Encyclopaedia of Reaction Mechanisms in Inorganic and Organometallic Systems PDF Download
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Author: Owen Parker
Publisher:
ISBN: 9781781540145
Category : Reaction mechanisms (Chemistry)
Languages : en
Pages : 1079
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Book Description
The effect of pressure upon the rate of a chemical reaction in solution is attributed to a volume change which occurs in the activation step of that reaction. If the change in volume on activation is negative, then the reaction is accelerated by an increase of pressure; if the volume change is positive, then the reaction is retarded by an increase of pressure. This review aims to show how such volume changes can be interpreted to yield information on the detailed molecular rearrangements which make up the reaction mechanisms of inorganic complexes.
Author: Owen Parker
Publisher:
ISBN: 9781781540145
Category : Reaction mechanisms (Chemistry)
Languages : en
Pages : 1079
Get Book Here
Book Description
The effect of pressure upon the rate of a chemical reaction in solution is attributed to a volume change which occurs in the activation step of that reaction. If the change in volume on activation is negative, then the reaction is accelerated by an increase of pressure; if the volume change is positive, then the reaction is retarded by an increase of pressure. This review aims to show how such volume changes can be interpreted to yield information on the detailed molecular rearrangements which make up the reaction mechanisms of inorganic complexes.
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Author: Uday Kumar (Assistant professor of chemistry)
Publisher:
ISBN: 9789350841808
Category : Chemistry, Inorganic
Languages : en
Pages : 296
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Book Description
Author: Owen Parker
Publisher:
ISBN: 9781781542163
Category : Organometallic compounds
Languages : en
Pages : 264
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Book Description
No further information has been provided for this title.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 146132663X
Category : Science
Languages : en
Pages : 458
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Book Description
This series provides a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organometallic reactions in solu tion, with coverage over the whole area being complete in each volume. The format of this second volume is very similar to that of the first, with material arranged according to reaction type and compound type along generally accepted lines. Papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms but may also include results of a nonkinetic nature, such as stereochemical studies and product ratios, when useful mechanistic information can be deduced. In this volume extra space has been given to areas concerned with electron transfer processes and substitution reactions of inert complexes, and to improve convenience for the reader the text has been further divided to form three additional chapters. Electron transfer processes are discussed in three chapters: "General and Theoretical," "Reactions between Two Complexes," and "Metal-Ligand Redox Reactions," while six chapters are concerned with substitution and related reactions. Here reactions of inert chromium and cobalt complexes are discussed in separate chapters. The period of literature coverage is January 1981 through June 1982 inclusive and in a few instances, where delays in delivery of journals have been encountered, the issues not covered will be included in the next volume.
Author: Robert B. Jordan
Publisher: Oxford University Press, USA
ISBN: 9780195115550
Category : Science
Languages : en
Pages : 371
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Book Description
Ideal for one semester courses at the advanced undergraduate or graduate level, the second edition of Reaction Mechanisms of Inorganic and Organometallic Systems helps students develop both an appreciation of and skepticism about mechanistic studies. This new edition simplifies the first two chapters, which concentrate on the real world of collecting and interpreting kinetic data, to make them easily understandable to students with minimal exposure to the basics of kinetics. Subsequent chapters cover ligand substitution mechanisms, stereochemical change and fluxional processes, mechanisms of organometallic reactions, electron transfer reactions, inorganic and organometallic photochemistry, selected bioinorganic systems, and experimental methods. The second edition adds sections on the numerical solution of differential equations; the isomerization of square planar systems; the aqueous and bioinorganic chemistry of nitric oxide; and a new chapter on experimental methods. Reaction Mechanisms of Inorganic and Organometallic Systems also offers unique coverage of several topics, including extensive information on solvent exchange reactions; mechanistic interpretation of activation volumes; application of orbital symmetry rules to fluxional organometallic systems; C-H bond activation mechanisms; intervalence electron transfer and its relationship to bridged electron transfer; and flash photolysis applications in photochemistry. The text includes over 900 references to original literature (updated through 1996) and provides sample problems for each chapter.
Author: M.V. Twigg
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 552
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Book Description
The purpose of this series is to provide a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organo metallic reactions in solution, with coverage being complete in each volume. The papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms and many include results of a nonkinetic nature when useful mechanistic information can be deduced. The period of literature covered by this volume is July 1982 through December 1983, and in some instances papers not available for inclusion in the previous volume are also included. Numerical results are usually reported in the units used by the original authors, except where data from different papers are com pared and conversion to common units is necessary. As in previous volumes material included covers the major areas of redox processes, reactions of the nonmetallic elements, reaction of inert and labile metal complexes and the reactions of organometallic compounds. While maintaining the space devoted to other areas, that given to the nonmetallic elements has been increased. In recognition of the increasing importance of the determination of volumes of activation in understanding the mechanisms of both inorganic and organometallic reactions a special reference section giving tabulated Ll V* values has been included and this extensive compilation will be updated in future volumes.
