this. This book provides data-based scientific information on the most advanced and innovative pretreatment of lignocellulosic and algal biomass for further processing. Pretreatment of biomass is considered one of the most expensive steps in the overall processing in a biomass-to-biofuel program. With the strong advancement in developing lignocellulose biomass- and algal biomass-based biorefineries, global focus has been on developing pretreatment methods and technologies that are technically and economically feasible. This book provides a comprehensive overview of the latest developments in methods used for the pretreatment of biomass. An entire section is devoted to the methods and technologies of algal biomass due to the increasing global attention of its use. - Provides information on the most advanced and innovative pretreatament processes and technologies for biomass - Covers information on lignocellulosic and algal biomass to work on the principles of biorefinery - Useful for researchers intending to study scale-up - Provides information on integration of processes and technologies for the pretreatment of biomass
Author: Keith W. Waldron
Publisher: Elsevier
ISBN: 1845699610
Category : Technology & Engineering
Languages : en
Pages : 497
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Book Description
Bioethanol is one of the main biofuels currently used as a petroleum-substitute in transport applications. However, conflicts over food supply and land use have made its production and utilisation a controversial topic. Second generation bioalcohol production technology, based on (bio)chemical conversion of non-food lignocellulose, offers potential advantages over existing, energy-intensive bioethanol production processes. Food vs. fuel pressures may be reduced by utilising a wider range of lignocellulosic biomass feedstocks, including energy crops, cellulosic residues, and, particularly, wastes.Bioalcohol production covers the process engineering, technology, modelling and integration of the entire production chain for second generation bioalcohol production from lignocellulosic biomass. Primarily reviewing bioethanol production, the book's coverage extends to the production of longer-chain bioalcohols which will be elemental to the future of the industry.Part one reviews the key features and processes involved in the pretreatment and fractionation of lignocellulosic biomass for bioalcohol production, including hydrothermal and thermochemical pretreatment, and fractionation to separate out valuable process feedstocks. Part two covers the hydrolysis (saccharification) processes applicable to pretreated feedstocks. This includes both acid and enzymatic approaches and also importantly covers the development of particular enzymes to improve this conversion step. This coverage is extended in Part three, with chapters reviewing integrated hydrolysis and fermentation processes, and fermentation and co-fermentation challenges of lignocellulose-derived sugars, as well as separation and purification processes for bioalcohol extraction.Part four examines the analysis, monitoring and modelling approaches relating to process and quality control in the pretreatment, hydrolysis and fermentation steps of lignocellulose-to-bioalcohol production. Finally, Part five discusses the life-cycle assessment of lignocellulose-to-bioalcohol production, as well as the production of valuable chemicals and longer-chain alcohols from lignocellulosic biomass.With its distinguished international team of contributors, Bioalcohol production is a standard reference for fuel engineers, industrial chemists and biochemists, plant scientists and researchers in this area. - Provides an overview of the life-cycle assessment of lignocelluloses-to-bioalcohol production - Reviews the key features and processes involved in the pre-treatment and fractionation of lignocellulosic biomass for bioalcohol production - Examines the analysis, monitoring and modelling approaches relating to process and quality control in pre-treatment, hydrolysis and fermentation
