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Author:
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ISBN:
Category :
Languages : en
Pages : 1157
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Author: R.Sarkar
Publisher: New Central Book Agency
ISBN: 9788173811364
Category :
Languages : en
Pages : 528
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Book Description
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
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Publisher:
ISBN:
Category :
Languages : en
Pages : 1157
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Book Description
Author: T.A. Ryan
Publisher: Elsevier
ISBN: 0080538800
Category : Science
Languages : en
Pages : 979
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Book Description
Phosgene, COCl2 is a C1 chemical of major industrial importance. The annual production, worldwide, is more than 1 million tons; 90% of which is used in the manufacture of isocyanates and of polyurethane and polycarbonate resins. Phosgene is also extensively used as a synthetic reagent in organic chemistry, in particular in the preparation of acyl chlorides, chloroformate esters, organic carbonates and carbamoyl chlorides.Although more than 7000 papers have appeared on phosgene and some 1000 papers on its analogues, this is the first book on these interesting chemicals. It presents a critical treatise of phosgene, ranging from its discovery and subsequent use as a war gas to some potential applications of the material into the 21st century. It includes chapters on biological effects and industrial hygiene; on synthesis, formation and manufacture; analysis, uses, environmental effects, and physical and thermodynamic properties. Reactions with organic and inorganic materials are described. Four of the seventeen chapters are devoted to a description of the carbonyl halides (especially carbonyl difluoride) related to phosgene, and a special section deals collectively with the electronic structures of carbonyl halide molecules.Featuring the first-ever comprehensive discussion of the medical effects of phosgene poisoning and the most modern methods of treating exposure victims, the book will be of interest to historians and militarists and those working in the chemical industries (heavy chemicals, agricultural and pharmaceutical), university libraries, hospitals, medical research centres, museums, environmental research centres, poison units and health and safety institutions world-wide.
Author: Jack Barrett
Publisher: Royal Society of Chemistry
ISBN: 9780854044719
Category : Education
Languages : en
Pages : 196
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Book Description
Inorganic Chemistry in Aqueous Solution reviews the chemistry of the elements in all their oxidation states in an aqueous environment. The nature of ions in solution is described in some detail and enthalpies and entropies of hydration of many ions are defined and recalculated from the best data available. These values are used to provide an understanding of the periodicities of standard reduction potentials. Standard reduction potential data for all of the elements, group-by-group, covering the s and p, d and f blocks of the Periodic Table is also included. Major sections are devoted to the acid/base behaviour and the solubilities of inorganic compounds in water. Inorganic Chemistry in Aqueous Solution is aimed at undergraduate chemistry students but will also be welcomed by geologists interested in this field. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.
Author: F. Albert Cotton
Publisher: John Wiley & Sons
ISBN: 0470166525
Category : Science
Languages : en
Pages : 578
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Book Description
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
Author: Katja A. Strohfeldt
Publisher: John Wiley & Sons
ISBN: 0470665580
Category : Science
Languages : en
Pages : 290
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Book Description
A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics of inorganic chemistry, including organometallic chemistry and radiochemistry, from a pharmaceutical perspective. Written for students of pharmacy and pharmacology, pharmaceutical sciences, medicinal chemistry and other health-care related subjects, this accessible text introduces chemical principles with relevant pharmaceutical examples rather than as stand-alone concepts, allowing students to see the relevance of this subject for their future professions. It includes exercises and case studies.
Author: Gary Wulfsberg
Publisher: University Science Books
ISBN: 9781891389955
Category : Science
Languages : en
Pages : 0
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Book Description
Foundations of Inorganic Chemistry by Gary Wulfsberg is our newest entry into the field of Inorganic Chemistry textbooks, designed uniquely for a one-semester stand alone course, or to be used in the first semester of a full year inorganic sequence. By covering virtually every topic in the test from the 2016 ACS Exams Institute, this book will prepare your students for success. The new book combines careful pedagogy, clear writing, beautifully rendered two-color art, and solved examples, with a broad array of original, chapter-ending exercises. It assumes a background in General Chemistry, but reviews key concepts, and also assumes enrollment in a Foundations of Organic Chemistry course. Symmetry and molecular orbital theory are introduced after the student has developed an understanding of fundamental trends in chemical properties and reactions across the periodic table, which allows MO theory to be more broadly applied in subsequent chapters. Key Features include: Over 900 end-of-chapter exercises, half answered in the back of the book.Over 180 worked examples.Optional experiments & demos.Clearly cited connections to other areas in chemistry and chemical sciencesChapter-opening biographical vignettes of noted scientists in Inorganic Chemistry.Optional General Chemistry review sections.
Author: Mayce Cannon Sneed
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 688
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Book Description
Author: Steven Michael Owen
Publisher: Longman Publishing Group
ISBN: 9780582064393
Category : Science
Languages : en
Pages : 340
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Book Description
This work acts as a guide to modern inorganic chemistry. The topics covered include main group and transition metal clusters, transition metal organometallic chemistry and electrical conduction in the solid state.
