Crevice Repassivation Potential of Alloy 22 in High-Nitrate Dust Deliquescence Type Environments PDF Download
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Languages : en
Pages : 13
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Book Description
The nitrate ion (NO3−) is an inhibitor for crevice corrosion of Alloy 22 (N06022) in chloride (Cl−) aqueous solutions. Naturally formed electrolytes may contain both chloride and nitrate ions. The higher the ratio R = [NO3−]/[Cl−] in the solution the stronger the inhibition of crevice corrosion. Atmospheric desert dust contains both chloride and nitrate salts, generally based on sodium (Na) and potassium (K). Some of these salts may deliquescence at relatively low humidity at temperatures on the order of 150 C and higher. The resulting deliquescent brines are highly concentrated and especially rich in nitrate. Electrochemical tests have been performed to explore the anodic behavior of Alloy 22 in high chloride high nitrate electrolytes at temperatures as high as 150 C at ambient atmospheres. Naturally formed brines at temperatures higher than 120 C do not induce crevice corrosion in Alloy 22 because they contain high levels of nitrate. The inhibitive effect of nitrate on crevice corrosion is still active for temperatures higher than 100 C.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 13
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Book Description
The nitrate ion (NO3−) is an inhibitor for crevice corrosion of Alloy 22 (N06022) in chloride (Cl−) aqueous solutions. Naturally formed electrolytes may contain both chloride and nitrate ions. The higher the ratio R = [NO3−]/[Cl−] in the solution the stronger the inhibition of crevice corrosion. Atmospheric desert dust contains both chloride and nitrate salts, generally based on sodium (Na) and potassium (K). Some of these salts may deliquescence at relatively low humidity at temperatures on the order of 150 C and higher. The resulting deliquescent brines are highly concentrated and especially rich in nitrate. Electrochemical tests have been performed to explore the anodic behavior of Alloy 22 in high chloride high nitrate electrolytes at temperatures as high as 150 C at ambient atmospheres. Naturally formed brines at temperatures higher than 120 C do not induce crevice corrosion in Alloy 22 because they contain high levels of nitrate. The inhibitive effect of nitrate on crevice corrosion is still active for temperatures higher than 100 C.
Author: Neil C. Hyatt
Publisher:
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 624
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Book Description
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
Author: Anthony E. Hughes
Publisher: Springer
ISBN: 9401775400
Category : Technology & Engineering
Languages : en
Pages : 429
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Book Description
This book covers a broad range of materials science that has been brought to bear on providing solutions to the challenges of developing self-healing and protective coatings for a range of metals. The book has a strong emphasis on characterisation techniques, particularly new techniques that are beginning to be used in the coatings area. It features many contributions written by experts from various industrial sectors which examine the needs of the sectors and the state of the art. The development of self-healing and protective coatings has been an expanding field in recent years and applies a lot of new knowledge gained from other fields as well as other areas of materials science to the development of coatings. It has borrowed from fields such as the food and pharmaceutical industries who have used, polymer techniques, sol-gel science and colloidosome technology for a range encapsulation techniques. It has also borrowed from fields like hydrogen storage such as from the development of hierarchical and other materials based on organic templating as “nanocontainers” for the delivery of inhibitors. In materials science, recent developments in high throughput and other characterisation techniques, such as those available from synchrotrons, are being increasing used for novel characterisation – one only needs to look at the application of these techniques in self healing polymers to gauge wealth of new information that has been gained from these techniques. This work is largely driven by the need to replace environmental pollutants and hazardous chemicals that represent risk to humans such as chromate inhibitors which are still used in some applications.
Author: G L Song
Publisher: Woodhead Publishing
ISBN: 9781845697082
Category : Technology & Engineering
Languages : en
Pages : 0
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Book Description
The use of magnesium alloys is increasing in a range of applications, and their popularity is growing wherever lightweight materials are needed. This book provides a comprehensive account of the corrosion of magnesium alloys. It covers not only the corrosion performances and mechanisms of Mg alloys in conventional environments, such as sodium chloride solutions, but also looks at their corrosion behaviours in special media, like engine coolants and simulated body fluids. Part one covers fundamentals such as the corrosion electrochemistry, activity and passivity of magnesium and its alloys. Part two then considers the metallurgical effect in relation to the corrosion of magnesium alloys, including the role of micro-structure and earth-rare elements, the corrosion behaviour of magnesium-based bulk metallic glasses, and the corrosion of innovative magnesium alloys. Part three goes on to describe environmental influences on the corrosion of magnesium alloys, such as atmospheric corrosion, stress corrosion cracking, creep and fatigue behaviour, and galvanic corrosion. Finally, part four is concerned with various means of protecting magnesium alloys against corrosion through the use of aluminium electrodeposition, conversion and electrophoretic coatings, and anodisation. With its distinguished editor and team of contributors, this book is an invaluable resource for metallurgists, engineers and designers working with magnesium and its alloys, as well as professionals in the aerospace and automotive industries.
Author: ASM International
Publisher:
ISBN: 9780871707086
Category :
Languages : en
Pages :
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Book Description
Author: George Vachtsevanos
Publisher: Springer Nature
ISBN: 3030328317
Category : Technology & Engineering
Languages : en
Pages : 339
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Book Description
This book discusses relevant topics in field of corrosion, from sensing strategies to modeling of control processes, corrosion prevention, detection of corrosion initiation, prediction of corrosion growth and evolution, to maintenance practices and return on investment.Written by leading international experts, it combines mathematical and scientific rigor with multiple case studies, examples, colorful images, case studies and numerous references exploring the essentials of corrosion in depth. It appeals to a wide readership, including corrosion engineers, managers, students and industrial and government staff, and can serve as a reference text for courses in materials, mechanical and aerospace engineering, as well as anyone working on corrosion processes.
Author: International Atomic Energy Agency
Publisher:
ISBN: 9789201061195
Category : Technology & Engineering
Languages : en
Pages :
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Book Description
This publication is a revision by amendment of IAEA Safety Standards Series No. SSG-15 and provides recommendations and guidance on the storage of spent nuclear fuel. It covers all types of storage facility and all types of spent fuel from nuclear power plants and research reactors. It takes into consideration the longer storage periods beyond the original design lifetime of the storage facility that have become necessary owing to delays in the development of disposal facilities and the reduction in reprocessing activities. It also considers developments associated with nuclear fuel, such as higher enrichment, mixed oxide fuels and higher burnup. Guidance is provided on all stages in the lifetime of a spent fuel storage facility, from planning through siting and design to operation and decommissioning. The revision was undertaken by amending, adding and/or deleting specific paragraphs addressing recommendations and findings from studying the accident at the Fukushima Daiichi nuclear power plant in Japan.
Author:
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ISBN:
Category : Nuclear fuels
Languages : en
Pages : 2
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Author: United States Department of Energy. Office of Civilian Radioactive Waste Management
Publisher:
ISBN:
Category : Radioactive waste disposal
Languages : en
Pages : 34
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Book Description
Author: Philippe Marcus
Publisher: CRC Press
ISBN: 9780203909188
Category : Mathematics
Languages : en
Pages : 760
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Book Description
Called "a useful contribution to the current litereture on corrosion science, engineering, and technology" by Corrosion Review, this book offers real-world applications and problem-solving techniques to reduce the occurrence of pits, cracks, and deterioration in industrial, automotive, marine, and electronic structures. It details the electrochemic
