Dissolution of High-density UO2, PuO2, and UO2-PuO2 Pellets in Inorganic Acids

Dissolution of High-density UO2, PuO2, and UO2-PuO2 Pellets in Inorganic Acids PDF Author: Armando L. Uriarte
Publisher:
ISBN:
Category : Inorganic acids
Languages : en
Pages : 90

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Dissolution of High-density UO2, PuO2, and UO2-PuO2 Pellets in Inorganic Acids

Dissolution of High-density UO2, PuO2, and UO2-PuO2 Pellets in Inorganic Acids PDF Author: Armando L. Uriarte
Publisher:
ISBN:
Category : Inorganic acids
Languages : en
Pages : 90

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DISSOLUTION OF HIGH-DENSITY UO2, PuO2, AND UO2-PuO2 PELLETS IN INORGANIC ACIDS.

DISSOLUTION OF HIGH-DENSITY UO2, PuO2, AND UO2-PuO2 PELLETS IN INORGANIC ACIDS. PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Analysis of UO2 Dissolution in Nitric Acid Solution

Analysis of UO2 Dissolution in Nitric Acid Solution PDF Author: H. F. Johnson
Publisher:
ISBN:
Category : Dissolution
Languages : en
Pages : 42

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Dissolution Properties of UO2--PuO2 Thermal Reactor Fuels

Dissolution Properties of UO2--PuO2 Thermal Reactor Fuels PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Experimental and Calculated Results for UO2 and UO2-PuO2 Fueled H2O-moderated Loadings

Experimental and Calculated Results for UO2 and UO2-PuO2 Fueled H2O-moderated Loadings PDF Author: Paolo Loizzo
Publisher:
ISBN:
Category :
Languages : en
Pages :

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THE PuO2-UO2 EXPERIMENT IN THE EBWR.

THE PuO2-UO2 EXPERIMENT IN THE EBWR. PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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The Dissolution of Uranium Oxides in HB-Line Phase 1 Dissolvers

The Dissolution of Uranium Oxides in HB-Line Phase 1 Dissolvers PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5

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A series of characterization and dissolution studies has been performed to define flowsheet conditions for the dissolution of uranium oxide materials in dissolvers. The samples selected for analysis were uranium oxide materials. The selection of these uranium oxide materials for characterization and dissolution studies was based on high enriched uranium content and trace levels of plutonium. Test results from the characterization study identified ferric oxide (Fe2O3) and iron/chromium/nickel (Fe/Cr/Ni) particles as impurities along with the tri-uranium oxide (U3O8) and uranium trioxide (UO3). The weight percent uranium in this material was found to vary depending on the impurity content. The trace impurity plutonium appears to be associated with the Fe/Cr/Ni particles. A small amount of absorbed moisture and waters of hydration is present. Most of the uranium oxides easily dissolved in low-molar nitric acid solutions without fluoride within one to two hours at solution temperature s between 60-80 degrees C.A small amount of residue remained following this dissolution step. To assure complete dissolution of uranium from these oxide materials, an additional dissolution step at 90 degrees C to boiling for at least one to two hours has been suggested. Only trace amounts of iron associated with Fe2O3 and Fe/Cr/Ni particles will dissolve during the dissolution steps. Neither hydrogen nor heat will be generated during the dissolution of these uranium oxide materials in nitric acid solutions. Some brown nitrogen dioxide (NO2) fumes will be generated during the dissolution of U3O8.

The Dissolution of Uranium Dioxide Sintered Pellets in Nitric Acid

The Dissolution of Uranium Dioxide Sintered Pellets in Nitric Acid PDF Author: R.F. Taylor
Publisher:
ISBN:
Category :
Languages : en
Pages : 27

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Dissolution of Plutonium Dioxide Using HCl-HF.

Dissolution of Plutonium Dioxide Using HCl-HF. PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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High-fired PuO2 (950° to 1700°C) can be dissolved in boiling 6.1 M HCl when the fluoride ion concentration to plutonium mole (F−/Pu) ratio is>0.5. The amount of PuO2 (950°C calcined oxide) dissolved in 1 hour increased from approx.0.2% to 66%, 91%, and 100% as the F−/Pu ratio increased from 0 to 0.5, 1.0, and 1.8, respectively. The PuO2 dissolution rates in HCl-CaF2 solutions decrease with increasing oxide calcination temperatures and decreasing oxide surface areas. At a F−/Pu ratio of 1.8, the 1700°C calcined oxide was completely dissolved in 2.5 hours versus 1 hour for the 950°C calcined oxide.

Comprehensive Nuclear Materials

Comprehensive Nuclear Materials PDF Author:
Publisher: Elsevier
ISBN: 0081028660
Category : Science
Languages : en
Pages : 4871

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Book Description
Materials in a nuclear environment are exposed to extreme conditions of radiation, temperature and/or corrosion, and in many cases the combination of these makes the material behavior very different from conventional materials. This is evident for the four major technological challenges the nuclear technology domain is facing currently: (i) long-term operation of existing Generation II nuclear power plants, (ii) the design of the next generation reactors (Generation IV), (iii) the construction of the ITER fusion reactor in Cadarache (France), (iv) and the intermediate and final disposal of nuclear waste. In order to address these challenges, engineers and designers need to know the properties of a wide variety of materials under these conditions and to understand the underlying processes affecting changes in their behavior, in order to assess their performance and to determine the limits of operation. Comprehensive Nuclear Materials, Second Edition, Seven Volume Set provides broad ranging, validated summaries of all the major topics in the field of nuclear material research for fission as well as fusion reactor systems. Attention is given to the fundamental scientific aspects of nuclear materials: fuel and structural materials for fission reactors, waste materials, and materials for fusion reactors. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource of information. Most of the chapters from the first Edition have been revised and updated and a significant number of new topics are covered in completely new material. During the ten years between the two editions, the challenge for applications of nuclear materials has been significantly impacted by world events, public awareness, and technological innovation. Materials play a key role as enablers of new technologies, and we trust that this new edition of Comprehensive Nuclear Materials has captured the key recent developments. Critically reviews the major classes and functions of materials, supporting the selection, assessment, validation and engineering of materials in extreme nuclear environments Comprehensive resource for up-to-date and authoritative information which is not always available elsewhere, even in journals Provides an in-depth treatment of materials modeling and simulation, with a specific focus on nuclear issues Serves as an excellent entry point for students and researchers new to the field