Electronic and Molecular Structure of Electrode-electrolyte Interfaces

Electronic and Molecular Structure of Electrode-electrolyte Interfaces PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 697

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Electronic and Molecular Structure of Electrode-electrolyte Interfaces

Electronic and Molecular Structure of Electrode-electrolyte Interfaces PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 697

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Electronic and Molecular Structure of Electrode-electrolyte Interfaces

Electronic and Molecular Structure of Electrode-electrolyte Interfaces PDF Author: Wilford N. Hansen
Publisher: Elsevier Publishing Company
ISBN:
Category : Electrochemistry
Languages : en
Pages : 718

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Proceedings of the Symposium on Microscopic Models of Electrode- Electrolyte Interfaces

Proceedings of the Symposium on Microscopic Models of Electrode- Electrolyte Interfaces PDF Author: Electrochemical Society. Corrosion Division
Publisher: The Electrochemical Society
ISBN: 9781566770521
Category : Science
Languages : en
Pages : 362

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Modern Aspects of Electrochemistry 28

Modern Aspects of Electrochemistry 28 PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 9780306451461
Category : Comics & Graphic Novels
Languages : en
Pages : 424

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Book Description
From reviews of previous volumes: 'This volume continues the valuable service that has been rendered by the Modern Aspects series.'-Journal of Electroanalytical Chemistry 'Extremely well referenced and very readable....Maintains the overall high standards of the series.'-Journal of the American Chemical Society

Modern Aspects of Electrochemistry

Modern Aspects of Electrochemistry PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1489917187
Category : Science
Languages : en
Pages : 414

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Book Description
No. 28 of this highly regarded series explores the fundamental and applied aspects of electrochemical science. This volume features two detailed studies on the rapidly developing field of electrochemical surface science.

Electronic and Atomic Structure and Dynamics of Electrode Electrolyte Interfaces by Computer Simulation

Electronic and Atomic Structure and Dynamics of Electrode Electrolyte Interfaces by Computer Simulation PDF Author: Sean Michael Walbran
Publisher:
ISBN:
Category :
Languages : en
Pages : 190

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Spectroelectrochemistry

Spectroelectrochemistry PDF Author: Robert J. Gale
Publisher: Springer Science & Business Media
ISBN: 1461309859
Category : Science
Languages : en
Pages : 462

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Book Description
The intention of this monograph has been to assimilate key practical and theoretical aspects of those spectroelectrochemical techniques likely to become routine aids to electrochemical research and analysis. Many new methods for interphasial studies have been and are being developed. Accordingly, this book is restricted in scope primarily to in situ methods for studying metal! electrolyte or semiconductor! electrolyte systems; moreover, it is far from inclusive of the spectroelectrochemical techniques that have been devised. However, it is hoped that the practical descriptions provided are sufficiently explicit to encourage and enable the newcomer to establish the experimental facilities needed for a particular problem. The chapters in this text have been written by international authorities in their particular specialties. Each chapter is broadly organized to review the origins and historical background of the field, to provide sufficiently detailed theory for graduate student comprehension, to describe the practical design and experimental methodology, and to detail some representative application examples. Since publication of Volume 9 of the Advances in Electrochemistry and Electrochemical Engineering series (1973), a volume devoted specifically to spectroelectrochemistry, there has been unabated growth of these fields. A number of international symposia-such as those held at Snowmass, Colorado, in 1978, the proceedings of which were published by North-Holland (1980); at Logan, Utah in 1982, published by Elsevier (1983); or at the Fritz Haber Institute in 1986-have served as forums for the discussion of nontraditional methods to study interphases and as means for the dissemination of a diversity of specialist research papers.

