Electron, Oxygen, and Spin Transport in Complex Oxide Perovskites

Electron, Oxygen, and Spin Transport in Complex Oxide Perovskites PDF Author: Purnima P. Balakrishnan
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
The manipulation of the spin of charge carriers within solid-state materials has the potential to greatly reduce power consumption and increase computational speeds and information storage densities. The development of these spintronic devices requires development of new materials which can be used to efficiently generate, propagate, and detect spin currents. One promising class of materials to use are the complex oxide perovskites, which exhibit a rich variety of tunable electronic and magnetic properties and which can be interfaced and combined to create emergent interfacial phenomena. In this thesis, I will cover two efforts to develop materials for spintronics applications. The first part of this thesis focuses on the surprising discovery that the pulsed laser deposition process used to grow homoepitaxial thin films of oxygen-deficient SrTiO(3-x) can significantly change the properties of the underlying SrTiO3 substrate. In the search for a low-dimensional metal with high mobility and high spin-orbit coupling, I find that the plume dynamics and kinetics during thin film growth cause significant oxygen-reduction of and conductivity in the entire substrate, significantly faster than by other processes. This has significant implications for thin film growth of many different materials. In the second part of the thesis, I will focus on spin current generation via microwaves in a low-loss ferromagnetic metal, (La2/3Sr1/3)MnO3, and the transmission of spin angular momentum across an epitaxial interface with a non-magnetic, high spin-orbit coupled metal, CaRuO3. Using ferromagnetic resonance spectroscopy to both generate these spin currents as well as measure magnetic properties, I not only find evidence of efficient spin pumping across the interface, but also find that the orthorhombic CaRuO3 can affect the magnetic and electronic anisotropy in these heterostructures, likely due to structural effects. While complex oxides remain promising candidates for spintronics, the integration of different materials offers additional degrees of freedom which must be fully understood to engineer additional functionality.

Electron, Oxygen, and Spin Transport in Complex Oxide Perovskites

Electron, Oxygen, and Spin Transport in Complex Oxide Perovskites PDF Author: Purnima P. Balakrishnan
Publisher:
ISBN:
Category :
Languages : en
Pages :

Get Book Here

Book Description
The manipulation of the spin of charge carriers within solid-state materials has the potential to greatly reduce power consumption and increase computational speeds and information storage densities. The development of these spintronic devices requires development of new materials which can be used to efficiently generate, propagate, and detect spin currents. One promising class of materials to use are the complex oxide perovskites, which exhibit a rich variety of tunable electronic and magnetic properties and which can be interfaced and combined to create emergent interfacial phenomena. In this thesis, I will cover two efforts to develop materials for spintronics applications. The first part of this thesis focuses on the surprising discovery that the pulsed laser deposition process used to grow homoepitaxial thin films of oxygen-deficient SrTiO(3-x) can significantly change the properties of the underlying SrTiO3 substrate. In the search for a low-dimensional metal with high mobility and high spin-orbit coupling, I find that the plume dynamics and kinetics during thin film growth cause significant oxygen-reduction of and conductivity in the entire substrate, significantly faster than by other processes. This has significant implications for thin film growth of many different materials. In the second part of the thesis, I will focus on spin current generation via microwaves in a low-loss ferromagnetic metal, (La2/3Sr1/3)MnO3, and the transmission of spin angular momentum across an epitaxial interface with a non-magnetic, high spin-orbit coupled metal, CaRuO3. Using ferromagnetic resonance spectroscopy to both generate these spin currents as well as measure magnetic properties, I not only find evidence of efficient spin pumping across the interface, but also find that the orthorhombic CaRuO3 can affect the magnetic and electronic anisotropy in these heterostructures, likely due to structural effects. While complex oxides remain promising candidates for spintronics, the integration of different materials offers additional degrees of freedom which must be fully understood to engineer additional functionality.

Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems

Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems PDF Author: Nina Orlovskaya
Publisher: Springer Science & Business Media
ISBN: 1402023499
Category : Technology & Engineering
Languages : en
Pages : 315

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Book Description
Advanced mixed ionic electronic conducting (MIEC) perovskites play an important role in many electrochemical systems for advanced energy technologies. They are major components in such devices as solid oxide fuel cells (SOFCs), oxygen separation membranes, chemical sensors and catalysts. In addition to energy technology, the development of these multifunctional materials is of crucial importance for transportation, aerospace engineering, and electronics. The use of these materials as chemical sensors is also important for anti-terrorism initiatives. The present book discusses progress and problems in the development of ionic, electronic, and MIEC materials as active materials in advanced energy systems; the development and design of solid-oxide fuel cells (SOFCs) for next-generation vehicles, chemical sensors and oxygen separation membranes; and identifies directions for future research, such as conducting mechanisms, stability and reliability of devices, degradation problems, crystal structure, classification of phase transitions exhibited by the materials.

Handbook of Spin Transport and Magnetism

Handbook of Spin Transport and Magnetism PDF Author: Evgeny Y. Tsymbal
Publisher: CRC Press
ISBN: 1439803781
Category : Science
Languages : en
Pages : 797

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Book Description
In the past several decades, the research on spin transport and magnetism has led to remarkable scientific and technological breakthroughs, including Albert Fert and Peter Grunberg's Nobel Prize-winning discovery of giant magnetoresistance (GMR) in magnetic metallic multilayers. Handbook of Spin Transport and Magnetism provides a comprehensive, bal

Oxide Spintronics

Oxide Spintronics PDF Author: Tamalika Banerjee
Publisher: CRC Press
ISBN: 0429886896
Category : Science
Languages : en
Pages : 225

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Book Description
Oxide materials have been used in mainstream semiconductor technology for several decades and have served as important components, such as gate insulators or capacitors, in integrated circuits. However, in recent decades, this material class has emerged in its own right as a potential contender for alternative technologies, generally designated as ‘beyond Moore’. The 2004 discovery by Ohtomo and Hwang was a global trendsetter in this context. It involved observing a two-dimensional, high-mobility electron gas at the heterointerface between two insulating oxides, LaAlO3 and SrTiO3, supported by the rise of nascent deposition and growth-monitoring techniques, which was an important direction in materials science research. The quest to understand the origin of this unparalleled physical property and to find other emergent properties has been an active field of research in condensed matter that has united researchers with expertise in diverse fields such as thin-film growth, defect control, advanced microscopy, semiconductor technology, computation, magnetism and electricity, spintronics, nanoscience, and nanotechnology.

Properties of Perovskites and Other Oxides

Properties of Perovskites and Other Oxides PDF Author: Karl A. Mller
Publisher: World Scientific
ISBN: 9814293350
Category : Science
Languages : en
Pages : 583

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Book Description
In this book some 50 papers published by K A Mller as author or co-author over a period from 1959 till 2009, amplified by more recent work mainly by T W Kool with collaborators are reproduced. The main subject is Electron Paramagnetic Resonance (EPR) applied to the study of perovskites and other oxides with related subjects. This wealth of papers is organized into eleven chapters, each with an introductory text written in the light of current understanding. The contributions of the first author on structural phase transitions have been immense, and because K A Mller and J C Fayet have published a review paper on the subject, the latter is reproduced in chapter VII. Exceptions is here I have omitted the half sentence on chapter VI, it is EPR related whole chapter VIII on dipolar and quantum paraelectric behavior with dielectric studies. Further in chapter X two papers proving the existence of Fermi-Glasses are reproduced. The year 1986 bears some significance: early in this year the paper by Bednorz and Mller on the possible observation of superconductivity was published. This resulted in a substantial shift in the paradigm of condensed matter physics to which the present first author has scientifically with those that of others in a second volume.

