Dynamics and Statics of Liquid-liquid and Gas-liquid Interfaces on Non-uniform Substrates at the Micron and Sub-micron Scales PDF Download
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Author: Michael M. Norton
Publisher:
ISBN:
Category :
Languages : en
Pages : 314
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Book Description
Droplets and bubbles are ubiquitous motifs found in natural and industrial processes. In the absence of significant external forces, liquid-liquid and gas-liquid interfaces form constant mean curvature surfaces that locally minimize the free energy of a given system subject to constraints. However, even for sub-micron bubbles and droplets free of hydrodynamic and hydrostatic stresses (small Capillary, Weber, and Bond numbers), non-equilibrium at the contact line of sessile bubbles and droplets can influence geometries and dynamics. First, the wetting of micron-sized ellipsoidal particles was considered. In the space of axially symmetric interfaces, it is found that multiple constant mean curvature surfaces can satisfy volume and contact angle constraints. Partial encapsulation may be preferred even when the droplet's volume is sufficient to fully engulf the particle. The co-existence of multiple equilibrium states suggests possible hysteretic encapsulation behavior. Secondly, motivated by electron microscopy observations of sub-micron bubbles in a liquid cell, a small mobile and growing bubble confined between two weakly diverging plates is considered theoretically. Scaling analysis suggests that observed bubbles move by continuously wetting and de-wetting the substrates onto which they are adhered. 2D and 3D models are constructed incorporating the Blake-Haynes mechanism, which relates the dynamic contact angle to contact line velocity; partial pinning of the contact line is also considered. In 2D, the system is fully described by a set of non-linear ordinary differential equations that can be readily solved. In 3D, the non-linear PDE system and constraints were solved using a pseudo-spectral method. Both 2D and 3D models predict that in order for a doubly confined bubble to grow in a super-saturated solution it must first increase its curvature; this is in contrast to a free-floating bubble whose curvature always decreases with the addition of mass/volume. Since the surface concentration is proportional to the internal pressure of the bubble, this geometric change temporarily regulates the growth of the bubble. The model predicts growth rates like those observed experimentally that are several orders of magnitude lower than predictions made by classical mass transfer driven growth theory developed by Epstein and Plesset.
Author: Michael M. Norton
Publisher:
ISBN:
Category :
Languages : en
Pages : 314
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Book Description
Droplets and bubbles are ubiquitous motifs found in natural and industrial processes. In the absence of significant external forces, liquid-liquid and gas-liquid interfaces form constant mean curvature surfaces that locally minimize the free energy of a given system subject to constraints. However, even for sub-micron bubbles and droplets free of hydrodynamic and hydrostatic stresses (small Capillary, Weber, and Bond numbers), non-equilibrium at the contact line of sessile bubbles and droplets can influence geometries and dynamics. First, the wetting of micron-sized ellipsoidal particles was considered. In the space of axially symmetric interfaces, it is found that multiple constant mean curvature surfaces can satisfy volume and contact angle constraints. Partial encapsulation may be preferred even when the droplet's volume is sufficient to fully engulf the particle. The co-existence of multiple equilibrium states suggests possible hysteretic encapsulation behavior. Secondly, motivated by electron microscopy observations of sub-micron bubbles in a liquid cell, a small mobile and growing bubble confined between two weakly diverging plates is considered theoretically. Scaling analysis suggests that observed bubbles move by continuously wetting and de-wetting the substrates onto which they are adhered. 2D and 3D models are constructed incorporating the Blake-Haynes mechanism, which relates the dynamic contact angle to contact line velocity; partial pinning of the contact line is also considered. In 2D, the system is fully described by a set of non-linear ordinary differential equations that can be readily solved. In 3D, the non-linear PDE system and constraints were solved using a pseudo-spectral method. Both 2D and 3D models predict that in order for a doubly confined bubble to grow in a super-saturated solution it must first increase its curvature; this is in contrast to a free-floating bubble whose curvature always decreases with the addition of mass/volume. Since the surface concentration is proportional to the internal pressure of the bubble, this geometric change temporarily regulates the growth of the bubble. The model predicts growth rates like those observed experimentally that are several orders of magnitude lower than predictions made by classical mass transfer driven growth theory developed by Epstein and Plesset.
Author: Shigeo Fujikawa
Publisher: Springer
ISBN: 9783642180378
Category : Technology & Engineering
Languages : en
Pages : 230
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Book Description
Physically correct boundary conditions on vapor-liquid interfaces are essential in order to make an analysis of flows of a liquid including bubbles or of a gas including droplets. Suitable boundary conditions do not exist at the present time. This book is concerned with the kinetic boundary condition for both the plane and curved vapor-liquid interfaces, and the fluid dynamics boundary condition for Navier-Stokes(fluid dynamics) equations. The kinetic boundary condition is formulated on the basis of molecular dynamics simulations and the fluid dynamics boundary condition is derived by a perturbation analysis of Gaussian-BGK Boltzmann equation applicable to polyatomic gases. The fluid dynamics boundary condition is applied to actual flow problems of bubbles in a liquid and droplets in a gas.
