Influence of Zirconium Alloy Chemical Composition on Microstructure Formation and Irradiation Induced Growth PDF Download
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Author: AV. Tselischev
Publisher:
ISBN:
Category : Composition
Languages : en
Pages : 22
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Book Description
The studies of the dislocation structure, phase, and microchemical compositions of alloy Zr-1Nb-1.2Sn-0.35Fe (E635) and its modifications containing Fe from 0.15 to 0.65% were carried out before and after research reactor irradiation at ~350°C to maximal fluence of ~1027 m-2 (E > 0.1 MeV) and at ~60°C. The size and concentration of the a-type loops depend on the alloy composition and fluence and saturate even at low doses (1 dpa). The evolution of the c-component dislocation structure in recrystallized alloys of E365 type is determined by the chemical and phase compositions of alloys specifically, by the Fe/Nb ratio and the threshold dose, and is consistent with the irradiation growth strain acceleration. In E635 alloy containing 0.15%Fe the accelerated growth is observed after the dose of 15 dpa and is attended with the evolution of the c dislocation structure which is similar to Zr-1Nb (E110) alloy behavior. The irradiation induced growth of E635 type alloy containing 0.65% Fe is similar to that of E635 having the normal composition; no
Author: AV. Tselischev
Publisher:
ISBN:
Category : Composition
Languages : en
Pages : 22
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Book Description
The studies of the dislocation structure, phase, and microchemical compositions of alloy Zr-1Nb-1.2Sn-0.35Fe (E635) and its modifications containing Fe from 0.15 to 0.65% were carried out before and after research reactor irradiation at ~350°C to maximal fluence of ~1027 m-2 (E > 0.1 MeV) and at ~60°C. The size and concentration of the a-type loops depend on the alloy composition and fluence and saturate even at low doses (1 dpa). The evolution of the c-component dislocation structure in recrystallized alloys of E365 type is determined by the chemical and phase compositions of alloys specifically, by the Fe/Nb ratio and the threshold dose, and is consistent with the irradiation growth strain acceleration. In E635 alloy containing 0.15%Fe the accelerated growth is observed after the dose of 15 dpa and is attended with the evolution of the c dislocation structure which is similar to Zr-1Nb (E110) alloy behavior. The irradiation induced growth of E635 type alloy containing 0.65% Fe is similar to that of E635 having the normal composition; no
Author: Gerry D. Moan
Publisher: ASTM International
ISBN: 0803128959
Category : Nuclear fuel claddings
Languages : en
Pages : 891
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Book Description
Annotation The 41 papers of this proceedings volume were first presented at the 13th symposium on Zirconium in the Nuclear Industry held in Annecy, France in June of 2001. Many of the papers are devoted to material related issues, corrosion and hydriding behavior, in-reactor studies, and the behavior and properties of Zr alloys used in storing spent fuel. Some papers report on studies of second phase particles, irradiation creep and growth, and material performance during loss of coolant and reactivity initiated accidents. Annotation copyrighted by Book News, Inc., Portland, OR.
Author: Daniel Charquet
Publisher:
ISBN: 9780803170186
Category : Alloys
Languages : en
Pages : 14
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Book Description
In order to optimize zirconium-based alloys, it is usually necessary to understand the relationships and interaction between four different types of parameters: chemical composition, manufacturing process, metallurgical characteristics, and functional properties Examples for various materials show that corrosion resistance depends on the texture and density, distribution, and composition of the precipitate particles. The precipitate composition is determined not only by the alloy chemistry, but also by other factors, such as the cooling rate from the beta phase range. It is also pointed out that some parameters can have opposite effets on nodular and uniform corrosion. Finally, the effects of some impurity elements are described, especially the effect of sulfur on creep and of chlorine on microstructure. The original paper was published by ASTM International in STP 1354, Zirconium in the Nuclear Industry: Twelfth International Symposium, 2000, pp. 314.
