Design, Synthesis, and Performance of Novel Bifunctional Transition Metal Complexes for Organic Reactions PDF Download
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Author: Braden Eric Silva
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
CHAPTER 1. This chapter introduces the field of study and motivations steering the direction of development. The topics of catalysis and bifunctional catalysis are discussed. CHAPTER 2. This chapter describes the development of biaryl phosphines containing functionalization with a pendent base for use in gold catalyzed organic reactions. This chapter starts with development of synthetic methods for high efficiency in the synthesis of new iterations on the chemical structure. The use of high throughput screening for reaction discovery is discussed and the result from our trials is discussed. Evaluation of the different ligand candidates is done through NMR spectroscopic studies on two reactions. The first reaction studied is carboxylic acid addition to terminal alkynes. The second reaction studied is isomerization of alkynes. CHAPTER 3. This chapter describes the synthesis of hydrogen-bond-donor-functionalized ferrocenyl bisphosphines, and studies on the coordination chemistry of the novel bisphosphines with platinum and nickel. Development of the synthetic route to yielding the target compounds was necessary, and the major points of concern are discussed. Studies on the coordination chemistry of the ferrocenyl bisphosphines with platinum and nickel are discussed
Author: Braden Eric Silva
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
CHAPTER 1. This chapter introduces the field of study and motivations steering the direction of development. The topics of catalysis and bifunctional catalysis are discussed. CHAPTER 2. This chapter describes the development of biaryl phosphines containing functionalization with a pendent base for use in gold catalyzed organic reactions. This chapter starts with development of synthetic methods for high efficiency in the synthesis of new iterations on the chemical structure. The use of high throughput screening for reaction discovery is discussed and the result from our trials is discussed. Evaluation of the different ligand candidates is done through NMR spectroscopic studies on two reactions. The first reaction studied is carboxylic acid addition to terminal alkynes. The second reaction studied is isomerization of alkynes. CHAPTER 3. This chapter describes the synthesis of hydrogen-bond-donor-functionalized ferrocenyl bisphosphines, and studies on the coordination chemistry of the novel bisphosphines with platinum and nickel. Development of the synthetic route to yielding the target compounds was necessary, and the major points of concern are discussed. Studies on the coordination chemistry of the ferrocenyl bisphosphines with platinum and nickel are discussed
Author: Jiro Tsuji
Publisher: John Wiley & Sons
ISBN: 9780471560272
Category : Science
Languages : en
Pages : 500
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Book Description
Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Category : Science
Languages : en
Pages : 358
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Book Description
This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Author: Howard Alper
Publisher: Elsevier
ISBN: 0323161936
Category : Science
Languages : en
Pages : 271
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Book Description
Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.
Author: David Morales-Morales
Publisher: Elsevier
ISBN: 0128129328
Category : Science
Languages : en
Pages : 756
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Book Description
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Author: B.I. Kharisov
Publisher: Elsevier
ISBN: 0128110627
Category : Science
Languages : en
Pages : 470
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Book Description
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. - Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more - Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water - Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 460
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Book Description
Controlling the absolute stereochemistry of molecules is a major challenge to contemporary chemists. Achieving high enantioselectivity with catalytic amounts of a chirality transfer (or inducing) agent, and the ease of regenerating such catalysts is yet another challenge. Due to the involvement of various transition metal complexes, the relatively young field of enantioselective catalysis has emerged as a powerful tool for organic chemistry.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: Complete coverage of nearly 35 years of transition metal complex chemistry An in-depth treatment of many innovative synthetic methodologies A rational classification of all reactions according to substrates and reaction mechanisms Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists.; Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.
Author: Susan E. Gibson
Publisher: Oxford University Press, USA
ISBN:
Category : Electronic books
Languages : en
Pages : 264
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Book Description
This volume is designed to disseminate practical expertise in this important and demanding area of chemistry to undergraduate and postgraduate students in universities and to researchers working in the chemical industry. The authors have considerable practical and teaching experience in theareas they cover. Topics include transition metal-promoted oxidations, palladium-catalysed carbon-carbon bond formation, ferrocene chemistry, applications of organoiron complexes in organic synthesis, applications of titanocene and zirconocene complexes in organic synthesis and arene chromiumtricarbonyl chemistry.
Author: Yoshiaki Nishibayashi
Publisher: John Wiley & Sons
ISBN: 352734425X
Category : Science
Languages : en
Pages : 496
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Book Description
A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
