Reversible excited-state electron-transfer reactions of transition metal complexes

Reversible excited-state electron-transfer reactions of transition metal complexes PDF Author: B. A. De Graff
Publisher:
ISBN:
Category :
Languages : en
Pages : 14

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Reversible excited-state electron-transfer reactions of transition metal complexes

Reversible excited-state electron-transfer reactions of transition metal complexes PDF Author: B. A. De Graff
Publisher:
ISBN:
Category :
Languages : en
Pages : 14

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Excited-state Electron-transfer Reactions of Transition Metal Complexes

Excited-state Electron-transfer Reactions of Transition Metal Complexes PDF Author: David Gordon Taylor
Publisher:
ISBN:
Category : Excited state chemistry
Languages : en
Pages : 232

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Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media

Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media PDF Author: Russell Hunter Schmehl
Publisher:
ISBN:
Category : Charge transfer
Languages : en
Pages : 446

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Collisionless Photoinduced Electron Transfer Reactions Involving Excited State Transition Metal Complexes

Collisionless Photoinduced Electron Transfer Reactions Involving Excited State Transition Metal Complexes PDF Author: Mark Edward McGuire
Publisher:
ISBN:
Category :
Languages : en
Pages : 406

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Mechanisms of Photochemical Reactions of Transition Metal Complexes: Excited State Electron Transfer and Organometallic Photochemistry

Mechanisms of Photochemical Reactions of Transition Metal Complexes: Excited State Electron Transfer and Organometallic Photochemistry PDF Author: M. S. Wrighton
Publisher:
ISBN:
Category :
Languages : en
Pages : 13

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This article summarizes two major areas of research, electron transfer and organometallic photochemistry, addressed during the last dozen or so years. The article emphasizes aspects of the mechanisms of photochemical reactions of transition metal complexes in these two areas. Excited state electron transfer and photoreactions of organometallic complexes have been, and will be, major areas of research opportunity. Practical applications may come in the fields of energy conversion and catalysis. (Author).

Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions

Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5

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Progress on 6 projects is reported: excited state absorption spectrum of Ru(bpy)[sub 3][sup 2+], solvent cage model for electron transfer quenching, reductive quenching of [sup *]Cr(III) complexes, solution medium effects in oxidative quenching of [sup *]Ru(II) complexes, photosensitized oxidation of phenol in aqueous solution, and quenching of Ru(II) complexes by oxygen.

Excited-state Properties of Transition-metal Complexes in Solution and the Solid State

Excited-state Properties of Transition-metal Complexes in Solution and the Solid State PDF Author: Mark David Newsham
Publisher:
ISBN:
Category : Excited state chemistry
Languages : en
Pages : 540

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Photochemistry and Photophysics of Metal Complexes

Photochemistry and Photophysics of Metal Complexes PDF Author: D.M. Roundhill
Publisher: Springer Science & Business Media
ISBN: 1489914951
Category : Science
Languages : en
Pages : 364

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Book Description
Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.

Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions. Progress Report, January 1, 1992--March 31, 1993

Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions. Progress Report, January 1, 1992--March 31, 1993 PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5

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Book Description
Progress on 6 projects is reported: excited state absorption spectrum of Ru(bpy)3{sup 2+}, solvent cage model for electron transfer quenching, reductive quenching of {sup *}Cr(III) complexes, solution medium effects in oxidative quenching of {sup *}Ru(II) complexes, photosensitized oxidation of phenol in aqueous solution, and quenching of Ru(II) complexes by oxygen.

Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Final Report, August 4, 1986--August 31, 1997

Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Final Report, August 4, 1986--August 31, 1997 PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 31

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The techniques of continuous photolysis and pulsed laser flash photolysis, continuous and pulse radiolysis, fast-scan cyclic voltammetry, and time-resolved fluorimetry have been used to examine intramolecular electron transfer within the solvent quenching cage, photodynamics of quenching of the excited states of transition-metal photosensitizers, the properties of excites states and one-electron reduced forms, ground- and excited-state interactions with solutes, and photoinduced oxidations of organic solutes in aqueous solution. The following specific areas were examined: (1) the parameters that govern the yields of redox products from excited-state electron-transfer quenching reactions; (2) the mediation of the properties of excited states and one-electron reduced forms by the ligands and the solution medium; (3) the effect of the interactions between the ground state of the complex and the solution components on the behavior of the excited state; (4) the yields of singlet oxygen from excited-state energy-transfer quenching by O2; and (5) the oxidations of solutes by singlet oxygen, excited-state electron-transfer quenching, and free radicals. This report contains the abstracts of 50 publications describing the studies.