Author: George P. Sabol
Publisher: ASTM International
ISBN: 0803124066
Category : Nuclear fuel claddings
Languages : en
Pages : 907
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Book Description
Author: VN. Shishov
Publisher:
ISBN:
Category : Damage dose
Languages : en
Pages : 14
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Book Description
The irradiation-induced damage of zirconium alloys subjected to neutron irradiation up to dose levels of ~50 dpa was investigated. Specimens of unalloyed zirconium, Zr-1%Nb, Zr-2.5%Nb and Zr-1%Nb-1.3%Sn-0.4%Fe were irradiated in the BOR-60 reactor over the temperature range 320-420°C. The dose dependence of the irradiation growth strain increased sharply in zirconium and Zr-Nb irradiated at ~350°C at doses above ~10 dpa. In the case of Zr-1%Nb-1.3%Sn-0.4%Fe, it increased at doses of ~37 dpa. Upon increasing the irradiation temperature to 420°C, a sharp accelerated irradiation growth of the Zr-1%Nb alloy began shifting up to about 30 dpa. For the Zr- 1%Nb-1.3%Sn-0.4%Fe, no change of the irradiation growth rate was observed up to a dose of 55 dpa. The onset of increased irradiation growth in alloys correlates with the occurrence of c-component dislocation loops which coincides with a loss of coherence of finely-dispersed precipitates. Post-irradiation annealing experiments demonstrated that a delay in loop formation leads to displacement of the "break-away" beginning in the dose dependence of the irradiation growth in the direction of high doses. The a+c-type dislocation loops were also formed in Zr-1%Nb alloy at high doses, but their influence on the change of macroscopic properties was not observed.
Author: D. Charquet
Publisher:
ISBN:
Category : Alloys
Languages : en
Pages : 12
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Book Description
In order to optimize zirconium-based alloys, it is usually necessary to understand the relationships and interactions between four different types of parameters: chemical composition, manufacturing process, metallurgical characteristics, and functional properties. Examples for various materials show that corrosion resistance depends on the texture and density, distribution, and composition of the precipitate particles. The precipitate composition is determined not only by the alloy chemistry, but also by other factors, such as the cooling rate from the beta phase range. It is also pointed out that some parameters can have opposite effects on nodular and uniform corrosion. Finally, the effects of some impurity elements are described, especially the effect of sulfur on creep and of chlorine on microstructure.
Author: Cyril A. Migdal
Publisher: ASTM International
ISBN: 0803134932
Category : Antioxidants
Languages : en
Pages : 929
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Book Description
This work presents papers from a December 2005 symposium held in Norfolk, Virginia, and sponsored by ASTM Committee D2 on Petroleum Products and Lubricants and its Subcommittees D02.09 on Oxidation and D02.C0 on Turbine Oils. Contributors include equipment manufacturers, end users, lubricant producers, lubricant additive suppliers, test equipment manufacturers, and standard test method developers. They share information on industry trends, evolving technologies, and changing equipment designs and operating conditions, with a focus on how these factors impact oxidation. Some topics covered include turbine oil performance limits, a new form of the rotating pressure vessel oxidation test, and degradation mechanisms leading to sludge and varnish in modern turbine oil formulations. B&w photos are included. There is no subject index. Migdal is affiliated with Chemtura Corporation.