Perovskites and Related Mixed Oxides

Perovskites and Related Mixed Oxides PDF Author: Pascal Granger
Publisher: John Wiley & Sons
ISBN: 3527337636
Category : Technology & Engineering
Languages : en
Pages : 1050

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Book Description
This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.

Spectroscopy of Complex Oxide Interfaces

Spectroscopy of Complex Oxide Interfaces PDF Author: Claudia Cancellieri
Publisher: Springer
ISBN: 3319749897
Category : Technology & Engineering
Languages : en
Pages : 326

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Book Description
This book summarizes the most recent and compelling experimental results for complex oxide interfaces. The results of this book were obtained with the cutting-edge photoemission technique at highest energy resolution. Due to their fascinating properties for new-generation electronic devices and the challenge of investigating buried regions, the book chiefly focuses on complex oxide interfaces. The crucial feature of exploring buried interfaces is the use of soft X-ray angle-resolved photoemission spectroscopy (ARPES) operating on the energy range of a few hundred eV to increase the photoelectron mean free path, enabling the photons to penetrate through the top layers – in contrast to conventional ultraviolet (UV)-ARPES techniques. The results presented here, achieved by different research groups around the world, are summarized in a clearly structured way and discussed in comparison with other photoemission spectroscopy techniques and other oxide materials. They are complemented and supported by the most recent theoretical calculations as well as results of complementary experimental techniques including electron transport and inelastic resonant X-ray scattering.

Spintronics Handbook, Second Edition: Spin Transport and Magnetism

Spintronics Handbook, Second Edition: Spin Transport and Magnetism PDF Author: Evgeny Y. Tsymbal
Publisher: CRC Press
ISBN: 0429784376
Category : Science
Languages : en
Pages : 530

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Book Description
The second edition offers an update on the single most comprehensive survey of the two intertwined fields of spintronics and magnetism, covering the diverse array of materials and structures, including silicon, organic semiconductors, carbon nanotubes, graphene, and engineered nanostructures. It focuses on seminal pioneering work, together with the latest in cutting-edge advances, notably extended discussion of two-dimensional materials beyond graphene, topological insulators, skyrmions, and molecular spintronics. The main sections cover physical phenomena, spin-dependent tunneling, control of spin and magnetism in semiconductors, and spin-based applications.

Epitaxial Growth of Complex Metal Oxides

Epitaxial Growth of Complex Metal Oxides PDF Author: Gertjan Koster
Publisher: Woodhead Publishing
ISBN: 0081029462
Category : Science
Languages : en
Pages : 534

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Book Description
Epitaxial Growth of Complex Metal Oxides, Second Edition reviews techniques and recent developments in the fabrication quality of complex metal oxides, which are facilitating advances in electronic, magnetic and optical applications. Sections review the key techniques involved in the epitaxial growth of complex metal oxides and explore the effects of strain and stoichiometry on crystal structure and related properties in thin film oxides. Finally, the book concludes by discussing selected examples of important applications of complex metal oxide thin films, including optoelectronics, batteries, spintronics and neuromorphic applications. This new edition has been fully updated, with brand new chapters on topics such as atomic layer deposition, interfaces, STEM-EELs, and the epitaxial growth of multiferroics, ferroelectrics and nanocomposites. - Examines the techniques used in epitaxial thin film growth for complex oxides, including atomic layer deposition, sputtering techniques, molecular beam epitaxy, and chemical solution deposition techniques - Reviews materials design strategies and materials property analysis methods, including the impacts of defects, strain, interfaces and stoichiometry - Describes key applications of epitaxially grown metal oxides, including optoelectronics, batteries, spintronics and neuromorphic applications

Emergent Electron Transport Properties at Complex Oxide Interfaces

Emergent Electron Transport Properties at Complex Oxide Interfaces PDF Author: K. H. Bevan
Publisher:
ISBN: 9781510803435
Category :
Languages : en
Pages : 30

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Book Description