Author: M.V. Twigg
Publisher: Springer
ISBN: 9780306419607
Category : Social Science
Languages : en
Pages : 552
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Book Description
The purpose of this series is to provide a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organo metallic reactions in solution, with coverage being complete in each volume. The papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms and many include results of a nonkinetic nature when useful mechanistic information can be deduced. The period of literature covered by this volume is July 1982 through December 1983, and in some instances papers not available for inclusion in the previous volume are also included. Numerical results are usually reported in the units used by the original authors, except where data from different papers are com pared and conversion to common units is necessary. As in previous volumes material included covers the major areas of redox processes, reactions of the nonmetallic elements, reaction of inert and labile metal complexes and the reactions of organometallic compounds. While maintaining the space devoted to other areas, that given to the nonmetallic elements has been increased. In recognition of the increasing importance of the determination of volumes of activation in understanding the mechanisms of both inorganic and organometallic reactions a special reference section giving tabulated Ll V* values has been included and this extensive compilation will be updated in future volumes.
Author: Smiljko Asperger
Publisher: Springer Science & Business Media
ISBN: 1441992766
Category : Science
Languages : en
Pages : 363
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Book Description
The serious study of the reaction mechanisms of transition metal com plexes began some five decades ago. Work was initiated in the United States and Great Britain; the pioneers ofthat era were, inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C. S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G. Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community of research scientists then entered the field, many of them stu dents ofthose just mentioned. Interest spread elsewhere as well, principally to Asia, Canada, and Europe. Before long, the results ofindividual studies were being consolidated into models, many of which traced their origins to the better-established field of mechanistic organic chemistry. For a time this sufficed, but major revisions and new assignments of mechanism became necessary for both ligand sub stitution and oxidation-reduction reactions. Mechanistic inorganic chemistry thus took on a shape of its own. This process has brought us to the present time. Interests have expanded both to include new and more complex species (e.g., metalloproteins) and a wealth of new experimental techniques that have developed mechanisms in ever-finer detail. This is the story the author tells, and in so doing he weaves in the identities of the investigators with the story he has to tell. This makes an enjoyable as well as informative reading.
Author: Ivano Bertini
Publisher: EOLSS Publications
ISBN: 1848262159
Category : Science
Languages : en
Pages : 502
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Book Description
Inorganic and Bio-Inorganic Chemistry is the component of Encyclopedia of Chemical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The Theme on Inorganic and Bio-Inorganic Chemistry in the Encyclopedia of Chemical Sciences, Engineering and Technology Resources deals with the discipline which studies the chemistry of the elements of the periodic table. It covers the following topics: From simple to complex compounds; Chemistry of metals; Inorganic synthesis; Radicals reactions with metal complexes in aqueous solutions; Magnetic and optical properties; Inorganometallic chemistry; High temperature materials and solid state chemistry; Inorganic biochemistry; Inorganic reaction mechanisms;Homogeneous and heterogeneous catalysis; Cluster and polynuclear compounds; Structure and bonding in inorganic chemistry; Synthesis and spectroscopy of transition metal complexes; Nanosystems;Computational inorganic chemistry; Energy and inorganic chemistry. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs
Author: Smiljko Asperger
Publisher: Springer
ISBN: 9781441992772
Category : Science
Languages : en
Pages : 361
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Book Description
The serious study of the reaction mechanisms of transition metal com plexes began some five decades ago. Work was initiated in the United States and Great Britain; the pioneers ofthat era were, inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C. S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G. Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community of research scientists then entered the field, many of them stu dents ofthose just mentioned. Interest spread elsewhere as well, principally to Asia, Canada, and Europe. Before long, the results ofindividual studies were being consolidated into models, many of which traced their origins to the better-established field of mechanistic organic chemistry. For a time this sufficed, but major revisions and new assignments of mechanism became necessary for both ligand sub stitution and oxidation-reduction reactions. Mechanistic inorganic chemistry thus took on a shape of its own. This process has brought us to the present time. Interests have expanded both to include new and more complex species (e.g., metalloproteins) and a wealth of new experimental techniques that have developed mechanisms in ever-finer detail. This is the story the author tells, and in so doing he weaves in the identities of the investigators with the story he has to tell. This makes an enjoyable as well as informative reading.
