Crystal-Quasicrystal Transitions

Crystal-Quasicrystal Transitions PDF Author: M.J. Yacamán
Publisher: Elsevier
ISBN: 0444599142
Category : Science
Languages : en
Pages : 248

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Book Description
The discovery of five-fold diffraction symmetry by D. Schechtman in 1985 shocked crystallography to its roots. Incommensurable modulation of a crystal changes former identical unit cells into different ones. This radical revolution has given rise to the study of an entirely new class of matter, the quasicrystalline materials. The study of these quasi-periodic crystals brings a unique elucidation of the fundaments of crystallography and the relationship between lattice structure and macroscopic properties. This book covers the transitions between the crystalline and the quasicrystalline state. A thorough understanding of the transition from quasiperiodic to periodic lattices is essential in order to investigate the uniqueness of quasicrystals. In this well-written volume, an overview is given of the most important problems in quasicrystallography today. Leading experts provide insight into recent experimental advances achieved by studying the phase transitions between crystalline and quasicrystalline states. In the theoretical chapters one is introduced to the depth of insight into the nature of crystallography which has arisen through a rigorous understanding of the quasicrystal structure. This book is an essential source of reference for crystallographers, crystal growers and solid state physicists working in the field.

Crystal-Quasicrystal Transitions

Crystal-Quasicrystal Transitions PDF Author: M.J. Yacamán
Publisher: Elsevier
ISBN: 0444599142
Category : Science
Languages : en
Pages : 248

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Book Description
The discovery of five-fold diffraction symmetry by D. Schechtman in 1985 shocked crystallography to its roots. Incommensurable modulation of a crystal changes former identical unit cells into different ones. This radical revolution has given rise to the study of an entirely new class of matter, the quasicrystalline materials. The study of these quasi-periodic crystals brings a unique elucidation of the fundaments of crystallography and the relationship between lattice structure and macroscopic properties. This book covers the transitions between the crystalline and the quasicrystalline state. A thorough understanding of the transition from quasiperiodic to periodic lattices is essential in order to investigate the uniqueness of quasicrystals. In this well-written volume, an overview is given of the most important problems in quasicrystallography today. Leading experts provide insight into recent experimental advances achieved by studying the phase transitions between crystalline and quasicrystalline states. In the theoretical chapters one is introduced to the depth of insight into the nature of crystallography which has arisen through a rigorous understanding of the quasicrystal structure. This book is an essential source of reference for crystallographers, crystal growers and solid state physicists working in the field.

Reconstructive Phase Transitions

Reconstructive Phase Transitions PDF Author: Pierre Tol‚dano
Publisher: World Scientific
ISBN: 9789810223649
Category : Science
Languages : en
Pages : 424

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Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

Phase Transitions and Crystal Symmetry

Phase Transitions and Crystal Symmetry PDF Author: Yurii Aleksandrovich Izyumov
Publisher: Springer Science & Business Media
ISBN: 9400919204
Category : Science
Languages : en
Pages : 462

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Book Description
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years.

Reconstructive Phase Transitions: In Crystals And Quasicrystals

Reconstructive Phase Transitions: In Crystals And Quasicrystals PDF Author: Vladimir Dmitriev
Publisher: World Scientific
ISBN: 981450002X
Category : Science
Languages : en
Pages : 416

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Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

Quasicrystals

Quasicrystals PDF Author: J.-B. Suck
Publisher: Springer Science & Business Media
ISBN: 3662050285
Category : Science
Languages : en
Pages : 575

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Book Description
The book provides an introduction to all aspects of the physics of quasicrystals. The chapters, each written by an expert in this field, cover quasiperiodic tilings and the modeling of the atomic structure of quasicrystals. The electronic density of states and the calculation of the electronic structure play a key role in this introduction, as does an extensive discussion of the atomic dynamics. The study of defects in quasicrystals by high resolution electron microscopy and the computer simulations of defects and fracture in decorated tilings are important subjects for the application of these aperiodic crystals.

Phase Transitions and Crystal Symmetry

Phase Transitions and Crystal Symmetry PDF Author: Yurii Aleksandrovich Izyumov
Publisher: Springer
ISBN: 9780792305422
Category : Science
Languages : en
Pages : 444

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Book Description
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years.

Crystallography of Quasicrystals

Crystallography of Quasicrystals PDF Author: Steurer Walter
Publisher: Springer Science & Business Media
ISBN: 3642018998
Category : Science
Languages : en
Pages : 388

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Book Description
From tilings to quasicrystal structures and from surfaces to the n-dimensional approach, this book gives a full, self-contained in-depth description of the crystallography of quasicrystals. It aims not only at conveying the concepts and a precise picture of the structures of quasicrystals, but it also enables the interested reader to enter the field of quasicrystal structure analysis. Going beyond metallic quasicrystals, it also describes the new, dynamically growing field of photonic quasicrystals. The readership will be graduate students and researchers in crystallography, solid-state physics, materials science, solid- state chemistry and applied mathematics.

Aperiodic Crystals

Aperiodic Crystals PDF Author: Ted Janssen
Publisher: Oxford University Press, USA
ISBN: 0198567774
Category : Science
Languages : en
Pages : 481

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Book Description
Most materials and crystals have an atomic structure which is described by a regular stacking of a microscopic fundamental unit, the unit cell. However, there are also many well ordered materials without such a unit cell. This book deals with the structure determination and a discussion of the main special properties of these materials.

ENERGY MODELLING IN MINERALS

ENERGY MODELLING IN MINERALS PDF Author: C.M. Gramaccioli
Publisher: The Mineralogical Society of Great Britain and Ireland
ISBN: 9634635660
Category : Science
Languages : en
Pages : 430

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Book Description
Nothing provided

Discontinuous Phase Transitions In Condensed Matter: Symmetry Breaking In Bulk Martensite, Quasiperiodic And Low-dimensional Nanostructures

Discontinuous Phase Transitions In Condensed Matter: Symmetry Breaking In Bulk Martensite, Quasiperiodic And Low-dimensional Nanostructures PDF Author: Vladimir Dmitriev
Publisher: World Scientific
ISBN: 1800612931
Category : Science
Languages : en
Pages : 469

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Book Description
Discontinuous (first-order) phase transitions constitute the most fundamental and widespread type of structural transitions existing in Nature, forming a large majority of the transitions found in elemental crystals, alloys, inorganic compounds, minerals and complex fluids. Nevertheless, only a small part of them, namely, weakly discontinuous transformations, were considered by phenomenological theories, leaving aside the most interesting from a theoretical point of view and the most important for application cases. Discontinuous Phase Transitions in Condensed Matter introduces a density-wave approach to phase transitions which results in a unified, symmetry-based, model-free theory of the weak crystallization of molecular mixtures to liquid-crystalline mesophases, strongly discontinuous crystallization from molten metals and alloys to conventional, fully segregated crystals, to aperiodic, quasi-crystalline structures. Assembly of aperiodic closed virus capsids with non-crystallographic symmetry also falls into the domain of applicability of the density-wave approach.The book also considers the applicability domains of the symmetry-based approach in physics of low-dimensional systems. It includes comparisons of stability of different surface superstructures and metal monoatomic coverage structures on the surface of single-crystalline substrates. The example of the twisted graphene bilayer demonstrates how parametrization in the spirit of an advanced phenomenological approach can establish symmetry-controlled, and therefore model-free, links between geometrical parameters of the twisted bilayer structure and reconstruction of its Brillouin zone and energy bands.