Author: D. W. White
Publisher:
ISBN:
Category : Irradiation-induced growth
Languages : en
Pages : 19
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Book Description
This paper is devoted to the study of the effect of the texture, phase composition, and microstructure on the irradiation-induced growth strain (GS) of zirconium-based alloys. GS measurements and TEM microstructural examinations were performed on Zry-2, NSF, and E635 samples in the recrystallized, beta quenched and cold-worked (CW) conditions. The samples were irradiated in the BOR-60 reactor in the temperature range of 315-325°C up to a neutron fluence level of 1.1 x 1026 n/m2 (E>1MeV), i.e., up to a damage dose of 23 dpa. Growth strains of NSF and E635 alloys in all states and in the longitudinal and transverse directions are lower as compared to those of Zry-2, and do not exceed 0.2 % even at the maximum fluence level. As for recrystallized Zry-2, the GS kinetics are characterized by the appearance of the accelerated growth stage. A combination of a certain amount of Nb, Fe, and Sn in the matrix content plays a key role in GS kinetics. The higher the degree of CW, the higher the irradiation growth but its rate of increase with increasing fluence is different for alloys of different compositions. The maximum GS, reaching 0.72 %, is observed in the 20 % CW Zry-2 samples. Texture, along with the alloy composition, is one of the main GS-determining factors. Irradiation growth of the transversal samples is lower as compared to the longitudinal ones because of texture. As for quenched alloys, the texture is practically isotropic and GS values are low, independent of the alloy composition. In CW materials, the density of ‹c›- dislocations greatly affects the irradiation growth strain. Particles of Zr(Fe,Cr)2 and Zr2(Fe,Ni) phases in Zry-2 as well as Zr(Nb,Fe)2 in NSF and E635 are depleted in iron under irradiation. The Fe goes into the matrix and modifies its properties. The HCP lattice structure in the Laves phases in NSF and E635 changes into BCC (?-Nb-type). FCC (Zr,Nb)2Fe precipitates preserve on the whole their composition and structure; no amorphization of the Nb-containing precipitates is observed. The Zr2(Fe,Ni) precipitates with a BCT lattice remain crystalline, and HCP Zr(Cr,Fe)2 precipitates undergo amorphization. The average particle size in the irradiated alloys is larger and the concentration is a little lower as compared to the unirradiated ones. Irradiation-induced fine dispersed precipitates about 3 nm in size, probably enriched in niobium, appear in NSF and E635. The observed changes of microhardness are discussed from the viewpoint of generation of radiation defects (clusters, dislocation loops), evolution of the initial dislocation structure, and matrix composition (enrichment in Fe, Cr, and, probably, Nb).
Author: K L Murty
Publisher: Elsevier
ISBN: 0857097458
Category : Technology & Engineering
Languages : en
Pages : 441
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Book Description
Light water reactors (LWRs) are the predominant class of nuclear power reactors in operation today; however, ageing and degradation can influence both their performance and lifetime. Knowledge of these factors is therefore critical to safe, continuous operation. Materials ageing and degradation in light water reactors provides a comprehensive guide to prevalent deterioration mechanisms, and the approaches used to handle their effects.Part one introduces fundamental ageing issues and degradation mechanisms. Beginning with an overview of ageing and degradation issues in LWRs, the book goes on to discuss corrosion in pressurized water reactors and creep deformation of materials in LWRs. Part two then considers materials’ ageing and degradation in specific LWR components. Applications of zirconium alloys in LWRs are discussed, along with the ageing of electric cables. Materials management strategies for LWRs are then the focus of part three. Materials management strategies for pressurized water reactors and VVER reactors are considered before the book concludes with a discussion of materials-related problems faced by LWR operators and corresponding research needs.With its distinguished editor and international team of expert contributors, Materials ageing and degradation in light water reactors is an authoritative review for anyone requiring an understanding of the performance and durability of this type of nuclear power plant, including plant operators and managers, nuclear metallurgists, governmental and regulatory safety bodies, and researchers, scientists and academics working in this area. Introduces the fundamental ageing issues and degradation mechanisms associated with this class of nuclear power reactors Considers materials ageing and degradation in specific light water reactor components, including properties, performance and inspection Chapters also focus on material management strategies
Author: Craig M. Eucken
Publisher: ASTM International
ISBN: 080311463X
Category : Nuclear fuel claddings
Languages : en
Pages : 794
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Book Description
The proceedings of the Ninth International Symposium on [title], held in Kobe, Japan, November 1990, address current trends in the development, performance, and fabrication of zirconium alloys for nuclear power reactors. the bulk of the most recent work on zirconium alloy behavior has concerned corr
