Heterocycles from Carbenes and Nitrenes

Heterocycles from Carbenes and Nitrenes PDF Author: Michael P. Doyle
Publisher: Springer Nature
ISBN: 3031367359
Category : Science
Languages : en
Pages : 381

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Book Description
This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.

Heterocycles from Carbenes and Nitrenes

Heterocycles from Carbenes and Nitrenes PDF Author: Michael P. Doyle
Publisher: Springer Nature
ISBN: 3031367359
Category : Science
Languages : en
Pages : 381

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Book Description
This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.

Organic Reaction Mechanisms 2016

Organic Reaction Mechanisms 2016 PDF Author: A. C. Knipe
Publisher:
ISBN: 9781119288657
Category : Organic reaction mechanisms
Languages : en
Pages : 872

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Book Description
Organic Reaction Mechanisms 2016, the 52nd annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2016. The following classes of organic reaction mechanisms are comprehensively reviewed: * Reaction of Aldehydes and Ketones and their Derivatives * Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives * Oxidation and Reduction * Carbenes and Nitrenes * Nucleophilic Aromatic Substitution * Electrophilic Aromatic Substitution * Carbocations * Nucleophilic Aliphatic Substitution * Carbanions and Electrophilic Aliphatic Substitution * Elimination Reactions * Polar Addition Reactions * Cycloaddition Reactions * Molecular Rearrangements

Synthesis of Divergent N-heterocycles Enabled by Nitrene Or Gold Carbene Intermediates

Synthesis of Divergent N-heterocycles Enabled by Nitrene Or Gold Carbene Intermediates PDF Author: Lina Song
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description


Carbenes, Nitrenes and Arynes

Carbenes, Nitrenes and Arynes PDF Author: Thomas Lonsdale Gilchrist
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 144

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Book Description


N-Heterocyclic Carbenes

N-Heterocyclic Carbenes PDF Author: Silvia Diez-Gonzalez
Publisher: Royal Society of Chemistry
ISBN: 1782626816
Category : Science
Languages : en
Pages : 637

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Book Description
In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

S-Heterocycles

S-Heterocycles PDF Author: Shrikaant Kulkarni
Publisher:
ISBN: 9781837674015
Category : Medical
Languages : en
Pages : 0

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Book Description
This edited volume reports the latest developments in practical and selective reactions and methods involving carbenes and nitrenes and provides details of the structural diversity of heterocycles.

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry PDF Author:
Publisher: Academic Press
ISBN: 008057615X
Category : Science
Languages : en
Pages : 379

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Book Description
Advances in Heterocyclic Chemistry

Handbook of Heterocyclic Chemistry

Handbook of Heterocyclic Chemistry PDF Author: Alan R. Katritzky
Publisher: Elsevier
ISBN: 1483293424
Category : Science
Languages : en
Pages : 568

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Book Description
Provides a one-volume overall picture of the largest of the classical divisions of organic chemistry, suitable for the graduate or advanced undergraduate student, as well as for research workers, both specialists in the field and those engaged in another discipline and requiring knowledge of heterocyclic chemistry. It represents Volume 9 of Comprehensive Heterocyclic Chemistry and utilizes the general chapters which appear in the 8-volume work. The highly systematic coverage given to the subject makes this the most authoritative one-volume account of modern heterocyclic chemistry available.

Heterocyclic Chemistry

Heterocyclic Chemistry PDF Author: Radha R. Gupta
Publisher: Springer Science & Business Media
ISBN: 3642722768
Category : Science
Languages : en
Pages : 431

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Book Description
Today, our world increasingly is conceived of as being molecular. An ever widening range of phenomena are described logically in terms of molecular properties and molecular interactions. The majority of known molecules are heterocyclic and heterocycles dominate the fields of biochemistry, medicinal chemistry, dyestuffs, photographic science and are of increasing importance in many others, including polymers, adhesives, and molecular engineering. Thus, the importance of heterocyclic chemistry continues to increase and this three volume work by Drs. R. R. Gupta, Mahendra Kumar and Vandana Gupta is a welcome addition to the available guides on the subject. Its scope places it in a useful niche between the single-volume texts and monographs of heterocyclic chemistry and the multivolume treatises. The authors have retained the well tried classical approach but have succeeded in placing their own individual spin on their arrangement. They have put together a well selected range from among the most important of the vast array offacts available. This factual material is ordered in a clear and logical fashion over the three volumes. The present work should be of great value to students-and practitioners of heterocyclic chemistry at all levels from the advanced undergraduate upwards. It will be of particular assistance in presenting a clear and modem view of the subject to those who use heterocycles in a variety of other fields and we wish it well.

Pericyclic Reactions

Pericyclic Reactions PDF Author: Alan P. Marchand
Publisher: Academic Press
ISBN: 1483218643
Category : Science
Languages : en
Pages : 301

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Book Description
Pericyclic Reactions, Volume 1 covers the theoretical approaches to pericyclic reactions and pericyclic reactions of reactive intermediates and of particular reaction types. The book discusses the operational criteria for evaluation of concertedness in potential pericyclic reactions; and the Mobius-Hückel treatment of organic systems and reactions and molecular orbital following as a technique in organic chemistry. The text also describes some pericyclic reactions of carbenes and carbanions. Physicists and people involved in the study of pericyclic reactions will find the book invaluable.