Author: Daniel Joseph Walls
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
This thesis is comprised of three parts, focusing on the dynamics of miscible liquid interfaces, the dynamics of ultra-low surface tension liquid interfaces, and the spreading of "rinsing" liquids across rotating, horizontal substrates. Miscible liquids commonly contact one another in natural and technological situations, often as one liquid suspended within another or in the proximity of a solid substrate. A systematic experimental study of the shape evolution of pendant and sessile droplets immersed in miscible environments was conducted. We present experimental findings that have distinctly different shape evolution and time-dependent dynamics from droplets present in immiscible environments, which have been reported previously. A complementary numerical approach to compute the concentration and velocity fields of these systems using a simplified set of governing equations is paired with our experimental findings. Additionally, a study of droplets freely rising through a miscible, more viscous liquid was conducted. We report observations of droplets of water rising through glycerol and corn syrup. A class of ultra-low surface tension liquids are aqueous two-phase solutions, which form by the phase separation of different polymers within an aqueous solution when a critical threshold in concentration of polymer is exceeded. We investigate two configurations of water-water emulsions: a sessile drop, and a drop at a planar liquid-liquid interface of an aqueous two-phase solution. A particular class of liquids that spread across solid surfaces are "rinsing" liquids. When applied to a rotating substrate, the dynamics of rinsing liquids are interesting fundamentally in the interaction of several classic modes of spreading and industrially in a variety of cleaning applications, such as in the manufacturing of silicon wafers. An investigation of the spreading of a rinsing liquid across a horizontal, rotating hydrophilic substrate was conducted. We present experimental findings of the spreading radius of the rinsing liquid, in which we observed four distinct growth rates across the parameter space and use lubrication theory to explain the phenomena.
Author: Alexander G. Volkov
Publisher: CRC Press
ISBN: 1000099032
Category : Medical
Languages : en
Pages : 448
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Book Description
Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area. Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes. Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.
Author: Nikola Kallay
Publisher: CRC Press
ISBN: 9780824700065
Category : Science
Languages : en
Pages : 0
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Book Description
An examination of the theoretical foundations of the kinetics and thermodynamics of solid-liquid interfaces, as well as state-of-the-art industrial applications, this book presents information on surface and colloidal chemical processes and evaluates vital analytical tools such as atomic force microscopy, surface force apparatus measurements, and photon correlation spectroscopy.
Author: Cameron Tropea
Publisher: Springer Science & Business Media
ISBN: 3540251413
Category : Science
Languages : en
Pages : 1570
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Book Description
Accompanying DVD-ROM contains ... "all chapters of the Springer Handbook."--Page 3 of cover.
Author: Annick LESNE
Publisher: Springer Science & Business Media
ISBN: 364215123X
Category : Science
Languages : en
Pages : 406
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Book Description
During a century, from the Van der Waals mean field description (1874) of gases to the introduction of renormalization group (RG techniques 1970), thermodynamics and statistical physics were just unable to account for the incredible universality which was observed in numerous critical phenomena. The great success of RG techniques is not only to solve perfectly this challenge of critical behaviour in thermal transitions but to introduce extremely useful tools in a wide field of daily situations where a system exhibits scale invariance. The introduction of scaling, scale invariance and universality concepts has been a significant turn in modern physics and more generally in natural sciences. Since then, a new "physics of scaling laws and critical exponents", rooted in scaling approaches, allows quantitative descriptions of numerous phenomena, ranging from phase transitions to earthquakes, polymer conformations, heartbeat rhythm, diffusion, interface growth and roughening, DNA sequence, dynamical systems, chaos and turbulence. The chapters are jointly written by an experimentalist and a theorist. This book aims at a pedagogical overview, offering to the students and researchers a thorough conceptual background and a simple account of a wide range of applications. It presents a complete tour of both the formal advances and experimental results associated with the notion of scaling, in physics, chemistry and biology.
Author: Hans-Jürgen Butt
Publisher: John Wiley & Sons
ISBN: 3527836160
Category : Science
Languages : en
Pages : 485
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Book Description
Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.
Author: Federico Toschi
Publisher: Springer Nature
ISBN: 3030233707
Category : Science
Languages : en
Pages : 309
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Book Description
This open access book, published in the Soft and Biological Matter series, presents an introduction to selected research topics in the broad field of flowing matter, including the dynamics of fluids with a complex internal structure -from nematic fluids to soft glasses- as well as active matter and turbulent phenomena. Flowing matter is a subject at the crossroads between physics, mathematics, chemistry, engineering, biology and earth sciences, and relies on a multidisciplinary approach to describe the emergence of the macroscopic behaviours in a system from the coordinated dynamics of its microscopic constituents. Depending on the microscopic interactions, an assembly of molecules or of mesoscopic particles can flow like a simple Newtonian fluid, deform elastically like a solid or behave in a complex manner. When the internal constituents are active, as for biological entities, one generally observes complex large-scale collective motions. Phenomenology is further complicated by the invariable tendency of fluids to display chaos at the large scales or when stirred strongly enough. This volume presents several research topics that address these phenomena encompassing the traditional micro-, meso-, and macro-scales descriptions, and contributes to our understanding of the fundamentals of flowing matter. This book is the legacy of the COST Action MP1305 “Flowing Matter”.
Author: John Monteith
Publisher: Butterworth-Heinemann
ISBN: 9780713129311
Category : Nature
Languages : en
Pages : 308
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Book Description
Thoroughly revised and up-dated edition of a highly successful textbook.