Inorganic Chemistry, Series One: Main group elements; group VII and noble gases, edited by V. Gutmann PDF Download
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Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 312
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Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 312
Get Book Here
Book Description
Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 416
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Book Description
Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 360
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ISBN:
Category : American literature
Languages : en
Pages : 650
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Author: B. J. Aylett
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
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A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 376
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Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 392
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Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 336
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Author:
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 416
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Book Description
Author:
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 418
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