Electrified Interfaces in Physics, Chemistry and Biology

Electrified Interfaces in Physics, Chemistry and Biology PDF Author: R Guidelli
Publisher: Springer Science & Business Media
ISBN: 940112566X
Category : Science
Languages : en
Pages : 604

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Book Description
Electrified interfaces span from metaVsemiconductor and metaVelectrolyte interfaces to disperse systems and biological membranes, and are notably important in so many physical, chemical and biological systems that their study has been tackled by researchers with different scientific backgrounds using different methodological approaches. The various electrified interfaces have several common features. The equilibrium distribution of positive and negative ions in an electrolytic solution is governed by the same Poisson-Boltzmann equation independent of whether the solution comes into contact with a metal, a colloidal particle or a biomembrane, and the same is true for the equilibrium distribution of free electrons and holes of a semiconductor in contact with a different conducting phase. Evaluation of electric potential differences across biomembranes is based on the same identity of electrochemical potentials which holds for a glass electrode and which yields the Nernst equation when applied to a metal/solution interface. The theory of thermally activated electron tunneling, which was developed by Marcus, Levich, Dogonadze and others to account for electron transfer across metaVelectrolyte interfaces, is also applied to light induced charge separation and proton translocation reactions across intercellular membranes. From an experimental viewpoint, the same electrochemical and in situ spectroscopic techniques can equally well be employed for the study of apparently quite different electrified interfaces.

Structure and Dynamics of Solutions

Structure and Dynamics of Solutions PDF Author: H. Ohtaki
Publisher: Elsevier
ISBN: 1483291421
Category : Science
Languages : en
Pages : 344

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Book Description
Recent advances in the study of structural and dynamic properties of solutions have provided a molecular picture of solute-solvent interactions. Although the study of thermodynamic as well as electronic properties of solutions have played a role in the development of research on the rate and mechanism of chemical reactions, such macroscopic and microscopic properties are insufficient for a deeper understanding of fast chemical and biological reactions. In order to fill the gap between the two extremes, it is necessary to know how molecules are arranged in solution and how they change their positions in both the short and long range. This book has been designed to meet these criteria. It is possible to develop a sound microscopic picture for reaction dynamics in solution without molecular-level knowledge of how reacting ionic or neutral species are solvated and how rapidly the molecular environment is changing with time. A variety of actual examples is given as to how and when modern molecular approaches can be used to solve specific solution problems. The following tools are discussed: x-ray and neutron diffraction, EXAFS, and XANES, molecular dynamics and Monte Carlo computer simulations, Raman, infrared, NMR, fluorescence, and photoelectron emission spectroscopic methods, conductance and viscosity measurements, high pressure techniques, and statistical mechanics methods. Static and dynamic properties of ionic solvation, molecular solvation, ion-pair formation, ligand exchange reactions, and typical organic solvents are useful for bridging the gap between classical thermodynamic studies and modern single-molecule studies in the gas phase. The book will be of interest to solution, physical, inorganic, analytical and structural chemists as well as to chemical kineticists.

Surface Science of Intercalation Materials and Solid Electrolytes

Surface Science of Intercalation Materials and Solid Electrolytes PDF Author: René Hausbrand
Publisher: Springer Nature
ISBN: 303052826X
Category : Science
Languages : en
Pages : 109

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Book Description
This book shares essential insights into the formation and properties of ionic interfaces based on the energy level structures of their interfaces obtained using a surface science approach. It covers both interfaces with liquid and solid electrolyte contacts, and includes different material classes, such as oxides and phosphates. The specific material properties result in particular effects observed at interfaces, which are often not yet, or not sufficiently, taken into account in battery development and technologies. Discussing fundamental issues concerning the properties of intercalation electrodes and electrode–solid electrolyte interfaces, the book investigates the factors that determine voltage, kinetics and reactivity. It presents experimental results on interface formation, and relates them to electron and ion energy levels in the materials and at their interfaces. It explores these topics integrating electrochemistry, solid-state ionics and semiconductor physics, and accordingly will appeal not only to battery scientists, but also to a broader scientific community, including material scientists and electrochemists.