EPRI-DOE-EPA Combined Utility Air Pollutant Control Symposium PDF Download
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Author:
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 632
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Book Description
Author:
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 632
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Book Description
Author:
Publisher: DIANE Publishing
ISBN: 1428904611
Category :
Languages : en
Pages : 139
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Book Description
Author:
Publisher: DIANE Publishing
ISBN: 1428902805
Category :
Languages : en
Pages : 57
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Book Description
Author: Karl B. Schnelle Jr.
Publisher: CRC Press
ISBN: 1482245620
Category : Nature
Languages : en
Pages : 446
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Book Description
A detailed reference for the practicing engineer, Air Pollution Control Technology Handbook, Second Edition focuses on air pollution control systems and outlines the basic process engineering and cost estimation required for its design. Written by seasoned experts in the field, this book offers a fundamental understanding of the factors resulting i
Author:
Publisher: DIANE Publishing
ISBN: 1428953868
Category :
Languages : en
Pages : 207
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Book Description
Author:
Publisher: DIANE Publishing
ISBN: 1428903720
Category :
Languages : en
Pages : 1811
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Book Description
Author: Erdem Sasmaz
Publisher: Stanford University
ISBN:
Category :
Languages : en
Pages : 195
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Book Description
Coal-fired power plants are a major anthropogenic source of worldwide mercury (Hg) emissions. Since mercury is considered to be one of the most toxic metals found in the environment, Hg emissions from coal-fired power plants is of major environmental concern. Mercury in coal is vaporized into its gaseous elemental form throughout the coal combustion process. Elemental Hg can be oxidized in subsequent reactions with other gaseous components (homogeneous) and solid materials (heterogeneous) in coal-fired flue gases. While oxidized Hg in coal-fired flue gases is readily controlled by its adsorption onto fly ash and/or its dissolution into existing solution-based sulfur dioxide (SO2) scrubbers, elemental Hg is not controlled. The extent of elemental Hg formed during coal combustion is difficult to predict since it is dependent on the type of coal burned, combustion conditions, and existing control technologies installed. Therefore, it is important to understand heterogeneous Hg reaction mechanisms to predict the speciation of Hg emissions from coal-fired power plants to design and effectively determine the best applicable control technologies. In this work, theoretical and experimental investigations have been performed to investigate the adsorption and in some cases the oxidation, of Hg on solid surfaces, e.g., calcium oxide (CaO), noble metals and activated carbon (AC). The objective of this research is to identify potential materials that can be used as multi-pollutant sorbents in power plants by carrying out both high-level density functional theory (DFT) electronic structure calculations and experiments to understand heterogeneous chemical pathways of Hg. This research uses a fundamental science-based approach to understand the environmental problems caused by coal-fired energy production and provides solutions to the power generation industry for emissions reductions. Understanding the mechanism associated with Hg and SO2 adsorption on CaO will help to optimize the conditions or material to limit Hg emissions from the flue gas desulfurization process. Plane-wave DFT calculations were used to investigate the binding mechanism of Hg species and SO2 on the CaO(100) surface. The binding strengths on the high-symmetry CaO adsorption sites have been investigated for elemental Hg, SO2, mercury chlorides (HgCl and HgCl2) and mercuric oxide (HgO). It has been discovered that HgCl, HgCl2, and SO2 chemisorb on the CaO(100) surface at 0.125 ML coverage. Binding energies of elemental Hg are minimal indicating a physisorption mechanism. Noble metals such as palladium (Pd), gold (Au), silver (Ag), and copper (Cu) have been proposed to capture elemental Hg. Plane-wave DFT calculations have been carried out to investigate the mercury interactions with Pd binary alloys and overlays in addition to pure Pd, Au, Ag, and Cu surfaces. It has been determined that Pd has the highest mercury binding energy in comparison to other noble metals. In addition, Pd is found to be the primary surface atom responsible for increasing the adsorption of Hg with the surface in both Pd binary alloys and overlays. Deposition of Pd overlays on Au and Ag has been found to enhance the reactivity of the surface by shifting the d-states of surface atoms up in energy. The possible binding mechanisms of elemental Hg onto virgin, brominated and sulfonated AC fiber and brominated powder AC sorbents have been investigated through packed-bed experiments in a stream of air and simulated flue gas conditions, including SO2, hydrogen chloride (HCl), nitrogen oxide (NO) nitrogen dioxide (NO2). A combination of spectroscopy and plane-wave DFT calculations was used to characterize the sorption process. X-ray photoelectron spectroscopy (XPS) and x-ray absorption fine structure (XAFS) spectroscopy were used to analyze the surface and bulk chemical compositions of brominated AC sorbents reacted with Hg0. Through XPS surface characterization studies it was found that Hg adsorption is primarily associated with halogens on the surface. Elemental Hg is oxidized on AC surfaces and the oxidation state of adsorbed Hg is found to be Hg2+. Though plane-wave DFT and density of states (DOS) calculations indicate that Hg is more stable when it is bound to the edge carbon atom interacting with a single bromine bound atop of Hg, a model that includes an interaction between the Hg and an additional Br atom matches best with experimental data obtained from extended x-ray absorption fine structure (EXAFS) spectroscopy. The flue gas species such as HCl and bromine (Br2) enhance the Hg adsorption, while SO2 is found to decrease the Hg adsorption significantly by poisoning the active sites on the AC surface. The AC sorbents represent the most market-ready technology for Hg capture and therefore have been investigated by both theory and experiment in this work. Future work will include similar characterization and bench-scale experiments to test the metal-based materials for the sorbent and oxidation performance.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 428
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Book Description
Author: Noel de Nevers
Publisher: Waveland Press
ISBN: 1478608471
Category : Technology & Engineering
Languages : en
Pages : 611
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Book Description
Air pollution control can be approached from a number of different engineering disciplines environmental, chemical, civil, and mechanical. To that end, Noel de Nevers has written an engaging overview of the subject. While based on the fundamentals of chemical engineering, the treatment is accessible to readers with only one year of college chemistry. In addition to discussions of individual air pollutants and the theory and practice of air pollution control devices, de Nevers devotes about half the book to topics that influence device selection and design, such as atmospheric models and U.S. air pollution law. The generous number of end-of-chapter problems are designed to develop more complex thinking about the concepts presented and integrate them with readers personal experienceincreasing the likelihood of deeper understanding.
Author: Medhat A. Nemitallah
Publisher: Springer
ISBN: 3030105881
Category : Technology & Engineering
Languages : en
Pages : 378
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Book Description
This book aims to be the reference book in the area of oxyfuel combustion, covering the fundamentals, design considerations and current challenges in the field. Its first part provides an overview of the greenhouse gas emission problem and the current carbon capture and sequestration technologies. The second part introduces oxy-fuel combustion technologies with emphasis on system efficiency, combustion and emission characteristics, applications and related challenges. The third part focuses on the recent developments in ion transport membranes and their performance in both oxygen separation units and oxygen transport reactors (OTRs). The fourth part presents novel approaches for clean combustion in gas turbines and boilers. Computational modelling and optimization of combustion in gas turbine combustors and boiler furnaces are presented in the fifth part with some numerical results and detailed analyses.
