Encyclopaedia of Reaction Mechanisms of Inorganic and Organomettalic [i.e. Organometallic] Systems PDF Download
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Author: Uday Kumar (Assistant professor of chemistry)
Publisher:
ISBN: 9789350841808
Category : Chemistry, Inorganic
Languages : en
Pages : 296
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Book Description
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Author: Uday Kumar (Assistant professor of chemistry)
Publisher:
ISBN: 9789350841808
Category : Chemistry, Inorganic
Languages : en
Pages : 296
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Book Description
Author: Owen Parker
Publisher:
ISBN: 9781781540145
Category : Reaction mechanisms (Chemistry)
Languages : en
Pages : 1079
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Book Description
The effect of pressure upon the rate of a chemical reaction in solution is attributed to a volume change which occurs in the activation step of that reaction. If the change in volume on activation is negative, then the reaction is accelerated by an increase of pressure; if the volume change is positive, then the reaction is retarded by an increase of pressure. This review aims to show how such volume changes can be interpreted to yield information on the detailed molecular rearrangements which make up the reaction mechanisms of inorganic complexes.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 1461324793
Category : Social Science
Languages : en
Pages : 521
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Book Description
The purpose of this series is to provide a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organo metallic reactions in solution, with coverage being complete in each volume. The papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms and many include results of a nonkinetic nature when useful mechanistic information can be deduced. The period of literature covered by this volume is July 1982 through December 1983, and in some instances papers not available for inclusion in the previous volume are also included. Numerical results are usually reported in the units used by the original authors, except where data from different papers are com pared and conversion to common units is necessary. As in previous volumes material included covers the major areas of redox processes, reactions of the nonmetallic elements, reaction of inert and labile metal complexes and the reactions of organometallic compounds. While maintaining the space devoted to other areas, that given to the nonmetallic elements has been increased. In recognition of the increasing importance of the determination of volumes of activation in understanding the mechanisms of both inorganic and organometallic reactions a special reference section giving tabulated Ll V* values has been included and this extensive compilation will be updated in future volumes.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 1461308275
Category : Science
Languages : en
Pages : 539
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Book Description
This series, Mechanisms of Inorganic and Organometallic Reactions, provides an ongoing critical review of the published literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. Emphasis is on reactions in solution, although solid state and gas phase studies are included where they provide mechanistic insight. The sixth volume deals with papers published during the period January 1987 through June 1988 inclusive, together with some earlier work where it is appropriate to make comparisons. Coverage spans the whole area as comprehensively as practically possible, and the cited references are chosen for their relevance to the elucidation of reaction mechanisms. The now familiar format of earlier volumes has been maintained to facilitate tracing progress in a particular topic over several volumes, but some small changes have been made. Reflecting the a'mount of mechanistic work associated with ligand reactivity, and the growing importance of this area, Chapter 12 has been renamed and enlarged to bring together informa tion on both coordination and organometallic systems involving ligand reactions. Numerical data are usually reported in the units used by the original authors, except when making comparisons and conversion to common units is necessary.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 146132663X
Category : Science
Languages : en
Pages : 458
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Book Description
This series provides a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organometallic reactions in solu tion, with coverage over the whole area being complete in each volume. The format of this second volume is very similar to that of the first, with material arranged according to reaction type and compound type along generally accepted lines. Papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms but may also include results of a nonkinetic nature, such as stereochemical studies and product ratios, when useful mechanistic information can be deduced. In this volume extra space has been given to areas concerned with electron transfer processes and substitution reactions of inert complexes, and to improve convenience for the reader the text has been further divided to form three additional chapters. Electron transfer processes are discussed in three chapters: "General and Theoretical," "Reactions between Two Complexes," and "Metal-Ligand Redox Reactions," while six chapters are concerned with substitution and related reactions. Here reactions of inert chromium and cobalt complexes are discussed in separate chapters. The period of literature coverage is January 1981 through June 1982 inclusive and in a few instances, where delays in delivery of journals have been encountered, the issues not covered will be included in the next volume.
Author: M. V. Twigg
Publisher:
ISBN: 9781489916259
Category :
Languages : en
Pages : 520
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Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: M.V. Twigg
Publisher: Springer
ISBN: 0306428415
Category : Science
Languages : en
Pages : 488
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Book Description
The current volume covers electron transfer reactions, substitution and relation reactions, and reactions of organometallic compounds.
Author: Robert B. Jordan
Publisher: Oxford University Press, USA
ISBN: 9780195115550
Category : Science
Languages : en
Pages : 371
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Book Description
Ideal for one semester courses at the advanced undergraduate or graduate level, the second edition of Reaction Mechanisms of Inorganic and Organometallic Systems helps students develop both an appreciation of and skepticism about mechanistic studies. This new edition simplifies the first two chapters, which concentrate on the real world of collecting and interpreting kinetic data, to make them easily understandable to students with minimal exposure to the basics of kinetics. Subsequent chapters cover ligand substitution mechanisms, stereochemical change and fluxional processes, mechanisms of organometallic reactions, electron transfer reactions, inorganic and organometallic photochemistry, selected bioinorganic systems, and experimental methods. The second edition adds sections on the numerical solution of differential equations; the isomerization of square planar systems; the aqueous and bioinorganic chemistry of nitric oxide; and a new chapter on experimental methods. Reaction Mechanisms of Inorganic and Organometallic Systems also offers unique coverage of several topics, including extensive information on solvent exchange reactions; mechanistic interpretation of activation volumes; application of orbital symmetry rules to fluxional organometallic systems; C-H bond activation mechanisms; intervalence electron transfer and its relationship to bridged electron transfer; and flash photolysis applications in photochemistry. The text includes over 900 references to original literature (updated through 1996) and provides sample problems for each chapter.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 1489916245
Category : Science
Languages : en
Pages : 504
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Book Description
Mechanisms of Inorganic and Organometallic Reactions provides an ongoing critical review of the primary literature concerned with mechanisms of inorganic and organometallic reactions. The main focus is on reactions in solution, although solid-state and gas-phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen-month literature period, and this, the eighth volume in the series, includes papers published during January 1990 through June 1991. Where appropriate, references to earlier reports and to specific sections in previous volumes are given. Coverage spans the whole area as comprehensively as possible in each volume, and while it is impossible to be absolutely exhaustive, every effort is made to include all of the important published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are converted to common units only when comparisons are being made. The successful format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic, and the series now permits this to be done for a twelve-year period. The introduction three volumes ago of computerized techniques to improve cross-referencing in the Index brought positive reader comments, and their use is being continued.
