Enhanced Control of Mercury Emissions Through Modified Speciation

Enhanced Control of Mercury Emissions Through Modified Speciation PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 14

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Book Description
In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonnes̀ work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg°.

Enhanced Control of Mercury Emissions Through Modified Speciation

Enhanced Control of Mercury Emissions Through Modified Speciation PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 14

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Book Description
In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonnes̀ work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg°.

Investigation of Modified Speciation for Enhanced Control of Mercury

Investigation of Modified Speciation for Enhanced Control of Mercury PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 16

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Book Description
The control of hazardous air pollutant (HAP) emissions was addressed in Title III of the Clean Air Act Amendments of 1990, which provided an initial list of 189 elements and compounds of concern. The combustion of coal has the potential to produce a number of those species, either directly as a result of the trace elements found in coal, or as products of chemical reactions occurring in combustion. However, field studies conducted by the U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and others have shown that the actual emissions are very low and that effective particulate-matter capture can control most of the inorganic species. The most significant exception is mercury, which has also been singled out for particular regulatory attention because of its behavior in the environment (bioaccumulation) and the potential for deleterious health effects. In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. The very small amount of mercury (on the order of a few micrograms per cubic meter) in flue gas, its occurrence in several chemical forms that vary from system to system, the very low solubility of the elemental form, and the fact that it is usually in the vapor phase combine to make the achievement of cost-effective control a challenging task.

Hazardous and Radioactive Waste Treatment Technologies Handbook

Hazardous and Radioactive Waste Treatment Technologies Handbook PDF Author: Chang H. Oh
Publisher: CRC Press
ISBN: 1420036459
Category : Science
Languages : en
Pages : 790

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Book Description
With detailed photos and schematic system diagrams, the Hazardous and Radioactive Waste Treatment Technologies Handbook provides the latest information on current technologies in the market. Intended as a reference for scientists, engineers, and engineering students, it covers waste-related thermal and non-thermal technologies, separation techniques, and stabilization technologies. It provides an overview of recent waste technologies, for both hazardous chemical wastes and radioactive wastes. By implementing the techniques presented in this book, readers will be able to decide which appropriate technology to use and how to design the equipment for their particular needs.

Control of mercury emissions from coalfired electric utility boilers interim report including errata dated 32102

Control of mercury emissions from coalfired electric utility boilers interim report including errata dated 32102 PDF Author:
Publisher: DIANE Publishing
ISBN: 1428900284
Category :
Languages : en
Pages : 346

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Book Description


EM

EM PDF Author:
Publisher:
ISBN:
Category : Air quality management
Languages : en
Pages : 716

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Book Description


Mercury Control

Mercury Control PDF Author: Evan J. Granite
Publisher: John Wiley & Sons
ISBN: 3527329498
Category : Technology & Engineering
Languages : en
Pages : 479

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Book Description
This essential handbook and ready reference offers a detailed overview of the existing and currently researched technologies available for the control of mercury in coal-derived gas streams and that are viable for meeting the strict standards set by environmental protection agencies. Written by an internationally acclaimed author team from government agencies, academia and industry, it details US, EU, Asia-Pacific and other international perspectives, regulations and guidelines.

Toxicological Effects of Methylmercury

Toxicological Effects of Methylmercury PDF Author: National Research Council
Publisher: National Academies Press
ISBN: 0309171717
Category : Nature
Languages : en
Pages : 364

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Book Description
Mercury is widespread in our environment. Methylmercury, one organic form of mercury, can accumulate up the aquatic food chain and lead to high concentrations in predatory fish. When consumed by humans, contaminated fish represent a public health risk. Combustion processes, especially coal-fired power plants, are major sources of mercury contamination in the environment. The U.S. Environmental Protection Agency (EPA) is considering regulating mercury emissions from those plants. Toxicological Effects of Methylmercury reviews the health effects of methylmercury and discusses the estimation of mercury exposure from measured biomarkers, how differences between individuals affect mercury toxicity, and appropriate statistical methods for analysis of the data and thoroughly compares the epidemiological studies available on methylmercury. Included are discussions of current mercury levels on public health and a delineation of the scientific aspects and policy decisions involved in the regulation of mercury. This report is a valuable resource for individuals interested in the public health effects and regulation of mercury. The report also provides an excellent example of the implications of decisions in the risk assessment process for a larger audience.

Coal Gasification and Its Applications

Coal Gasification and Its Applications PDF Author: David A. Bell
Publisher: William Andrew
ISBN: 1437778518
Category : Science
Languages : en
Pages : 414

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Book Description
Skyrocketing energy costs have spurred renewed interest in coal gasification. Currently available information on this subject needs to be updated, however, and focused on specific coals and end products. For example, carbon capture and sequestration, previously given little attention, now has a prominent role in coal conversion processes.This book approaches coal gasification and related technologies from a process engineering point of view, with topics chosen to aid the process engineer who is interested in a complete, coal-to-products system. It provides a perspective for engineers and scientists who analyze and improve components of coal conversion processes.The first topic describes the nature and availability of coal. Next, the fundamentals of gasification are described, followed by a description of gasification technologies and gas cleaning processes. The conversion of syngas to electricity, fuels and chemicals is then discussed. Finally, process economics are covered. Emphasis is given to the selection of gasification technology based on the type of coal fed to the gasifier and desired end product: E.g., lower temperature gasifiers produce substantial quantities of methane, which is undesirable in an ammonia synthesis feed. This book also reviews gasification kinetics which is informed by recent papers and process design studies by the US Department of Energy and other groups, and also largely ignored by other gasification books.• Approaches coal gasification and related technologies from a process engineering point of view, providing a perspective for engineers and scientists who analyze and improve components of coal conversion processes • Describes the fundamentals of gasification, gasification technologies, and gas cleaning processes • Emphasizes the importance of the coal types fed to the gasifier and desired end products • Covers gasification kinetics, which was largely ignored by other gasification books - Provides a perspective for engineers and scientists who analyze and improve components of the coal conversion processes - Describes the fundamentals of gasification, gasification technologies, and gas cleaning processes - Covers gasification kinetics, which was largely ignored by other gasification books

Coal Fired Flue Gas Mercury Emission Controls

Coal Fired Flue Gas Mercury Emission Controls PDF Author: Jiang Wu
Publisher: Springer
ISBN: 3662463474
Category : Technology & Engineering
Languages : en
Pages : 163

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Book Description
Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations. Readers will arrive at a comprehensive understanding of various mercury emission control methods that are suitable for industrial applications. The book is intended for scientists, researchers, engineers and graduate students in the fields of energy science and technology, environmental science and technology and chemical engineering.

EPRI-DOE-EPA Combined Utility Air Pollutant Control Symposium

EPRI-DOE-EPA Combined Utility Air Pollutant Control Symposium PDF Author:
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 608

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Book Description